C01F17/17

Materials derived from coal using environmentally friendly solvents

In a first embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture, isolating a residue from the first mixture, forming a second mixture comprising the residue, and electrospinning the second mixture to form a carbon fiber precursor material. In a second embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a mixture comprising solids and a liquid fraction, separating and filtering the liquid fraction from the mixture, and isolating one or more compounds from the liquid fraction. In a third embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture comprising residues, exposing the first mixture to (a) an acid, (b) a solvent, or (c) both to form a second mixture, and isolating rare earth elements and rare earth element compounds.

Materials derived from coal using environmentally friendly solvents

In a first embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture, isolating a residue from the first mixture, forming a second mixture comprising the residue, and electrospinning the second mixture to form a carbon fiber precursor material. In a second embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a mixture comprising solids and a liquid fraction, separating and filtering the liquid fraction from the mixture, and isolating one or more compounds from the liquid fraction. In a third embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture comprising residues, exposing the first mixture to (a) an acid, (b) a solvent, or (c) both to form a second mixture, and isolating rare earth elements and rare earth element compounds.

METHODS FOR SEPARATION AND RECOVERY OF RARE EARTH ELEMENTS FROM AQUEOUS SOLUTIONS USING DIGLYCOLAMIDE DERIVATIVES

A method for extracting rare earth elements from aqueous solution, comprising: (i) acidifying an aqueous solution containing said rare earth elements with an inorganic acid to result in an acidified aqueous solution containing said rare earth elements and containing the inorganic acid in a concentration of 1-12 M, wherein said rare earth elements are selected from lanthanides, actinides, or combination thereof, and (ii) contacting the acidified aqueous solution with an aqueous-insoluble hydrophobic solution comprising a rare earth extractant compound dissolved in an aqueous-insoluble hydrophobic solvent to result in extraction of one or more of the rare earth elements into the aqueous-insoluble hydrophobic solution by binding of the rare earth extractant compound to the one or more rare earth elements, wherein the rare earth extractant compound has the following structure:

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provided that at least one of the conditions (a)-(d) applies.

Method for recovering scandium

A method for recovering scandium, by which scandium is able to be recovered from nickel oxide ore. The present invention comprises: a leaching step S1 for obtaining a leachate by leaching a nickel oxide ore containing scandium with use of sulfuric acid; a neutralization step by adding a neutralizing agent thereto; a sulfurization step by adding a sulfurizing agent to the post-neutralization solution; an ion exchange step by bringing the post-sulfurization solution into contact with a chelating resin; a dissolution step by obtaining a precipitate of scandium hydroxide by adding an alkali into the scandium eluent, and subsequently adding an acid solution to the scandium hydroxide; a solvent extraction step by bringing the scandium acid dissolution liquid into contact with a neutral extractant; and a scandium recovery step by adding oxalic acid to the extraction residue and subsequently roasting the salt of scandium oxalate.

Method for recovering scandium

A method for recovering scandium, by which scandium is able to be recovered from nickel oxide ore. The present invention comprises: a leaching step S1 for obtaining a leachate by leaching a nickel oxide ore containing scandium with use of sulfuric acid; a neutralization step by adding a neutralizing agent thereto; a sulfurization step by adding a sulfurizing agent to the post-neutralization solution; an ion exchange step by bringing the post-sulfurization solution into contact with a chelating resin; a dissolution step by obtaining a precipitate of scandium hydroxide by adding an alkali into the scandium eluent, and subsequently adding an acid solution to the scandium hydroxide; a solvent extraction step by bringing the scandium acid dissolution liquid into contact with a neutral extractant; and a scandium recovery step by adding oxalic acid to the extraction residue and subsequently roasting the salt of scandium oxalate.

PROCESSING OF TITANIFEROUS ORES AND MINERALS
20230312364 · 2023-10-05 ·

The present invention relates to metallurgical processes, and more particularly to a process for producing titaniferous feedstock and fines, a process for agglomerating titaniferous fines, and a process for producing titaniferous metals and titaniferous alloys. Recovery of rare-earth, vanadium and scandium from titanium iron bearing resources is also disclosed. Selective leaching for Scandium recovery from all magnetite type resources such as ilmenite, ferro titanic resources, nickel laterites, magnetite iron resources etc.

PROCESSING OF TITANIFEROUS ORES AND MINERALS
20230312364 · 2023-10-05 ·

The present invention relates to metallurgical processes, and more particularly to a process for producing titaniferous feedstock and fines, a process for agglomerating titaniferous fines, and a process for producing titaniferous metals and titaniferous alloys. Recovery of rare-earth, vanadium and scandium from titanium iron bearing resources is also disclosed. Selective leaching for Scandium recovery from all magnetite type resources such as ilmenite, ferro titanic resources, nickel laterites, magnetite iron resources etc.

Process for separating scandium from complex salt mixtures

A method of separating scandium from a feedstock wherein a scandium enriched solution is produced from the feedstock and the scandium enriched solution is extracted to produce an organic phase of the scandium enriched solution. The organic phase of the scandium enriched solution is re-extracted to produce an aqueous phase including scandium chloride. The aqueous phase is precipitated and calcinated to produce scandium oxide powder.

Process for separating scandium from complex salt mixtures

A method of separating scandium from a feedstock wherein a scandium enriched solution is produced from the feedstock and the scandium enriched solution is extracted to produce an organic phase of the scandium enriched solution. The organic phase of the scandium enriched solution is re-extracted to produce an aqueous phase including scandium chloride. The aqueous phase is precipitated and calcinated to produce scandium oxide powder.

PROCESS FOR THE SYNTHESIS OF THE IONIC LIQUID TETRAOCTYLAMMONIUM DI(2-ETHYLHEXYL)-OXAMATE (IL-5), PRODUCT OBTAINED AND ITS USE IN SELECTIVE METAL EXTRACTION

a) The present invention falls within the area of the synthesis of ionic liquids, namely it concerns a process of synthesis of the ionic liquid tetraoctylammonium di(2-ethylhexyl)-oxamate (IL-5) with a high degree of purity and its use in the extraction and selective separation of metals, namely lanthanides. Thus, it is the object of the present invention, a process for the synthesis of a pure ionic liquid using in its constitution only the elements carbon, hydrogen, oxygen and nitrogen (CHON), assuming itself as a “green” alternative in the recovery of metals, thus reducing the environmental impact in the way they are recovered, as well as the guarantee of a more efficient extraction of these metals.