Patent classifications
C01P2004/45
POSITIVE ELECTRODE ACTIVE MATERIAL FOR AN ALL-SOLID-STATE LITHIUM-ION BATTERY, ELECTRODE AND ALL-SOLID-STATE LITHIUM-ION BATTERY
What is claimed is a positive electrode active material for an all-solid-state lithium-ion battery composed of particles containing crystals of a lithium metal composite oxide,
wherein the lithium metal composite oxide has a layered structure and contains at least Li and a transition metal, and wherein, in the particles, in pore physical properties obtained from nitrogen adsorption isotherm measurement and nitrogen desorption isotherm measurement at a liquid nitrogen temperature, the total pore volume obtained from a nitrogen adsorption amount when the relative pressure (p/p.sub.0) of an adsorption isotherm is 0.99 is less than 0.0035 cm.sup.3/g.
LITHIUM METAL COMPOSITE OXIDE, POSITIVE ELECTRODE ACTIVE SUBSTANCE FOR LITHIUM SECONDARY BATTERY, POSITIVE ELECTRODE FOR LITHIUM SECONDARY BATTERY, LITHIUM SECONDARY BATTERY, AND METHOD FOR PRODUCING LITHIUM METAL COMPOSITE OXIDE
A lithium metal composite oxide having a layered structure, including at least lithium and an element X, wherein:the element X is at least one element selected from the group consisting of Co, Mn, Fe, Cu, Ti, Mg, Al, W, Mo, Nb, Zn, Sn, Zr, Ga, V, B, Si, S and P; the lithium metal composite oxide contains single particles and satisfies all of requirements (1) to (5):(1): a volume-based 50% cumulative particle size D.sub.50 of the lithium metal composite oxide is 2 μm or more and 10 μm or less; (2): the single particles have, on at least a part of surfaces thereof, adhered fine particles, with the proviso that a maximum particle size of the adhered fine particles is smaller than a particle size of the single particles; (3): the particle size of the single particles is 0.2 to 1.5 times D.sub.50 of the lithium metal composite oxide; (4): a particle size of the adhered fine particles is 0.01 to 0.1 times the D.sub.50 of the lithium metal composite oxide; and (5): an average number of the adhered fine particles adhered per particle of the single particles is 1 or more and 30 or less as measured with respect to a range observable in an image obtained by scanning electron microscope.
CATHODE ACTIVE MATERIAL AND LITHIUM SECONDARY BATTERY COMPRISING SAME
The present exemplary embodiments relate to a positive electrode active material and a lithium secondary battery including the same. The positive active material for a lithium secondary battery according to an exemplary embodiment includes lithium metal oxide particles including lithium, nickel, cobalt, manganese and doping elements, and includes a first domain and a second domain inside the lithium metal oxide particles.
POSITIVE ELECTRODE ACTIVE MATERIAL FOR ALL-SOLID-STATE LITHIUM ION SECONDARY BATTERY, METHOD FOR PRODUCING THE SAME, AND ALL-SOLID-STATE LITHIUM ION SECONDARY BATTERY
A positive electrode active material for an all-solid-state lithium ion secondary battery, containing: a lithium-metal composite oxide particle having a niobium solid solution layer and a center other than the niobium solid solution layer; and a coating layer coating at least a part of a surface of the lithium-metal composite oxide particle and formed of a compound containing lithium and niobium, an average thickness of the coating layer is 2 nm or more and 1 μm or less, and an average thickness of the niobium solid solution layer is 0.5 nm or more and 20 nm or less.
Crumpled mesoporous MXene powders synthesized by acid-, base-, or salt-induced crumpling
The present disclosure describes a crumpled form of MXene materials, and methods of making and using these novel compositions.
Carbon-coated particles
Core particles produced in situ or introduced as preformed core particles are coated with a layer of carbon. Non-carbon as well as some carbon-based core materials can be utilized. The resulting carbon coated particles can find applications in rubber products, for instance as reinforcement for tire components.
Positive electrode active material and lithium secondary battery comprising the same
The present invention relates to a positive electrode active material which has the structural stability of a lithium composite oxide constituting a positive electrode active material and a lithium secondary battery including the same. The lithium composite oxide constituting the positive electrode active material according to the present invention is able to reduce the surface area and grain boundary of secondary particles having a side reaction with an electrolyte solution, thereby improving high-temperature stability and reducing gas generation caused by the positive electrode active material, and the structural stability of the lithium composite oxide may be improved using a cation-mixing layer covering the surface of a primary particle.
Method of controlling crystallographic arrangement in mesocrystals
The present invention relates to a method of controlling the arrangement of building block nanocrystals in iron oxide mesocrystals by controlling the type of surface ligand, the method including mixing an iron ion precursor and a surface ligand. The present invention can provide nanoparticles having different magnetic properties by controlling the crystallographic arrangement of building block nanocrystals in mesocrystals according to surface ligands.
Radio wave absorber
A radio wave absorber includes a base member, and a radio wave absorption film formed on the base member. The radio wave absorption film includes at least MTC-substituted ε-Fe.sub.2O.sub.3 and black titanium oxide. The MTC-substituted ε-Fe.sub.2O.sub.3 is a crystal belonging to the same space group as an ε-Fe.sub.2O.sub.3 crystal and expressed by ε-M.sub.xTi.sub.yCo.sub.yFe.sub.2−2y−xO.sub.3 where M is at least one element selected from the group consisting of Ga, In, Al, and Rh, 0<x<1, and 0<y<1.
Method of Preparing Positive Electrode Active Material Precursor for Lithium Secondary Battery, Positive Electrode Active Material Precursor, and Positive Electrode Active Material, Positive Electrode, and Lithium Secondary Battery Which are Prepared by Using the Precursor
A positive electrode active material precursor, a method of preparing the same, and a positive electrode active material, a positive electrode, and a lithium secondary battery prepared from the same. In some embodiments, a positive electrode active material precursor includes nickel, cobalt, and manganese, wherein the positive electrode active material precursor satisfies: Equation 1 (2.5≤C.sub.(100)/C.sub.(001)≤5.0) and Equation 2 (1.0≤C.sub.(101)/C.sub.(001)≤3.0), where C.sub.(001) is a crystalline size in a (001) plane, C.sub.(100) is a crystalline size in a (100) plane, and C.sub.(101) is a crystalline size in a (101) plane. The positive electrode active material precursor has particle growth of a (001) plane that is suppressed.