A method according to an embodiment is for recovering a valuable metal from a waste electrode material of a lithium secondary battery by using lithium carbonate. An anode-cathode mixed electrode material that has been separated by draining, crushing, screening, and sorting a waste lithium secondary battery is preprocessed. A precipitation operation performed by adding lithium carbonate (Li2CO3) to a metal melt acquired by performing sulfuric acid dissolution using sulfuric acid. A valuable metal such as nickel, cobalt, manganese, aluminum, and copper is recovered as a residue in the form of a carbonate composite, and a lithium sulfate (Li2SO4) aqueous solution including lithium is recovered as a filtrate.

A method according to an embodiment is for recovering a valuable metal from a waste electrode material of a lithium secondary battery by using lithium carbonate. An anode-cathode mixed electrode material that has been separated by draining, crushing, screening, and sorting a waste lithium secondary battery is preprocessed. A precipitation operation performed by adding lithium carbonate (Li2CO3) to a metal melt acquired by performing sulfuric acid dissolution using sulfuric acid. A valuable metal such as nickel, cobalt, manganese, aluminum, and copper is recovered as a residue in the form of a carbonate composite, and a lithium sulfate (Li2SO4) aqueous solution including lithium is recovered as a filtrate.

A method for manufacturing a cobalt based hydroxide carbonate compound having a malachite-rosasite mineral structure, comprising the steps of: providing an first aqueous solution comprising a source of Co, providing a second aqueous solution comprising Na.sub.2CO.sub.3, mixing both solutions in a precipitation reactor at a temperature above 70° C., thereby precipitating a cobalt based hydroxide carbonate compound whilst evacuating from the reactor any CO.sub.2 formed by the precipitation reaction, wherein the residence time of the compound in the reactor is between 1 and 4 hours, and recovering the cobalt based hydroxide carbonate compound. The cobalt based hydroxide carbonate compound is used as a precursor of a lithium cobalt based oxide usable as an active positive electrode material in lithium ion batteries.

The present disclosure discloses a preparation method of platy aluminum-doped cobalt carbonate and use thereof. The preparation method includes the following steps: S1: mixing a cobalt salt, an aluminum salt, and a polyhydroxy compound to prepare a mixed solution; S2: mixing the mixed solution with an ammonium bicarbonate solution, adjusting a pH, and heating and stirring to allow a reaction to obtain a seed crystal solution; and S3: adding the mixed solution and an ammonium bicarbonate solution to the seed crystal solution, adjusting a pH, and heating and stirring to allow a reaction, during which a solid content in a slurry is controlled at 20% to 40% until a particle size in the slurry grows to a target value; and separating out, washing, and drying a solid phase to obtain the platy aluminum-doped cobalt carbonate.

The present disclosure discloses a preparation method of platy aluminum-doped cobalt carbonate and use thereof. The preparation method includes the following steps: S1: mixing a cobalt salt, an aluminum salt, and a polyhydroxy compound to prepare a mixed solution; S2: mixing the mixed solution with an ammonium bicarbonate solution, adjusting a pH, and heating and stirring to allow a reaction to obtain a seed crystal solution; and S3: adding the mixed solution and an ammonium bicarbonate solution to the seed crystal solution, adjusting a pH, and heating and stirring to allow a reaction, during which a solid content in a slurry is controlled at 20% to 40% until a particle size in the slurry grows to a target value; and separating out, washing, and drying a solid phase to obtain the platy aluminum-doped cobalt carbonate.

Process for precipitating a carbonate or (oxy)hydroxide comprising nickel from an aqueous solution of a nickel salt wherein such process is carried out in a vessel comprising (A) a vessel body, (B) one or more elements that control the hydraulic flow of the slurry formed during the precipitation and that induce a loop-type circulation flow, and (C) a stirrer whose stirrer element is in the vessel but located separately from the element(s) (B).

Process for precipitating a carbonate or (oxy)hydroxide comprising nickel from an aqueous solution of a nickel salt wherein such process is carried out in a vessel comprising (A) a vessel body, (B) one or more elements that control the hydraulic flow of the slurry formed during the precipitation and that induce a loop-type circulation flow, and (C) a stirrer whose stirrer element is in the vessel but located separately from the element(s) (B).

A bimodal lithium transition metal oxide based powder mixture comprising a first and a second lithium transition metal oxide based powder. The first powder comprises a material A having a layered crystal structure comprising the elements Li, a transition metal based composition M and oxygen and has a particle size distribution with a span <1.0. The second powder has a monolithic morphology and a general formula Li.sub.1+bN.sub.1-bO.sub.2, wherein 0.03b0.10, and N=Ni.sub.xM.sub.yCo.sub.zE.sub.d, wherein 0.30x0.92, 0.05y0.40, 0.05z0.40 and 0d0.10, with M being one or both of Mn or Al, and E being a dopant different from M. The first powder has an average particle size D50 between 10 and 40 m. The second powder has an average particle size D50 between 2 and 4 m. The weight ratio of the second powder in the bimodal mixture is between 20 and 60 wt %.

A bimodal lithium transition metal oxide based powder mixture comprises a first and a second lithium transition metal oxide based powder. The first powder comprises particles of a material A comprising the elements Li, a transition metal based composition M and oxygen. The first powder has a particle size distribution characterized by a (D90D10)/D50<1.0. The second powder comprises a material B having single crystal particles, said particles having a general formula Li.sub.+bN.sub.bO.sub.2, wherein 0.03b0.10, and NNi.sub.xM.sub.yCo.sub.zE.sub.d, wherein 0.30x0.92, 0.05y0.40, 0.05z0.40 and 0d0.10, wherein M is one or both of Mn or Al, and E is a dopant different from M. The first powder has an average particle size D50 between 10 and 40 m. The second powder has a D50 between 2 and 4 m. The weight ratio of the second powder in the mixture is between 15 and 60 wt %.

A bimodal lithium transition metal oxide based powder mixture comprises a first and a second lithium transition metal oxide based powder. The first powder comprises particles of a material A comprising the elements Li, a transition metal based composition M and oxygen. The first powder has a particle size distribution characterized by a (D90D10)/D501.5. The second powder comprises a material B having single crystal particles, said particles having a general formula Li.sub.+bN.sub.bO.sub.2, wherein 0.03b0.10, and N=Ni.sub.xM.sub.yCo.sub.zE.sub.d, wherein 0.30x0.92, 0.05y0.40, 0.05z0.40 and 0d0.10, wherein M is one or both of Mn or Al, and E is a dopant different from M. The first powder has an average particle size D50 between 10 and 40 m. The second powder has a D50 between 2 and 4.5 m. The weight ratio of the second powder in the mixture is between 15 and 60 wt %.