The invention provides for the orchestrated treatment of disparate fractions of a shale deposit to recover vanadium values, with distinct steps of beneficiation that together provide a combined vanadium-enriched concentrate amenable to subsequent combined steps of hydrometallurgical vanadium extraction.

The invention relates to sulfonated aminomethylated chelate resins, to a method for producing same, to the use thereof for obtaining and purifying metals, in particular rare earth metals, from aqueous solutions and organic liquids, and for producing highly pure silicon.

The present invention relates to metallurgical processes, and more particularly to a process for producing titaniferous feedstock and fines, a process for agglomerating titaniferous fines, and a process for producing titaniferous metals and titaniferous alloys. Recovery of rare-earth, vanadium and scandium from titanium iron bearing resources is also disclosed. Selective leaching for Scandium recovery from all magnetite type resources such as ilmenite, ferro titanic resources, nickel laterites, magnetite iron resources etc.

Provided are a selective recovery method of vanadium and cesium from a waste sulfuric acid vanadium catalyst by a hydrometallurgical method including water leaching, solid-liquid separation, vanadium solvent extraction, vanadium selective stripping, and cesium alum production, and a high-quality vanadium aqueous solution and cesium alum produced thereby.

Provided are a selective recovery method of vanadium and cesium from a waste sulfuric acid vanadium catalyst by a hydrometallurgical method including water leaching, solid-liquid separation, vanadium solvent extraction, vanadium selective stripping, and cesium alum production, and a high-quality vanadium aqueous solution and cesium alum produced thereby.

The present disclosure broadly relates to a process for recovering vanadium, iron, titanium and silica values from vanadiferous feedstocks. More specifically, but not exclusively, the present disclosure relates to a metallurgical process in which vanadium, iron, titanium and silica values are recovered from vanadiferous feedstocks such as vanadiferous titanomagnetite, iron ores, vanadium slags and industrial wastes and by-products containing vanadium. The process broadly comprises digesting the vanadiferous feedstocks into sulfuric acid thereby producing a sulfation cake; dissolving the sulfation cake and separating insoluble solids thereby producing a pregnant solution; reducing the pregnant solution thereby producing a reduced pregnant solution; and crystallizing ferrous sulfate hydrates from the reduced pregnant solution, producing an iron depleted reduced solution. The process further comprises removing titanium compounds from the iron depleted reduced solution thereby producing a vanadium-rich pregnant solution; concentrating vanadium and recovering vanadium products and/or a vanadium electrolyte.

The invention provides for the orchestrated treatment of disparate fractions of a shale deposit to recover vanadium values, with distinct steps of beneficiation that together provide a combined vanadium-enriched concentrate amenable to subsequent combined steps of hydrometallurgical vanadium extraction.

The present disclosure broadly relates to a process for recovering vanadium, iron, titanium and silica values from vanadiferous feedstocks. More specifically, but not exclusively, the present disclosure relates to a metallurgical process in which vanadium, iron, titanium and silica values are recovered from vanadiferous feedstocks such as vanadiferous titanomagnetite, iron ores, vanadium slags and industrial wastes and by-products containing vanadium. The process broadly comprises digesting the vanadiferous feedstocks into sulfuric acid thereby producing a sulfation cake; dissolving the sulfation cake and separating insoluble solids thereby producing a pregnant solution; reducing the pregnant solution thereby producing a reduced pregnant solution; and crystallizing ferrous sulfate hydrates from the reduced pregnant solution, producing an iron depleted reduced solution. The process further comprises removing titanium compounds from the iron depleted reduced solution thereby producing a vanadium-rich pregnant solution; concentrating vanadium and recovering vanadium products and/or a vanadium electrolyte.

A system for extracting vanadium from a leaching solution containing vanadium chromium silicon and for preparing vanadium pentoxide, and a method therefor, the system comprising, in sequence: an impurity removal system, an extraction system, a reverse-extraction and vanadium precipitation system, a washing system and a calcining system. The method comprises the following steps: removing silicon in a leaching solution by using a silicon removal agent, extracting most of the vanadium to an organic phase by using centrifugal extraction, reverse-extracting the vanadium of a vanadium-rich organic phase by using a mixed solution containing a basic solution and an ammonium salt, and precipitating ammonium metavanadate to obtain an ammonium metavanadate solid, washing and drying, and then calcining at a certain temperature to obtain a low chromium, low silicon, low aluminum and high-purity vanadium pentoxide product.

The present invention relates to a method for preparing high-purity vanadium pentoxide from vanadium-bearing shale by all-wet process. The technical solution is: the Gradient continuous leaching system of vanadium-bearing shale is used to wet activate and compound leach vanadium-bearing shale to obtain vanadium-containing acid leachate. The pH adjusting device of the vanadium-containing acid leachate is used to adjust the pH of vanadium-containing acid leaching leachate. The post-treatment solution is subjected to hydroxime countercurrent extraction after oxidation, and the raffinate returns to the water using in the wet activation and electrodialysis after neutralization, and the loaded organic phase is regenerated by countercurrent reduction stripping. The regenerated organic phase directly returns to hydroxime countercurrent extraction. The pH is adjusted for vanadium precipitation with chemical valence conversion, and the mother liquor after vanadium precipitation is incorporated into the vanadium-containing acid leachate, and the vanadium-containing hydroxide is oxidized and roasted to prepare vanadium pentoxide.