Disclosed is a device for preparing multi-component metal hydroxide including a raw material feeder configured to feed raw materials including a metal raw material, a pH adjuster and a complexing agent, a reactor configured to react the raw materials fed from the raw material feeder to prepare a reaction solution and grow particles of multi-component metal hydroxide contained in the reaction solution, a storage tank configured to store the reaction solution transferred from the reactor, a first duct configured to transfer the raw materials from the raw material feeder to the reactor, a second duct configured to transfer the reaction solution from the reactor to the storage tank, a third duct configured to transfer the reaction solution from the storage tank to the reactor, and an operation controller configured to control operations of the reactor and the storage tank to circulate the reaction solution between the reactor and the storage tank until the particles of multi-component metal hydroxide grow to a target particle size.

Provided are a CaMg.sub.2-based alloy hydride material for hydrolysis production of hydrogen, a preparation method therefor and a use thereof. The material has a general formula of CaMg.sub.xM.sub.yH.sub.z, wherein M is Ni, Co or Fe, 1.5≦x<2.0, 0<y≦0.5, and 3≦z<6. The preparation method for the material comprises the following steps: (1) stacking three pure metal block materials in a crucible, wherein a metal block material M is placed at the top; (2) installing the crucible in a high-frequency induction melting furnace, evacuating and introducing an argon gas; (3) starting the high-frequency induction melting furnace to heat at a low power first, then increasing the power to uniformly fuse same; and thereafter cooling with the furnace to obtain an alloy ingot, and hammer-milling to obtain a hydrogen storage alloy based on CaMg.sub.2; and (4) hydrogenating the hammer-milled hydrogen storage alloy to obtain the material for hydrolysis production of hydrogen. The preparation method is simple and low in cost. The material can absorb hydrogen at normal temperature with a good hydrogen absorption performance The prepared hydrogen is pure, and can be directly introduced into and used in a hydrogen fuel battery.

Provided are a CaMg.sub.2-based alloy hydride material for hydrolysis production of hydrogen, a preparation method therefor and a use thereof. The material has a general formula of CaMg.sub.xM.sub.yH.sub.z, wherein M is Ni, Co or Fe, 1.5≦x<2.0, 0<y≦0.5, and 3≦z<6. The preparation method for the material comprises the following steps: (1) stacking three pure metal block materials in a crucible, wherein a metal block material M is placed at the top; (2) installing the crucible in a high-frequency induction melting furnace, evacuating and introducing an argon gas; (3) starting the high-frequency induction melting furnace to heat at a low power first, then increasing the power to uniformly fuse same; and thereafter cooling with the furnace to obtain an alloy ingot, and hammer-milling to obtain a hydrogen storage alloy based on CaMg.sub.2; and (4) hydrogenating the hammer-milled hydrogen storage alloy to obtain the material for hydrolysis production of hydrogen. The preparation method is simple and low in cost. The material can absorb hydrogen at normal temperature with a good hydrogen absorption performance The prepared hydrogen is pure, and can be directly introduced into and used in a hydrogen fuel battery.

The invention relates to a compound of the formula Li.sub.7-xPS.sub.6-xX.sub.x-z(BH.sub.4).sub.z, in which x is selected from the group comprising Cl, Br, I, F and CN, 0≤x≤2, 0≤z≤0.50. This compound can be used as a solid electrolyte of a lithium-ion electrochemical element.

A palladium hydride nanomaterial includes nanostructures having a chemical composition represented by the formula: M.sub.y—Pd.sub.xH.sub.z, where M is at least one metal different from palladium; x has a non-zero value in the range of 0 to 5; y has a value in the range of 0 to 5; and z has a non-zero value in the range of 0 to 5.

A palladium hydride nanomaterial includes nanostructures having a chemical composition represented by the formula: M.sub.y—Pd.sub.xH.sub.z, where M is at least one metal different from palladium; x has a non-zero value in the range of 0 to 5; y has a value in the range of 0 to 5; and z has a non-zero value in the range of 0 to 5.

A solid-state hydrogen storage device includes a first storage for storing a reversible solid-state hydrogen storage material, a reactor disposed in the first storage to enable a hydrolysis reaction of a non-reversible solid-state hydrogen storage material to be performed therein, and a fuel cell stack, wherein the non-reversible solid-state hydrogen storage material is stored in the reactor, and wherein the non-reversible solid-state hydrogen storage material releases heat when the hydrolysis is performed.

A method for producing a thin film according to the present disclosure comprises a step of forming the thin film on a substrate using a target. The target is formed of a mixture containing a first material and a second material. The first material has a composition represented by ATiO.sub.3 (where A is at least one selected from the group consisting of Ba and Sr). The second material has a composition represented by EH.sub.2 (where E is at least one selected from the group consisting of Ti and Zr). The thin film is formed of a first oxide containing A, Ti, and O. Some of oxide ions contained in the first oxide have been replaced by hydride ions.

A method for producing a thin film according to the present disclosure comprises a step of forming the thin film on a substrate using a target. The target is formed of a mixture containing a first material and a second material. The first material has a composition represented by ATiO.sub.3 (where A is at least one selected from the group consisting of Ba and Sr). The second material has a composition represented by EH.sub.2 (where E is at least one selected from the group consisting of Ti and Zr). The thin film is formed of a first oxide containing A, Ti, and O. Some of oxide ions contained in the first oxide have been replaced by hydride ions.

Laves phase-related BCC metal hydride alloys historically have limited electrochemical capabilities. Provided are processes of activating these alloys to produce hydrogen storage materials with greater than 200 mAh/g capacities and commonly much greater than 300 mAh/g capacities. The processes include cooling the alloy during hydrogenation to reduced temperatures or by subjecting the materials to significantly increased hydrogen pressures. Temperatures in many embodiments do not exceed 300° C. By decreasing the temperature or increasing the hydrogen pressure the phase structure of the material is optimized to increase a synergistic effect between multiple phases in the resulting alloy thereby greatly improving the electrochemical capacities.