Patent classifications
C01B39/14
ONE-STEP METHOD FOR THE SYNTHESIS OF HIGH SILICA CONTENT ZEOLITES IN ORGANIC-FREE MEDIA
In an embodiment, the present disclosure pertains to a composition comprising a zeolite with high silica content. In some embodiments, the silica to aluminum ratio (SAR) for the zeolite is 2:1. In some embodiments, the zeolite comprises Zeolite HOU-2 (LTA-type). In some embodiments, the silica to aluminum ratio (SAR) for the zeolite is >3. In some embodiments, the zeolite comprises Zeolite HOU-3 (FAU type). In some embodiments, the zeolite is synthesized using a one-step method. In some embodiments, the zeolite is synthesized without the use of an organic structure-directing agent (OSDA). In some embodiments, the zeolite is synthesized without the use of post-synthesis dealumination. In some embodiments, the zeolite is synthesized without the use crystal seeds. In some embodiments, the zeolite is used in commercial ion exchange. In some embodiments, the zeolite is used for catalysis reaction. In some embodiments, the zeolite is highly thermostable.
CATALYST AND METHOD FOR PREPARING CATALYST
A catalyst includes LTA zeolite including copper ions, wherein a Si/Al ratio of the LTA zeolite is 2 to 50. The catalyst is coated on a honeycomb carrier or a filter. The catalyst removes NOx from a reaction gas at 100° C. or above. The catalyst has an NOx conversion rate of 80% at 450° C. or above.
METHOD FOR PREPARING ZEOLITE CATALYST
A method for manufacturing a zeolite catalyst includes: manufacturing a first Linde Type A (LTA) zeolite using an LTA seed; manufacturing a second LTA zeolite including ions by substituting ions to the first LTA zeolite; and manufacturing a copper LTA zeolite by performing copper ion exchange on the second LTA zeolite.
HIGH-EFFICIENCY, FAST AND GREEN METHOD FOR PREPARING ZEOLITE MOLECULAR SIEVE
A method for preparing a zeolite molecular sieve includes the steps of: (1) mixing at least one of a silicon source, an aluminum source and a phosphorus source with an alkaline substance, a template agent and water uniformly to obtain a zeolite molecular sieve precursor solution; aging the zeolite molecular sieve precursor solution at 20-30° C. for 10-15 h; and subjecting the aged solution to ionizing radiation, and then washing the obtained solid to neutrality and drying to obtain the zeolite molecular sieve. The method of the present invention is green, simple and extremely cost-effective. Under the irradiation of an ionizing radiation source, the synthesis period of zeolite molecular sieve is short and no heating is needed in the preparation process, so energy consumption is reduced and a high-pressure system is avoided.
ZEOLITE AND PREPARATION METHOD THEREFOR
Disclosed is a method of producing zeolite that includes obtaining a lithium residue including aluminosilicate from lithium ore including lithium oxide; washing the lithium residue to adjust the pH of the lithium residue; adjusting a molar ratio of silicon to aluminum (Si/Al) included in the lithium residue; preparing a hydrogel by adding an alkali material to the lithium residue; and preparing crystals by crystallizing the lithium residue in the form of a hydrogel.
ZEOLITE AND PREPARATION METHOD THEREFOR
Disclosed is a method of producing zeolite that includes obtaining a lithium residue including aluminosilicate from lithium ore including lithium oxide; washing the lithium residue to adjust the pH of the lithium residue; adjusting a molar ratio of silicon to aluminum (Si/Al) included in the lithium residue; preparing a hydrogel by adding an alkali material to the lithium residue; and preparing crystals by crystallizing the lithium residue in the form of a hydrogel.
SEPARATION MEMBRANE STRUCTURE
A separation membrane structure includes a porous support, a first separation membrane and a second separation membrane. The first separation membrane is formed on the porous support and contains high silica zeolite having Si/Al atomic ratio of greater than or equal to 200. The second separation membrane is formed on the first separation membrane and contains cation.
SEPARATION MEMBRANE STRUCTURE
A separation membrane structure includes a porous support, a first separation membrane and a second separation membrane. The first separation membrane is formed on the porous support and contains high silica zeolite having Si/Al atomic ratio of greater than or equal to 200. The second separation membrane is formed on the first separation membrane and contains cation.
Production of pulverulent, porous crystalline metal silicates by means of flame spray pyrolysis
The present invention relates to a process for preparing a pulverulent, porous crystalline metal silicate, comprising the following steps: a) hydrothermal synthesis in an aqueous mixture comprising (A) at least one silicon source, (B) at least one metal source and (C) at least one mineralizer to obtain an aqueous suspension comprising a porous crystalline metal silicate as reaction product; and b) calcination of the reaction product, characterized in that the calcination is conducted by means of flame spray pyrolysis at an adiabatic combustion temperature within a range of 450-2200° C., wherein the suspension having a solids content of 70% by weight which is obtained in step a) is sprayed into a flame generated by combustion of a fuel in the presence of oxygen to form a pulverulent, porous crystalline metal silicate.
Production of pulverulent, porous crystalline metal silicates by means of flame spray pyrolysis
The present invention relates to a process for preparing a pulverulent, porous crystalline metal silicate, comprising the following steps: a) hydrothermal synthesis in an aqueous mixture comprising (A) at least one silicon source, (B) at least one metal source and (C) at least one mineralizer to obtain an aqueous suspension comprising a porous crystalline metal silicate as reaction product; and b) calcination of the reaction product, characterized in that the calcination is conducted by means of flame spray pyrolysis at an adiabatic combustion temperature within a range of 450-2200° C., wherein the suspension having a solids content of 70% by weight which is obtained in step a) is sprayed into a flame generated by combustion of a fuel in the presence of oxygen to form a pulverulent, porous crystalline metal silicate.