Patent classifications
C01B7/07
HYDROGEN CHLORIDE LOOP FUEL REACTION
A hydrogen chloride loop fuel reaction is designed and configured for turbine/generator combination which can be used for automotive propulsion or as a standalone electrical generation or for auxiliary equipment. A method for providing a hydrogen chloride loop fuel reaction includes creating hydrogen chloride fuel in a sealed furnace vessel, wherein at start up, the sealed furnace vessel is vacuumed out and hydrogen and chlorine are injected into a burner and ignited resulting in the hydrogen chloride fuel in an exhaust stream of the sealed furnace vessel; and looping the hydrogen chloride fuel leaving the sealed furnace vessel in the exhaust stream of the sealed furnace vessel.
METHOD AND SYSTEM FOR PRODUCING HIGH-PURITY HYDROGEN CHLORIDE
The present invention provides a method for producing high-purity hydrogen chloride, comprising the steps of: purifying each of crude hydrogen and crude chlorine as raw materials to a purity of 99.999% or higher; reacting an excessive molar amount of the purified hydrogen with the purified chlorine at a temperature ranging from 1,200° C. to 1,400° C. to synthesize hydrogen chloride; converting the hydrogen chloride to a liquid state by compression; and purifying the hydrogen chloride and separating unreacted hydrogen by fractional distillation. The invention also provides a system for carrying out the method. According to the method and system, an environmentally friendly production process can be provided, which can easily produce a large amount of hydrogen chloride having a purity of 3 N (99.9%)−6 N (99.9999%) in a cost-effective manner and enables energy consumption to be significantly reduced.
Method for flexibly controlling the use of hydrochloric acid from chemical production
The invention relates to a method for flexibly controlling the use of hydrochloric acid having an HCl concentration of at least 10 wt %, in particular at a volume flow rate of at least 1 m.sup.3/h, obtained from a continuous chemical production process (A). In the method, purified hydrochloric acid (54) from a hydrochloric acid store (E) is optionally fed to a dispatch station (H), an HCl electrolysis station (F) and a chloralkali electrolysis station (L), which are consumption points for the hydrochloric acid, or to a neutralisation station (G) in that if one or more of said consumption points (H, F, L) is not available or if there are bottlenecks at the consumption points (H, F, L), the hydrochloric acid (54) is fed to the neutralisation station (G) and neutralised with concentrated alkali solution (55), in particular with concentrated sodium hydroxide solution, and the resulting salt solution (56) is fed either to the chloralkali process station (L) or to a disposal station (M).
Method and device for the continuous neutralization of hydrochloric acid
Disclosed is a method and a device for the continuous neutralization of hydrochloric acid at an industrial scale.
A METHOD AND AN APPARATUS FOR SEPARATING CHLORINE GAS FROM A GASEOUS ANODE OUTLET STREAM OF AN ELECTROCHEMICAL REACTOR
The invention relates to a method for separating chlorine from a gaseous anode outlet stream mass flow of an electrochemical cell reactor. In a first aspect, the method makes use of an absorption step, wherein an anode outlet stream mass flow of the electrochemical cell reactor is exposed to an organic solvent being essentially immiscible with water for achieving an exergy-efficient separation of chlorine and hydrogen chloride. In a further aspect, the method makes use of absorption step, wherein the anode outlet stream mass flow is exposed to an ionic liquid, wherein the hydrogen chloride is dissolved in said ionic liquid, thereby forming a gas flow containing essentially chlorine and a solution mass flow comprising the ionic liquid and the hydrogen chloride. The hydrogen chloride is desorbed from the solution mass flow in a desorption step. In another aspect, the method makes use of a distillation step, wherein the anode outlet stream mass flow is separated at a static pressure of at least 2 bar for an exergy-efficient separation.
STORAGE MEDIUM AND METHOD FOR SEPARATING, STORING AND TRANSPORTING CHLORINE FROM CHLORINE-CONTAINING GASES
The invention relates to a storage medium and to a method for using a storage medium based on ionic compounds, which can reversibly absorb and store chlorine and chlorine from process gases, and which can release the same again by changing the ambient conditions, wherein the storage medium can be reused for this task after discharge.
Process for making horizontally-aligned epoxy graphene material
A method includes depositing graphene into a hardener, mixing the hardener and the graphene to produce a homogeneous composite mixture, adding a resin material to the composite mixture to produce an epoxy graphene material, coating a structure with the epoxy graphene material, aligning the graphene sheets in the in-plane orientation, and curing the epoxy graphene material.
PYROLYTIC EXTRACTION OF HYDROCHLORIC ACID FROM MAGNESIUM SALT MIXTURES, ESPECIALLY BITTERNS
Processes are provided which pyrolytically extract hydrochloric acid from a magnesium ion-rich salt mixture. In this regard, a supply of the magnesium ion-rich salt mixture (e.g., bittern) may be directed to a pyrolytic chamber where it is contacted with heated gas (e.g., combustion flue gas) at a sufficient temperature and for a sufficient time to form a vapor product stream comprised of hydrochloric acid and an insoluble pyrolyzed mixed salt stream comprised of magnesium hydroxide and sodium sulfate decahydrate. The solid pyrolyzed mixed salt stream may be separated into separate product streams comprising the insoluble magnesium hydroxide and remaining soluble salt fractions, while the vapor product stream of hydrochloric acid from the pyrolytic chamber may be condensed form an aqueous HCl solution. The magnesium ion rich salt mixture may be dehydrated prior to pyrolysis to achieve magnesium ions in a tetrahydrate state or lower (e.g., a monohydrate to a trihydrate state).
HYDROGEN CHLORIDE MIXTURE, METHOD FOR PRODUCING THE SAME, AND FILLING CONTAINER
A method for producing a hydrogen chloride mixture containing hydrogen chloride and water, the method including: a first dehydration step of cooling a hydrogen chloride mixture in which a concentration of water is 1 mol ppm or more, to condense and separate water in the hydrogen chloride mixture; a second dehydration step of bringing a hydrogen chloride mixture obtained in the first dehydration step into contact with a water adsorbent to allow a concentration of water to be less than 0.5 mol ppm; and a filling step of filling a filling container with a hydrogen chloride mixture obtained in the second dehydration step so that at least a part of the hydrogen chloride mixture is liquid, and a concentration of water in a liquid phase at a time of completion of the filling is 0.01 mol ppm or more and less than 1 mol ppm.
Process for providing hydrogen chloride for chemical reactions
The invention relates to an improved process for making available the coproduct hydrogen chloride obtained in the preparation of an isocyanate by phosgenation of the corresponding amine for a desired subsequent use (i.e. a chemical reaction), in which part of the total hydrogen chloride obtained is isolated in gaseous form at a pressure which is higher than the pressure desired for the subsequent use of the hydrogen chloride by lowering the pressure of the crude product from the phosgenation and the remaining part of the total hydrogen chloride obtained is separated off at a pressure lower than that desired for the subsequent use from the liquid crude product from the phosgenation remaining after lowering of the pressure and is subsequently compressed to a pressure which is higher than that desired for the subsequent use, and in which the two hydrogen chloride streams obtained in this way are, preferably together after having been combined, purified so as to give a purified hydrogen chloride at a pressure which is higher than the pressure desired for the subsequent use.