The present invention relates to a process for the preparation of ruthenium(III) chloride (RuCl.sub.3) as well to a process for the purification of ruthenium(III) chloride (RuCl.sub.3) and a use of the process for the preparation or the purification of ruthenium(III) chloride (RuCl.sub.3).

An object of the invention is to provide a jig electrolytic stripper that can sufficiently remove palladium adhered to the current-conducting portion of a plating jig, that can remove palladium adhered to the insulating-material-coated portion of the jig, and that exhibits reduced erosion of the metal of the current-conducting portion of the jig. The jig electrolytic stripper comprises the following components (A) to (C): (A) at least one member selected from the group consisting of nitric acid and salts thereof, (B) at least one member selected from the group consisting of ammonia, ammonium salts, ethylene amine compounds, alkyl diamine compounds, and amino acids, and (C) a bromide.

The invention relates to sulfonated aminomethylated chelate resins, to a method for producing same, to the use thereof for obtaining and purifying metals, in particular rare earth metals, from aqueous solutions and organic liquids, and for producing highly pure silicon.

Extraction of platinum-group elements, e.g. Pd, by adsorption from acidic aqueous solutions, using chelating acrylic fibers having amidoxime substituents followed by recovery by elution with an HCl-thiourea solution. From about 10% to 100% of the acrylic fiber CN are converted to amidoxime by reaction with NH.sub.2OH (hydroxylamine) in H.sub.2O/MeOH solution in the range of 30° C.-90° C. for from 15 min to 72 hrs. The adsorptive loading of elements onto the fiber and the efficiency of elution therefrom is substantially 100%, in multiple cycles of adsorption/elution. The novel fiber/extraction process is rapid, lending it to a continuous recovery operation. A portion of the CN groups of may be converted to carboxylate groups by reaction with NaOH. Short lengths of fiber are loaded into a vertical column and the pregnant solution introduced. Upon breakthrough, the fibers may be eluted, washed and recycled hundreds of times without removal from the column.

An object of the invention is to provide a jig electrolytic stripper that can sufficiently remove palladium adhered to the current-conducting portion of a plating jig, that can remove palladium adhered to the insulating-material-coated portion of the jig, and that exhibits reduced erosion of the metal of the current-conducting portion of the jig. The jig electrolytic stripper comprises the following components (A) to (C): (A) at least one member selected from the group consisting of nitric acid and salts thereof, (B) at least one member selected from the group consisting of ammonia, ammonium salts, ethylene amine compounds, alkyl diamine compounds, and amino acids, and (C) a bromide.

A process for efficiently and economically recovering palladium from a colloidal suspension of tin and palladium involves the use of centrifugation to obtain a sediment enriched in tin and a centrifugate enriched in palladium. An aggregating agent is employed to enhance separation during centrifugation, and ion exchange may be employed to recover palladium from the centrifugate.

Extraction of platinum-group elements, e.g. Pd, by adsorption from acidic aqueous solutions, using chelating acrylic fibers having amidoxime substituents followed by recovery by elution with an HCl-thiourea solution. From about 10% to 100% of the acrylic fiber CN are converted to amidoxime by reaction with NH.sub.2OH (hydroxylamine) in H.sub.2O/MeOH solution in the range of 30° C.-90° C. for from 15 min to 72 hrs. The adsorptive loading of elements onto the fiber and the efficiency of elution therefrom is substantially 100%, in multiple cycles of adsorption/elution. The novel fiber/extraction process is rapid, lending it to a continuous recovery operation. A portion of the CN groups of may be converted to carboxylate groups by reaction with NaOH. Short lengths of fiber are loaded into a vertical column and the pregnant solution introduced. Upon breakthrough, the fibers may be eluted, washed and recycled hundreds of times without removal from the column.

Disclosed herein is a method of manufacturing a membrane electrode assembly (MEA) including directly depositing a liquid suspension containing a platinum precursor onto an ionically conductive membrane (e.g., proton-exchange membrane) that, when the platinum precursor deposit layer is reduced, provides a layer that will scavenge hydrogen that has diffused back through the membrane due to cell stack pressure differential.

A method for separating an amount of osmium from a mixture containing the osmium and at least one other additional metal is provided. In particular, method for forming and trapping OsO.sub.4 to separate the osmium from a mixture containing the osmium and at least one other additional metal is provided.

The present invention relates to a process for the preparation of ruthenium(III) chloride (RuCl.sub.3) as well to a process for the purification of ruthenium(III) chloride (RuCl.sub.3) and a use of the process for the preparation or the purification of ruthenium(III) chloride (RuCl.sub.3).