Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C.sub.8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m.sup.2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

A method for the large-scale synthesis of a zeolite-templated carbon (ZTC). The method includes the steps of: introducing a bed material comprising a zeolite to a fluidized bed reactor and heating the bed material to a temperature between 550° C. and 800° C.; fluidizing the bed material with a fluidizing gas and maintaining the temperature of the bed material between 550° C. and 800° C.; introducing an organic carbon precursor while fluidizing the zeolite for a period of time such that carbon is deposited on the zeolite by chemical vapor deposition to produce a zeolite-carbon composite; and treating the zeolite-carbon composite with an acid solution such that the zeolite template is dissolved and the ZTC is obtained.

A method for the large-scale synthesis of a zeolite-templated carbon (ZTC). The method includes the steps of: introducing a bed material comprising a zeolite to a fluidized bed reactor and heating the bed material to a temperature between 550° C. and 800° C.; fluidizing the bed material with a fluidizing gas and maintaining the temperature of the bed material between 550° C. and 800° C.; introducing an organic carbon precursor while fluidizing the zeolite for a period of time such that carbon is deposited on the zeolite by chemical vapor deposition to produce a zeolite-carbon composite; and treating the zeolite-carbon composite with an acid solution such that the zeolite template is dissolved and the ZTC is obtained.

The present invention relates to a process for preparing a pulverulent, porous crystalline metal silicate, comprising the following steps: a) hydrothermal synthesis in an aqueous mixture comprising (A) at least one silicon source, (B) at least one metal source and (C) at least one mineralizer to obtain an aqueous suspension comprising a porous crystalline metal silicate as reaction product; and b) calcination of the reaction product, characterized in that the calcination is conducted by means of flame spray pyrolysis at an adiabatic combustion temperature within a range of 450-2200° C., wherein the suspension having a solids content of 70% by weight which is obtained in step a) is sprayed into a flame generated by combustion of a fuel in the presence of oxygen to form a pulverulent, porous crystalline metal silicate.

The present invention relates to a process for preparing a pulverulent, porous crystalline metal silicate, comprising the following steps: a) hydrothermal synthesis in an aqueous mixture comprising (A) at least one silicon source, (B) at least one metal source and (C) at least one mineralizer to obtain an aqueous suspension comprising a porous crystalline metal silicate as reaction product; and b) calcination of the reaction product, characterized in that the calcination is conducted by means of flame spray pyrolysis at an adiabatic combustion temperature within a range of 450-2200° C., wherein the suspension having a solids content of 70% by weight which is obtained in step a) is sprayed into a flame generated by combustion of a fuel in the presence of oxygen to form a pulverulent, porous crystalline metal silicate.

A zeolite membrane composite includes a porous support and a zeolite membrane formed on at least one surface of the porous support. The zeolite membrane of the zeolite membrane composite is formed of an X-MOR-type zeolite, where X includes at least one type of transition metal ion.

A catalyst composition comprising (a) carrier comprising (i) 5 to 95 wt % mordenite type zeolite having a mean crystallite length parallel to the direction of the 12-ring channels of 60 nm or less and a mesopore volume of at least 0.10 cc/gram, (ii) 5 to 95 wt % ZSM-5 type zeolite; and (iii) 10 to 60 wt % inorganic binder; and (b) 0.001 to 10 wt % of one or more catalytically active metals, wherein the inorganic binder comprises titania, its preparation and its use in alkylaromatic conversion.

The present disclosure relates to a method for preparing a mordenite zeolite, the method including crystallizing, at a temperature of 150° C. to 190° C., a gel which includes, in mol based on 1 mol of silica, 0.02 to 0.2 of an alumina precursor, 0.01 to 0.04 of a structure-directing agent, 0.1 to 0.18 of a pH control agent, and 10 to 100 of water. According to the present disclosure, a mordenite zeolite having high particle size uniformity and a particle size controllable while maintaining the particle size uniformity may be prepared.

The present disclosure is directed to a method of manufacture of mordenite zeolites. This is accomplished by using an improved sol-gel formulation including a water-soluble fraction of ODSO as an additional component. The resulting products are, or contain, mordenite zeolites, with increased yield.

The present disclosure is directed to a method of manufacture of beta zeolites. This is accomplished by using an improved sol-gel formulation including a water-soluble fraction of ODSO as an additional component. The resulting products are, or contain, beta zeolites, with increased yield.