A hybrid dehydrogenation reaction system includes: an acid aqueous solution tank having an acid aqueous solution; an exothermic dehydrogenation reactor including a chemical hydride of a solid state and receiving the acid aqueous solution from the acid aqueous solution tank for an exothermic dehydrogenation reaction of the chemical hydride and the acid aqueous solution to generate hydrogen; an LOHC tank including a liquid organic hydrogen carrier (LOHC); and an endothermic dehydrogenation reactor receiving the liquid organic hydrogen carrier from the LOHC tank and generating hydrogen through an endothermic dehydrogenation reaction of the liquid organic hydrogen carrier by using heat generated from the exothermic dehydrogenation reactor.

The present invention relates to improved hydrogen storage materials and improved processes for their preparation. The hydrogen storage materials prepared by the processes described herein exhibit enhanced hydrogen storage capacity when used as hydrogen storage systems. The processes described herein may be undertaken on a commercial scale.

The present invention relates to a process for producing and for regenerating siloxane hydrogen carrier compounds.

The present invention relates to a hydrogen gas production method, which includes: a first step of concentrating an aqueous solution containing an alkali metal formate; a second step of protonating at least a part of the alkali metal formate by electrodialysis to produce a formic acid; and a third step of decomposing the formic acid to produce a hydrogen gas.

The present invention relates to the use of a formulation which is liquid at ambient temperature comprising at least one terpene derivative for the fixing and the release of hydrogen in at least one hydrogenation/dehydrogenation cycle of said formulation.

The invention also relates to the use of said formulation for the transportation and the handling of hydrogen resulting from the steam cracking of petroleum products, of inevitable hydrogen resulting from chemical reactions, such as the electrolysis of salt, or of hydrogen resulting from the electrolysis of water.

The invention relates to a process, catalysts, materials for conversion of renewable electricity, air, and water to low or zero carbon fuels and chemicals by the direct capture of carbon dioxide from the atmosphere and the conversion of the carbon dioxide to fuels and chemicals using hydrogen produced by the electrolysis of water.

A hydrogen storage device 200 comprises: a first vessel 230, having a first fluid inlet 210 and/or a first fluid outlet 220, having therein a thermally conducting network 240 thermally coupled to a first heater (not shown); wherein the first vessel 230 is arranged to receive therein a hydrogen storage material in thermal contact, at least in part, with the thermally conducting network 240; wherein the thermally conducting network 240 has a lattice geometry, a gyroidal geometry and/or a fractal geometry in two and/or three dimensions, comprising a plurality of nodes, having thermally conducting arms therebetween, with voids between the arms; and wherein the hydrogen storage material comprises and/or is a liquid organic hydrogen carrier, LOHC.

The present disclosure refers to systems and methods for the production, storage, and transportation of hydrogen. In a representative embodiment a reactor system comprises a fluidized bed combustor configured for reduced metal oxide oxidation and heat generation without significant greenhouse gas emission and/or with readily capturable emissions. The reactor system also comprises a liquid organic hydrogen carrier dehydrogenation reactor. The fluidized bed combustor is operatively coupled to the liquid organic hydrogen carrier dehydrogenation reactor. Advantageously, at least a portion of heat generated by the fluidized bed combustor may be transferred to the liquid organic hydrogen carrier dehydrogenation reactor. In this manner hydrogen production and transportation is both energy efficient, low carbon intensity and cost-effective.

The system includes a reactor vessel having a reactor space bound by a reactor wall. The reactor vessel is arranged for holding a mixture of a catalyst and formic acid in the reactor space. The reactor vessel includes a mixture inflow opening for allowing the mixture to enter the reactor space and a mixture outflow opening for allowing said mixture to exit the reactor space, and a gas outflow opening for allowing hydrogen originating from the mixture to exit the reactor space. A method for hydrogen production includes: providing the formic acid and the catalyst into the reactor space; withdrawing the mixture from the reactor space; heating and/or cooling the mixture to a predetermined temperature range outside the reactor space; and introducing the heated and/or cooled mixture into the reactor space in a predetermined direction having a tangential component arranged for stirring said mixture in the reactor space.

The object of the present invention addresses a problem of providing a novel hydrogen storage material containing a metal-organic framework that can effectively store hydrogen. Hydrogen can be effectively stored by use of a hydrogen storage material containing a metal-organic framework, the metal-organic framework comprising a carboxylate ion of formula (I) and a multivalent metal ion, wherein the carboxylate ion and the multivalent metal ion are bound to each other. (In formula (I), X is an unsubstituted or substituted C2-C20 alkyl group, an unsubstituted or substituted alkenyl group, an unsubstituted or substituted alkynyl group, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted alkenyloxy group, an unsubstituted or substituted alkynyloxy group, a benzyloxy group, an unsubstituted or substituted alkylsulfanyl group, an unsubstituted or substituted alkenylsulfanyl group, an unsubstituted or substituted alkynylsulfanyl group, an unsubstituted or substituted alkylamino group, an unsubstituted or substituted dialkylamino group, an unsubstituted or substituted alkenylamino group, an unsubstituted or substituted dialkenylamino group, an unsubstituted or substituted alkynylamino group, an unsubstituted or substituted dialkynylamino group, a phenyl group, a sulfanyl group or an unsubstituted or substituted alkoxycarbonyl group.)

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