C01P2006/17

AQUEOUS ROUTE TO NITROGEN-DOPED MESOPOROUS CARBONS

A method for preparation of mesoporous nitrogen-doped carbon includes forming a composition by solubilizing a nitrogen-containing polymer in an aqueous solution of ZnCl.sub.2 and drying the aqueous solution, the method further includes heating the composition after drying to a temperature sufficiently high to carbonize the nitrogen-containing polymer to form the mesoporous nitrogen-doped carbon.

POSITIVE ELECTRODE ACTIVE MATERIAL FOR AN ALL-SOLID-STATE LITHIUM-ION BATTERY, ELECTRODE AND ALL-SOLID-STATE LITHIUM-ION BATTERY
20230052234 · 2023-02-16 ·

What is claimed is a positive electrode active material for an all-solid-state lithium-ion battery composed of particles containing crystals of a lithium metal composite oxide,

wherein the lithium metal composite oxide has a layered structure and contains at least Li and a transition metal, and wherein, in the particles, in pore physical properties obtained from nitrogen adsorption isotherm measurement and nitrogen desorption isotherm measurement at a liquid nitrogen temperature, the total pore volume obtained from a nitrogen adsorption amount when the relative pressure (p/p.sub.0) of an adsorption isotherm is 0.99 is less than 0.0035 cm.sup.3/g.

Method for producing silica aerogel blanket and apparatus for producing same
11554962 · 2023-01-17 · ·

Provided is a method for producing a silica aerogel blanket and an apparatus for producing the same, which are capable of easily controlling the physical properties of a silica aerogel blanket by separately injecting silica sol and a gelation catalyst to control gelation time, improving aerogel pore structure to be uniform and improving thermal insulation performance by sufficiently and uniformly impregnating the silica sol and the gelation catalyst into a blanket, reducing the loss of silica sol and gelation catalyst by allowing the silica sol and the gelation catalyst to pass on an ascending slope before gelation to remove any excessive silica sol and gelation catalyst exceeding an appropriate impregnation amount, and providing a silica aerogel blanket having less process trouble, and less dust.

TABLETED ALPHA-ALUMINA CATALYST SUPPORT

A tableted catalyst support, characterized by an alpha-alumina content of at least 85 wt.-%, a pore volume of at least 0.40 mL/g, as determined by mercury porosimetry, and a BET surface area of 0.5 to 5.0 m.sup.2/g. The tableted catalyst support is an alpha-alumina catalyst support obtained with high geometrical precision and displaying a high overall pore volume, thus allowing for impregnation with a high amount of silver, while exhibiting a surface area sufficiently large so as to provide optimal dispersion of catalytically active species, in particular metal species. The invention further provides a process for producing a tableted alpha-alumina catalyst support, which comprises i) forming a free-flowing feed mixture comprising, based on inorganic solids content, at least 50 wt.-% of a transition alumina; ii) tableting the free-flowing feed mixture to obtain a compacted body; and iii) heat treating the compacted body at a temperature of at least 1100° C., preferably at least 1300° C., more preferably at least 1400° C., in particular at least 1450° C., to obtain the tableted alpha-alumina catalyst support. The invention moreover relates to a compacted body obtained by tableting a free-flowing feed mixture which comprises, based on inorganic solids content, at least 50 wt.-% of a transition alumina having a loose bulk density of at most 600 g/L, a pore volume of at least 0.6 mL/g, as determined, and a median pore diameter of at least 15 nm. The invention moreover relates to a shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising at least 15 wt.-% of silver, relative to the total weight of the catalyst, deposited on the tableted alpha-alumina catalyst support. The invention moreover relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of the shaped catalyst body.

DLM-1 Molecular Sieve, Process for Preparing the Same, and Use Thereof
20230025198 · 2023-01-26 ·

A DLM-1 molecular sieve, a process for preparing the molecular sieve, and use thereof in treating an organic substance are provided. The DLM-1 molecular sieve is an Al-SBA-15 molecular sieve, and has a schematic chemical composition as represented by the formula “first oxide*second oxide”. The first oxide is silica, the second oxide is alumina, and the content by mass percent of alumina in the schematic chemical composition is 2% to 85%. The DLM-1 molecular sieve is suitable for the hydrodenitrogenation reaction of heavy distillate oil, and is favorable for improving the hydrodenitrogenation activity.

POROUS CARBON, AND POSITIVE ELECTRODE AND LITHIUM SECONDARY BATTERY COMPRISING SAME

Porous carbon particles, and a positive electrode active material and a lithium secondary battery including the same. This may improve the energy density of the lithium secondary battery by applying a porous electrode containing micropores and mesopores and having a uniform size distribution and shape as a positive electrode material.

Cerium- and zirconium-based mixed oxide

The invention relates to a mixed oxide composed of zirconium, cerium, lanthanum and at least one rare earth oxide other than cerium and lanthanum, having a specific porosity and a high specific surface area; to the method for preparing same and to the use thereof in catalysis.

Methods for preparing high-purity boehmite and porous gamma-alumina nano-powder

Disclosed are methods for preparing high-purity boehmite and porous gamma-alumina nano-powder, comprising: adding aluminum isopropoxide into water and stirring the aluminum isopropoxide added water, then adding aluminum hydroxide generated by hydrolysis of high-purity aluminum powder into that stirred water, stirring that aluminum hydroxide added water to obtain a mixed system; carrying out hydrothermal reaction on the mixed system, performing centrifuging, washing, drying and crushing to the reacted mixed system, obtaining high-purity boehmite; calcining the high-purity boehmite to obtain porous gamma (γ)-alumina nano-powder. By strictly controlling the addition of isopropanolic aluminum and the temperature as well as the duration of the hydrothermal reaction, the product boehmite γ-AlOOH obtains good character in terms of crystalline structure, purity, morphology and dispersion; γ-Al.sub.2O.sub.3 obtained after calcining remains basically the same morphology as that of boehmite powder with good powder dispersion and no major changes.

ALUMINA WITH A PARTICULAR PORE PROFILE

The present invention relates to an alumina with a particular pore profile and good thermal stability. This alumina is also characterized in that it has a high bulk density. The alumina has, after calcining in air at 1100° C. for 5 hours: a pore volume in the range of pores with a size of between 5 nm and 100 nm which is between 0.50 and 0.75 mL/g, more particularly between 0.50 and 0.70 mL/g; and a pore volume in the range of pores with a size of between 100 nm and 1000 nm which is less than or equal to 0.20 mL/g, more particularly less than or equal to 0.15 mL/g, or even less than or equal to 0.10 mL/g.

MOLDED BODY MADE OF OPAQUE QUARTZ GLASS AND METHOD FOR PRODUCING SAME

Producing a molded body made of opaque quartz glass includes providing SiO.sub.2 grains obtained by comminuting quartz glass having a purity of at least 99.9 wt % SiO.sub.2, forming a slurry containing a suspension liquid and the SiO.sub.2 grains and which has a total solids content, wet grinding the SiO.sub.2 grains in the slurry so as to form ground SiO.sub.2 grain particles, forming a porous green body from the slurry, and sintering the porous green body. To provide a low cost quartz glass, the wet grinding of the SiO.sub.2 grains takes place at least temporarily in the presence of SiO.sub.2 nanoparticles, the proportion of which in the total solids content of the slurry is in the range of 0.1 wt % to 10 wt %, and the slurry has a solids content in the range of 76 to 80 wt % after addition of the SiO.sub.2 nanoparticles and after the wet grinding.