Patent classifications
C01C1/26
METHODS OF PRODUCING AMMONIUM BICARBONATE DURING THE PRODUCTION OF ORGANIC FERTILIZERS
Methods for producing a solid ammonium bicarbonate product that includes preparing an organic feedstock that contains at least one nitrogen compound by causing organic animal manure and/or organic food waste to undergo anaerobic digestion, removing solids from the organic feedstock to produce an organic liquid effluent that contains at least one of ammonium and ammonia, performing a distillation process on the organic liquid effluent to strip and concentrate a vapor mixture therefrom that contains ammonia, carbon dioxide, and water and cool the vapor mixture to produce a condensed solution containing ammonium bicarbonate and/or ammonium carbonate, contacting the condensed solution with carbon dioxide to cause an ammonium bicarbonate precipitate to form from the condensed solution, and performing an evaporation process on the ammonium bicarbonate precipitate to remove water therefrom and produce the dry, solid ammonium bicarbonate product.
METHODS OF PRODUCING AMMONIUM BICARBONATE DURING THE PRODUCTION OF ORGANIC FERTILIZERS
Methods for producing a solid ammonium bicarbonate product that includes preparing an organic feedstock that contains at least one nitrogen compound by causing organic animal manure and/or organic food waste to undergo anaerobic digestion, removing solids from the organic feedstock to produce an organic liquid effluent that contains at least one of ammonium and ammonia, performing a distillation process on the organic liquid effluent to strip and concentrate a vapor mixture therefrom that contains ammonia, carbon dioxide, and water and cool the vapor mixture to produce a condensed solution containing ammonium bicarbonate and/or ammonium carbonate, contacting the condensed solution with carbon dioxide to cause an ammonium bicarbonate precipitate to form from the condensed solution, and performing an evaporation process on the ammonium bicarbonate precipitate to remove water therefrom and produce the dry, solid ammonium bicarbonate product.
Process for the preparation of high purity alumina
A method for preparing high purity alumina (HPA) is provided. The method includes subjecting an aluminum feedstock to acid leaching, thereby yielding an aluminum bearing leachate; subjecting the aluminum bearing leachate to solvent extraction, thereby yielding an organic phase which is loaded with aluminum; stripping the aluminum from the loaded organic phase with a stripping solution containing an acid, thereby yielding an aluminum bearing extract; crystallizing an aluminum salt from the aluminum bearing extract; dissolving the aluminum salt in an ammoniacal solution, thereby generating a boehmite precursor compound and an ammonium salt; calcining the boehmite precursor compound to yield HPA; subjecting the ammonium salt to electro-dialysis, thereby yielding ammonia and the acid; and performing at least one step of (a) utilizing the ammonia in preparing the ammoniacal solution used in a subsequent iteration of the method, or (b) utilizing the acid in preparing the stripping solution used in a subsequent iteration of the method.
DHSV SCALE REMOVAL METHOD IN THE PRODUCTION STRING
The present invention addresses to a method of removing scale from the DHSV of the oil production string aiming at maintaining the production of the wells and thus avoiding the loss of production. First, a neutralizing solution is placed in the service line, before pumping the scale removing solution through the string to act on the DHSV. Next, the acid is pumped into the production string to react with the calcium carbonate scale. After the time for the dissolution of the scale inside the DHSV, the well is opened for production by the service line. The spent acid is mixed with the neutralizing solution inside the service line, reducing its corrosiveness in relation to the service line, contributing to its preservation.
Catalytic multi-reaction zone reactor system
The present invention is a production method for ammonia and ammonia derivatives in a Multi-Reaction Zone Reactor. Said production method comprising the steps of: a) producing at least some section of ammonia as a result of balance reaction of ammonia by means of nitrogen and hydrogen catalyst in at least one primary reaction zone (RZ-1), b) realizing absorption by means of chemical or physical absorbents of at least some section of ammonia which is in gas form and which is produced in primary reaction zone (RZ-1) in at least one secondary reaction zone (RZ-2) which is not separated by discrete physical barriers with the primary reaction zone (RZ-1).
Catalytic multi-reaction zone reactor system
The present invention is a production method for ammonia and ammonia derivatives in a Multi-Reaction Zone Reactor. Said production method comprising the steps of: a) producing at least some section of ammonia as a result of balance reaction of ammonia by means of nitrogen and hydrogen catalyst in at least one primary reaction zone (RZ-1), b) realizing absorption by means of chemical or physical absorbents of at least some section of ammonia which is in gas form and which is produced in primary reaction zone (RZ-1) in at least one secondary reaction zone (RZ-2) which is not separated by discrete physical barriers with the primary reaction zone (RZ-1).
Formic acid formation from a carbon dioxide source
The concerns a process for producing formic acid, (a) a carbon capture step in which a source of carbon dioxide is contacted with an amine solution in an amine scrubber, to obtain an ammonium bicarbonate solution, where the carbon capture uses a chilled amine solution having a temperature in the range of 0-20 ° C.; (b) inducing crystallization in the ammonium bicarbonate solution to obtain a concentrated ammonium bicarbonate solution; (c) subjecting the concentrated ammonium bicarbonate solution to a hydrogenation step to obtain an ammonium formate; and (d) heating the ammonium formate to a temperature in the range of 50-150 ° C., to obtain a gaseous product containing the amine and a liquid product stream containing formic acid. The application further concerns a system for performing the process.
Formic acid formation from a carbon dioxide source
The concerns a process for producing formic acid, (a) a carbon capture step in which a source of carbon dioxide is contacted with an amine solution in an amine scrubber, to obtain an ammonium bicarbonate solution, where the carbon capture uses a chilled amine solution having a temperature in the range of 0-20 ° C.; (b) inducing crystallization in the ammonium bicarbonate solution to obtain a concentrated ammonium bicarbonate solution; (c) subjecting the concentrated ammonium bicarbonate solution to a hydrogenation step to obtain an ammonium formate; and (d) heating the ammonium formate to a temperature in the range of 50-150 ° C., to obtain a gaseous product containing the amine and a liquid product stream containing formic acid. The application further concerns a system for performing the process.
Use of aqueous solution of organic ammonium carboxylate in preventing dusting of fine material and combination of an aqueous solution of organic ammonium carboxylate and fine material
The invention relate to use of aqueous solution of organic ammonium carboxylate of formula (I): [NR.sup.1R.sup.2R.sup.3R.sup.4].sup.+n[R.sup.5(COO)].sup.−n, in which R.sup.1, R.sup.2, and R.sup.3 are selected from the group composing of hydrogen and methyl, R.sup.4 is a C.sub.1-C.sub.4-alkyl substituted with a hydroxyl group, R.sup.5 is hydrogen or methyl and n is 1, as a mist or drops in preventing dusting of fine material and in lowering the freezing point of said aqueous solution on the surface of said fine material or on the surface of dust particles obtained from said fine material by spraying said mist or drops onto fine material or onto dust particles obtained from said fine material to neutralize negatively charged dust particles or by changing negatively charged dust particles into positively charged dust particles, wherein said fine material is selected from the group composing of sand, crushed stone, stone powder, crushed expanded clay, or crushed expanded clay aggregate, crushed cement or concrete, cement or concrete powder, chopped organic material, minerals and metal powder.
Process to recover ammonium bicarbonate from wastewater
The present invention is a process, a method, and system for recovery and concentration of dissolved ammonium bicarbonate from a wastewater containing ammonia (NH3) using gas separation, condensation, and crystallization, each at controlled operating temperatures. The present invention includes 1) removal of ammonia from waste (sludges, semi-solids, and solids and liquids) without the use of chemicals at a temperature of at least 80 degrees Celsius, 2) condensing the gaseous containing ammonia, carbon dioxide and water vapor to remove water vapor concentrating the amount of gaseous ammonia and carbon dioxide, 3) concentrating the ammonia and carbon dioxide in the water by established means, such as concentrating the gas using partial condensation followed by passing the concentrated gas through an absorption column at a temperature of between about 20 and 50 degrees Celsius to form dissolved ammonium carbonate and ammonium bicarbonate, or total condensation followed by dewatering using reverse osmosis, and 4) crystallizing concentrated dissolved ammonium carbonate and ammonium bicarbonate at a temperature of less than about 35 degrees Celsius to form solid ammonium bicarbonate and ammonium carbonate.