Porphyrin photosensitizers including 5,15-di(naphthalimide) moieties useful for photocatalytic hydrogen evolution, compositions including the same, and methods of use thereof.

A device for preparing high-purity hydrogen and/or oxygen by electrolyzing water, including an electrolyzer and a degasser for degassing desalted water. The degasser is located at the upstream of the electrolyzer. After desalted water is heated and degassed in the degasser, the content of gaseous impurities, particularly argon, can be reduced to several ppb (weight ratio). The hydrogen and oxygen generated after the desalted and degassed water is electrolyzed in the electrolyzer also contain an extremely small amount of argon, so that the requirements in semiconductor industry are met. Also involved is a method of preparing high-purity hydrogen and/or oxygen by using the device.

The present invention relates to carbon fiber composites and a method for producing the same. By reducing specific transition metal ions with a specific concentration, the method for producing the carbon fiber composites can form nanoparticles of a transition metal on an outer surface of a titanium dioxide layer encapsulating a carbon fiber to produce the carbon fiber composites. The nanoparticles of the transition metal directionally contact the titanium dioxide layer, so that the carbon fiber composites have synergistically photocatalytic activity.

A system for and method of cleaving a bond between a first atom and a second atom in a molecule of a material are presented. One embodiment of the technique includes selecting a first electromagnetic radiation frequency, the first electromagnetic radiation frequency including a product of a golden mean and a base frequency associated with at least one of the first atom and the second atom. Such an embodiment further includes directing a first electromagnetic radiation at the material, where the first electromagnetic radiation has a frequency equal to the first electromagnetic radiation frequency, and where the first electromagnetic radiation frequency is sufficient to cleave the bond between the first atom and the second atom.

A photocatalytic device includes a substrate having a surface, and an array of conductive projections supported by the substrate and extending outward from the surface of the substrate. Each conductive projection of the array of conductive projections has a semiconductor composition. The semiconductor composition establishes a photochemical diode. The surface may be nonplanar such that subsets of the array of conductive projections are oriented at different angles.

Disclosed herein is a method and apparatus for producing hydrogen and oxygen from water, more particularly, for decomposing water molecular bonds using resonant waves. The produced hydrogen gas may be used as a fuel, and the released oxygen gas may be used as an oxidant.

A catalyst comprising a porous electrically conductive substrate (such as a foam, carbon fibre paper and carbon fibre cloth) and a porous metallic composite of amorphous NiMoP coating at least a portion of the surface or multiple surfaces of the substrate. The composite preferably forms a continuous layer which coats the surfaces and pores of the substrate. Also methods for preparing and using the catalyst, for example in electrolytic water splitting.

Devices for photoelectrodes for water splitting based on indium nanowires on flexible substrates as well as methods of manufacture by transferring nanowire arrays to flexible substrates.

A containerized system for producing anhydrous ammonia from air, water and a power source, includes a containerized hydrogen production unit that produces hydrogen gas from a water source by low temperature electrolyser, high temperature electrolyser, battolyser or by other methods; a containerized nitrogen production unit comprising an onboard air compression and storage unit that produces and stores pressurized air, a pressure swing adsorption process or other methods that use regenerative molecule that does not need any maintenance, which intakes compressed air and produces nitrogen gas through a series of adsorption and desorption processes, or other such methods of producing nitrogen from air; a containerized ammonia production unit comprising a gas booster that increases the pressure of a mixture of the hydrogen gas and the nitrogen gas using the pressurized air; a multi-reactor assembly joint in series or in parallel; and a recycle loop that separates the ammonia from unreacted gases.

A hydrogen production apparatus including a photocatalyst and generating hydrogen from water includes a wavelength separation unit separating sunlight by wavelength, an infrared light conversion unit converting infrared light separated by the wavelength separation unit to visible light, and an ultraviolet light conversion unit converting ultraviolet light separated by the wavelength separation unit to visible light.