A process for treating an ammonium fluorosulfate byproduct includes providing an ammonium fluorosulfate byproduct including primarily ammonium fluorosulfate and lesser amounts of fluorosulfonic acid and bis(fluorosulfonyl) imide, mixing the ammonium fluorosulfate byproduct with water, reacting the mixture of the ammonium fluorosulfate byproduct and the water at a hydrolysis reaction temperature to hydrolyze the ammonium fluorosulfate, the fluorosulfonic acid and the bis(fluorosulfonyl) imide to form ammonium bisulfate and aqueous hydrogen fluoride; and separating the ammonium bisulfate from the aqueous hydrogen fluoride.

A process for treating an ammonium fluorosulfate byproduct includes providing an ammonium fluorosulfate byproduct including primarily ammonium fluorosulfate and lesser amounts of fluorosulfonic acid and bis(fluorosulfonyl) imide, mixing the ammonium fluorosulfate byproduct with water, reacting the mixture of the ammonium fluorosulfate byproduct and the water at a hydrolysis reaction temperature to hydrolyze the ammonium fluorosulfate, the fluorosulfonic acid and the bis(fluorosulfonyl) imide to form ammonium bisulfate and aqueous hydrogen fluoride; and separating the ammonium bisulfate from the aqueous hydrogen fluoride.

The present invention relates to a high purity synthetic fluorite (CaF.sub.2). The present invention further relates to a process and an apparatus for preparing said high purity synthetic fluorite (CaF.sub.2), classified as acid grade, starting from fluorosilicic acid H.sub.2SiF.sub.6 (FSA) and calcium carbonate (CaCO.sub.3). Finally, the present invention relates to the use of said high purity synthetic fluorite (CaF.sub.2) in the industrial production of hydrofluoric acid.

The present invention is directed to a process for producing a molded polymeric article including: providing a polymerizable composition of a reaction mixture of at least the following components: a mold release agent of ionic fluoride and/or ionic fluoride precursor, and a polymeric organic material selected from thermosetting organic polymeric materials and thermoplastic organic materials; allowing the reaction mixture to undergo exothermic reaction; providing a mold having a first part and a second part spaced one from the other thereby forming a cavity there between; introducing the reaction mixture into the mold cavity wherein the reaction mixture is at a temperature of up to 130 C.; holding the mold at a temperature and for a time sufficient to cure the reaction mixture thereby forming a molded polymeric article within the mold; and removing the molded polymeric article from the mold.

Molded articles also are provided.

The present invention relates to processes for producing fluorine-containing compounds by means of precipitation reactions from solutions containing fluoride ions wherein the pH value is determined using an electrochemical measuring chain and to electrochemical measuring chains for determining pH values.

The present invention relates to a high purity synthetic fluorite (CaF.sub.2). The present invention further relates to a process and an apparatus for preparing said high purity synthetic fluorite (CaF.sub.2), classified as acid grade, starting from fluorosilicic acid H.sub.2SiF.sub.6 (FSA) and calcium carbonate (CaCO.sub.3). Finally, the present invention relates to the use of said high purity synthetic fluorite (CaF.sub.2) in the industrial production of hydrofluoric acid.

In particular, in alternative embodiments, the invention provides for a method to recover silicofluoride and phosphate species from wastewaters, or barometric condenser waters, that are typically utilized in wet-process phosphoric acid facilities. The species are recovered via a continuous ion exchange approach that allows for economic recovery of the materials and especially with the silicofluoride component allows for the production of valuable industrial materials such as hydrofluoric acid and other fluoride salts as well as industrial-grade precipitated silica materials. Return of the treated waste water to the phos-acid plant allows for optimization of reagent usage.

The present invention is directed to an organic polymerizable composition for producing a molded polymeric article. The composition includes a mold release agent of ionic fluoride and/or ionic fluoride precursor present in an amount sufficient to effect at least partial demolding of the polymeric article from a mold. Molded articles also are provided.