A method for upgrading an ilmenite ore for yielding a high-TiO.sub.2-content titanium source by separating and removing an iron component from ilmenite (FeTiO.sub.3), which includes an oxidation step of oxidizing a starting ilmenite; after the oxidation step, a reduction step of reducing the treated ilmenite; and after the reduction step, an extraction step of dissolving the iron component with an acid, to thereby remove the iron component. Also disclosed is a production method for producing a high-TiO.sub.2-content titanium source, which includes upgrading an ilmenite ore as described above, and a high-TiO.sub.2-content titanium source produced through the production method.

The present invention relates to metallurgical processes, and more particularly to a process for producing titaniferous feedstock and fines, a process for agglomerating titaniferous fines, and a process for producing titaniferous metals and titaniferous alloys. Recovery of rare-earth, vanadium and scandium from titanium iron bearing resources is also disclosed. Selective leaching for Scandium recovery from all magnetite type resources such as ilmenite, ferro titanic resources, nickel laterites, magnetite iron resources etc.

The present disclosure broadly relates to a process for recovering vanadium, iron, titanium and silica values from vanadiferous feedstocks. More specifically, but not exclusively, the present disclosure relates to a metallurgical process in which vanadium, iron, titanium and silica values are recovered from vanadiferous feedstocks such as vanadiferous titanomagnetite, iron ores, vanadium slags and industrial wastes and by-products containing vanadium. The process broadly comprises digesting the vanadiferous feedstocks into sulfuric acid thereby producing a sulfation cake; dissolving the sulfation cake and separating insoluble solids thereby producing a pregnant solution; reducing the pregnant solution thereby producing a reduced pregnant solution; and crystallizing ferrous sulfate hydrates from the reduced pregnant solution, producing an iron depleted reduced solution. The process further comprises removing titanium compounds from the iron depleted reduced solution thereby producing a vanadium-rich pregnant solution; concentrating vanadium and recovering vanadium products and/or a vanadium electrolyte.

A hydroximic acid-metal hydroxide coordination complex and preparation and application thereof are disclosed. The hydroximic acid-metal hydroxide coordination complex is formed by a coordination of hydroximic acid with divalent or higher valent metal ions under an alkaline condition. The hydroximic acid-metal hydroxide coordination complex has a strong selectivity and a strong collection ability for metal oxide minerals such as tungsten-containing minerals, ilmenite, rutile, cassiterite, and rare earth. The preparation method is simple and low in costs, and is beneficial to industrialized production.

The invention relates to a method for treating a residue obtained from the chloride process, wherein the residue comprises the components titanium dioxide, coke, an inert metal oxide, and an iron-containing component. Further, the invention refers to the use of this method to separate the components contained in said residue, and to the use of the separated components in the chloride process for obtaining titanium dioxide.

The present invention provides a method for preparing a transparent free-standing titanium dioxide nanotube array film. In the method, with the titanium foil as a substrate, the titanium dioxide nanotube array film is obtained by anode oxidation on the surface of the titanium foil. Upon high temperature annealing, the titanium dioxide nanotube array film naturally falls off to obtain the transparent free-standing titanium dioxide nanotube array film. The method according to the present invention features simple operations, saves time and cost. With the method, a completely strippable titanium dioxide nanotube array film may be prepared, and in addition, morphology of the titanium dioxide nanotube is not damaged. The free-standing and complete titanium dioxide nanotube array film facilitates transfer and post-treatment, has the feature of transparency and may be in favor of the applications to the studies such as photocatalysis and the like.

Digestion of impure alumina with sulfuric acid dissolves all constituents except silica. Resulting sulfates, produced from contaminants in the impure alumina, remain in solution at approximately 90 C. Hot filtration separates silica. Solution flow over metallic iron reduces ferric sulfate to ferrous sulfate. Controlled ammonia addition promotes hydrolysis and precipitation of hydrated titania from titanyl sulfate that is removed by filtration. Addition of ammonium sulfate forms ferrous ammonium sulfate and ammonium aluminum sulfate solutions. Alum is preferentially separated by crystallization. Addition of ammonium bicarbonate to ammonium alum solution precipitates ammonium aluminum carbonate which may be heated to produce alumina, ammonia, and carbon dioxide. The remaining iron rich liquor also contains magnesium sulfate. Addition of oxalic acid generates insoluble ferrous oxalate which is thermally decomposed to ferrous oxide. Carbon monoxide reduces the ferrous oxide to metallic iron. Further oxalic acid addition precipitates magnesium oxalate which is thermally decomposed to magnesium oxide.

A chemical disinfection process for vehicles using chlorine dioxide and titanium dioxide with calculated re-treatment formulas and schedules based on bacterial infestation data. Systems and methods that include client devices and servers that monitor and control a chemical disinfection process. The system generates a surety arrangement that facilitates re-treatment and electronic notification alerts to chemical solution vendors, dealers and vehicle owners.

The present disclosure broadly relates to a process for recovering vanadium, iron, titanium and silica values from vanadiferous feedstocks. More specifically, but not exclusively, the present disclosure relates to a metallurgical process in which vanadium, iron, titanium and silica values are recovered from vanadiferous feedstocks such as vanadiferous titanomagnetite, iron ores, vanadium slags and industrial wastes and by-products containing vanadium. The process broadly comprises digesting the vanadiferous feedstocks into sulfuric acid thereby producing a sulfation cake; dissolving the sulfation cake and separating insoluble solids thereby producing a pregnant solution; reducing the pregnant solution thereby producing a reduced pregnant solution; and crystallizing ferrous sulfate hydrates from the reduced pregnant solution, producing an iron depleted reduced solution. The process further comprises removing titanium compounds from the iron depleted reduced solution thereby producing a vanadium-rich pregnant solution; concentrating vanadium and recovering vanadium products and/or a vanadium electrolyte.

A method is disclosed including: (a) use of sized respectively, ilmenite concentrates and leucoxene concentrates with less than 20% weight of minus 100 microns and titania slags in the 75 to 850 micron range containing minor alkaline oxides within the market limits for chloride TiO2 feedstocks; (b) oxidizing respectively the sized, ilmenite concentrates, leucoxene concentrates and titania slags by contacting with and oxygen containing gas at the temperature of at least of 850 C. for a period of at least 1.5 hours such that, a substantial portion of iron oxide are converted to the ferric state; (c) reducing respectively, the oxidized ilmenite concentrates, oxidized leucoxene concentrates and oxidized titania slags in a reducing atmosphere at a temperature of at least about 1150 C. for a period of at least 1 hour such that the ferric state iron oxides are converted to the metallic iron state; (d) Chlorination respectively, of the resulting oxidized and subsequently reducednamely treated, ilmenite concentrates, leucoxene concentrates and titania slags at a temperature of at least about 800 C., for a period of at least about 1 hour; (e) washing in water and drying respectively, the Upgraded chlorinated ilmenite concentrates, Upgraded chlorinated leucoxene concentrates and Upgraded chlorinated titania slags. The method produces respective products with high TiO2 content suitable for the chloride process of TiO2 pigment production and, ferric chloride condensate By-product suitable for the waste water and water treatment industry.