Patent classifications
C01B39/00
PROCESS FOR PREPARING A MOLDING COMPRISING A ZEOLITE CATALYST AND METHOD FOR CONVERTING OXYGENATES TO OLEFINS USING THE CATALYTIC MOLDING
The present invention relates to a process for preparing a molding comprising a zeolitic material and one or more oxidic binders, the process particularly comprising preparing a mixture of a zeolitic material, such as Mg-ZSM-5, a source of an oxidic binder, and a first plasticizer; admixing an acid to said mixture; and shaping of the mixture, to obtain a precursor of a molding; wherein in said mixture a specific weight ratio of the source of the oxidic binder to the sum of the zeolitic material and the source of the oxidic binder is applied. Further, the present invention relates to a molding obtainable or obtained by the inventive process, and to a molding itself displaying in particular a comparatively improved crush strength. Yet further, the present invention relates to a method for the conversion of oxygenates to olefins and to a use of the inventive molding.
Fire-Proof Lithium-Ion Battery
A lithium-ion battery separator includes a substrate defining inter-particle pores and a zeolite coating on a surface of the substrate. The zeolite coating includes zeolite particles. The zeolite particles are hydrophobic and have an average diameter smaller than an average pore size of inter-particle pores of the substrate, such that some of the zeolite particles are positioned in some of the inter-particle pores. The separator is non-flammable In a lithium-ion battery, the substrate is a first electrode, and a second electrode is in direct contact with the zeolite coating. The lithium-ion battery includes a non-flammable salt-concentrated electrolyte, and the zeolite coating has a high wettability for the electrolyte. The lithium-ion battery is non-flammable.
Porous aluminum pyrazoledicarboxylate frameworks
A porous aluminum-based metal-organic framework (MOF) comprises inorganic aluminum chains linked via carboxylate groups of 1H-pyrazole-3,5-dicarboxylate (HPDC) linkers, and of formula: [Al(OH)(C.sub.5H.sub.2O.sub.4N.sub.2)(H.sub.2O)].
Process for the flash calcination of a zeolitic material
The present invention relates to a process for the calcination of a zeolitic material, wherein said process comprises the steps of (i) providing a zeolitic material comprising YO.sub.2 and optionally further comprising X.sub.2O.sub.3 in its framework structure in the form of a powder and/or of a suspension of the zeolitic material in a liquid, wherein Y stands for a tetravalent element and X stands for a trivalent element; (ii) atomization of the powder and/or of the suspension of the zeolitic material provided in (i) in a gas stream for obtaining an aerosol; (iii) calcination of the aerosol obtained in (ii) for obtaining a calcined powder; as well as to a zeolitic material obtainable and/or obtained according the inventive process, and to its use as a molecular sieve, as an adsorbent, for ion-exchange, as a catalyst, and/or as a catalyst support.
Method and system for neutralizing asbestos
A system for asbestos neutralization, that includes a neutralization unit having a module configured for sorting of asbestos waste, an asbestos waste grinder; a concentrated sulfuric acid tank, a vat containing a hot diluted acid solution, for which temperature is between 70° C. and 100° C., in which grinded asbestos waste containing asbestos is dipped, the solution is configured for neutralizing asbestos contained in the grinded asbestos waste, a filtration unit to separate, at the end of the neutralization reaction, a solid inert waste from a liquid phase of the diluted acid solution, a regeneration unit for the diluted acid solution, which adjusts the hydrogen potential of the extracted liquid phase by adding concentrated sulfuric acid from the tank, and means for transferring the regenerated solution into the vat.
Metal-organic framework/polymer foam composite materials and their uses in decontamination and/or ballistic protection
A composite material is provided comprising a porous polymeric matrix having metal-organic framework (MOF) domains dispersed within the porous polymeric matrix, each of said MOF domains in fluid communication with the external environment through the pores in the porous polymeric matrix. A process of using the composite material to chemically modify or detoxify a chemical warfare agent or a toxic industrial chemical is also provided. The chemical warfare agent or the toxic industrial chemical is brought into contact with a MOF domain within the porous polymeric matrix so that the MOFs adsorb and chemically modify the chemical warfare agent or the toxic industrial chemical. A process for producing such a composite material is also disclosed.
MOLDED ADSORBENT AND WATER PURIFICATION CARTRIDGE
To improve a performance for removing soluble lead and finely particulate lead. A molded adsorbent (1) includes an adsorption material (3) and a fibrous binder (5). The adsorption material (3) contains activated carbon (3A) and zeolite (3B). A central particle size D50 of the activated carbon (3A) is 27 μm or more and 35 μm or less, a central particle size D50 of the zeolite (3B) is 24 μm or more and 31 μm or less, and a content rate of the zeolite (3B) is 10 mass % or more and 70.5 mass % or less.
SOLID-STATE CRYSTALLIZATION OF METAL ORGANIC FRAMEWORKS WITHIN MESOPOROUS MATERIALS METHODS AND HYBRID MATERIALS THEREOF
A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula A.sub.x(L.sup.-x) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula A.sub.x(L.sup.-x)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula H.sub.x(L.sup.- .sup.x)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M.sup.+y(B).sub.y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M.sup.+y(B).sub.y][H.sub.x(L.sup.-x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M.sup.+yL.sup.-x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.
SOLID-STATE CRYSTALLIZATION OF METAL ORGANIC FRAMEWORKS WITHIN MESOPOROUS MATERIALS METHODS AND HYBRID MATERIALS THEREOF
A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula A.sub.x(L.sup.-x) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula A.sub.x(L.sup.-x)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula H.sub.x(L.sup.- .sup.x)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M.sup.+y(B).sub.y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M.sup.+y(B).sub.y][H.sub.x(L.sup.-x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M.sup.+yL.sup.-x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.
Hybrid membrane comprising zeolitic imidazolate framework nanoparticles and method of gas separation using the same
The present invention relates to a hybrid membrane mixed with nanoparticles including a zeolitic imidazolate framework (ZIF), and a gas separation method using the same. A hybrid membrane according to the present invention comprises a polymer matrix, and nanoparticles which are dispersed in the polymer matrix and include the ZIF.