The present invention relates to a process for selectively removing a first charged species from a plurality of charged species in solution, which process comprises: treating a solution with a functionalised polymer and a surfactant, wherein the solution comprises a plurality of charged species dissolved in a solvent, wherein the plurality of charged species comprises the first charged species and at least one further charged species which is different from the first charged species, and wherein the functionalised polymer comprises groups that bind preferentially to the first charged species.

The present invention relates to a process for selectively removing a first charged species from a plurality of charged species in solution, which process comprises: treating a solution with a functionalised polymer and a surfactant, wherein the solution comprises a plurality of charged species dissolved in a solvent, wherein the plurality of charged species comprises the first charged species and at least one further charged species which is different from the first charged species, and wherein the functionalised polymer comprises groups that bind preferentially to the first charged species.

Solid-supported trithiol compounds are prepared. The solid-supported trithiol compounds have formula (I): ##STR00001##
in which R is a linker moiety, X is a solid support, and n≧1. The compounds of formula (I) may be incorporated into methods for removing heavy metals from solutions and into batch systems or filtration apparatus that remove heavy metals from solutions.

Disclosed is a water-insoluble polymeric iron chelating agent having a polymer backbone and an aromatic ring attached to the polymer backbone through an —NH—CH.sub.2— bond, wherein the aromatic ring has one or two first functional groups in the form of hydroxyl group and one or two second functional groups located at the ortho position with respect to the first functional group; and wherein the second functional group is —OH, —COOH, or a group represented by formula (I) wherein A represents —CH.sub.3, —CH.sub.2—CH.sub.3, —CH.sub.2—C.sub.6H.sub.5, —CH.sub.2—C.sub.5H.sub.4N or —CH.sub.2—COOH and B represents —CH.sub.2—COOH. The water-insoluble polymeric iron chelating agent of the present invention offers the advantages of being capable of selectively chelating iron ions, particularly biologically unstable iron, and being insoluble in water, and moreover not being incorporated in metabolic processes in vivo.

Disclosed is a water-insoluble polymeric iron chelating agent having a polymer backbone and an aromatic ring attached to the polymer backbone through an —NH—CH.sub.2— bond, wherein the aromatic ring has one or two first functional groups in the form of hydroxyl group and one or two second functional groups located at the ortho position with respect to the first functional group; and wherein the second functional group is —OH, —COOH, or a group represented by formula (I) wherein A represents —CH.sub.3, —CH.sub.2—CH.sub.3, —CH.sub.2—C.sub.6H.sub.5, —CH.sub.2—C.sub.5H.sub.4N or —CH.sub.2—COOH and B represents —CH.sub.2—COOH. The water-insoluble polymeric iron chelating agent of the present invention offers the advantages of being capable of selectively chelating iron ions, particularly biologically unstable iron, and being insoluble in water, and moreover not being incorporated in metabolic processes in vivo.

A process for purifying a diaryl carbonate, comprises introducing an aqueous stream to a diaryl carbonate stream that comprises a metal contaminant, wherein the aqueous stream reacts with the metal contaminant to form a precipitate; wherein introducing the aqueous stream to the diaryl carbonate stream results in introducing 100 to 10,000 ppm water based on the total composition of the diaryl carbonate stream and the aqueous stream; removing the precipitate via one or both of a separation column and a filter to result in a purified diaryl carbonate.

A process for purifying a diaryl carbonate, comprises introducing an aqueous stream to a diaryl carbonate stream that comprises a metal contaminant, wherein the aqueous stream reacts with the metal contaminant to form a precipitate; wherein introducing the aqueous stream to the diaryl carbonate stream results in introducing 100 to 10,000 ppm water based on the total composition of the diaryl carbonate stream and the aqueous stream; removing the precipitate via one or both of a separation column and a filter to result in a purified diaryl carbonate.

The present disclosure discloses an efficient and regenerable nano manganese remover, and a method for preparing same and application thereof, belonging to the technical field of wastewater treatment and reuse. The manganese remover of the present disclosure includes Fe.sub.3O.sub.4, RGO, SiO.sub.2 and EDTA. The Fe.sub.3O.sub.4 nanoparticles are supported on the surface of the RGO, the SiO.sub.2 coats the Fe.sub.3O.sub.4, and the EDTA is grafted on the SiO.sub.2. First, Fe.sub.3O.sub.4-RGO is prepared. Then, a TEOS-ethanol solution is dropwise added, and the resulting mixture is allowed to react to obtain Fe.sub.3O.sub.4@SiO.sub.2-RGO composite particles. Finally, an EDTA-water solution is dropwise added to obtain the manganese remover. The manganese remover prepared in the present disclosure is magnetic, and the preparation process is simple and easy for industrial production. The nano manganese remover can quickly remove manganese in manganese-containing wastewater. A small amount of the manganese remover can achieve a large adsorption capacity. Further, the nano manganese remover can be separated from the manganese-containing wastewater quickly, thereby avoiding secondary pollution to the system.

The present disclosure discloses an efficient and regenerable nano manganese remover, and a method for preparing same and application thereof, belonging to the technical field of wastewater treatment and reuse. The manganese remover of the present disclosure includes Fe.sub.3O.sub.4, RGO, SiO.sub.2 and EDTA. The Fe.sub.3O.sub.4 nanoparticles are supported on the surface of the RGO, the SiO.sub.2 coats the Fe.sub.3O.sub.4, and the EDTA is grafted on the SiO.sub.2. First, Fe.sub.3O.sub.4-RGO is prepared. Then, a TEOS-ethanol solution is dropwise added, and the resulting mixture is allowed to react to obtain Fe.sub.3O.sub.4@SiO.sub.2-RGO composite particles. Finally, an EDTA-water solution is dropwise added to obtain the manganese remover. The manganese remover prepared in the present disclosure is magnetic, and the preparation process is simple and easy for industrial production. The nano manganese remover can quickly remove manganese in manganese-containing wastewater. A small amount of the manganese remover can achieve a large adsorption capacity. Further, the nano manganese remover can be separated from the manganese-containing wastewater quickly, thereby avoiding secondary pollution to the system.

A process for treating acid mine drainage removes iron ions from the acid mine drainage in the form of zero-valent iron nanoparticles which can be subsequently used for environmental remediation.