Techniques and systems for neutralizing discharge waters from ballast and/or cooling water biocidal treatment and disinfection systems are provided. The systems utilize, inter alia, oxidation reduction potential control to regulate the dechlorination of an electrocatalytically generated biocidal agent to allowable discharge levels in ship buoyancy systems and ship cooling water systems.

In one aspect, composite particles are described herein. A composite particle comprises a substrate, composite metallic or metal oxide nanoparticles supported by the substrate and an amphiphilic or hydrophilic component associated with the substrate, wherein the composite metallic or metal oxide nanoparticles comprise iron and at least one additional transition metal.

A method for reducing nitrates, nitrites, and/or hydroxylamine in water using a homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex. The method includes dissolving a copper(II) tetra-substituted fluorinated pinacolate ligand pre-catalyst complex in water having an excess amount of nitrates, nitrites, and/or hydroxylamine therein. The dissolved copper(II) tetra-substituted fluorinated pinacolate ligand pre-catalyst complex in the water is subjected to electrochemical reduction to form a homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex. The homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex reduces the nitrates, nitrites, and/or hydroxylamine in the water to compounds with nitrogen in a lower oxidation state with the homogeneous reduced copper tetra-substituted fluorinated pinacolate ligand catalyst complex.

The present application relates to a novel method for reductive degradation of perfluoroalkyl-containing compounds, such as perfluoroalkyl sulfonates, by activated carbon (AC) supported zero valent iron-nickle nanoparticles (nNi.sup.0Fe.sup.0).

A filter for a liquid purifier, comprising: a filter housing having an inlet to receive water and an outlet to discharge the water; and a filter module provided in the filter housing, and configured to purify water introduced through the inlet, and to provide the purified water to the outlet, wherein the filter module includes a carbon block having a hollow tube shape by mixing activated carbon, a binder, ferric hydroxide, and titanium oxide, and the binder is mixed at a ratio of 13% to 23% by weight.

Catalyst materials comprising iron and palladium are described. Also described are methods for preparing such materials. In addition, methods for remediating materials such as sediments and groundwater using the catalyst materials are described.

A composition for remediation of soil and groundwater containing halogenated compounds. The remediation composition includes an elemental iron-based composition, which may include activated carbon capable of absorbing the halogenated compounds with numerous pores impregnated with elemental iron. The remediation composition further includes a first bioremediation material including a blend of one-to-many organisms capable of degrading the halogenated compounds. The remediation composition includes an organic compound or polymeric substance and a second bioremediation material including a blend of one-to-many organisms capable of degrading the organic compound or polymeric substance over time (e.g., 20 to 365 or more days to provide a time release substrate-creating material or platform) into smaller molecules or compounds used by the organisms in the first bioremediation material while degrading the halogenated compounds. The organic compound may be a complex carbohydrate such as food grade starch, chitin, or other complex carbohydrate such as one with low water solubility.

The invention is about a stabilized electromagnetic base liquid, as well as its preparation method and its application in the high-salt wastewater treatment. The raw material components of the electromagnetic base fluid include: 20-30 parts of alkali metal hydroxides(e.g., as sodium hydroxide); 20-30 parts of non-alkali metal (e.g., as silicon or phosphorus); 2-6 parts of ammonia; 31-140 parts of water; after treatment with a direct electrical current the parameters of the stabilized electromagnetic base liquid are: pH value: 12 to 14; oxidation reduction potential value: −1.0 to −1.8 v; with no corrosivity, confirming the presence of stabilized hydrated electrons (e.sub.aq−−). With the stabilized electromagnetic base liquid, the storage problem of the electromagnetic base liquid is solved, and the large-scale application in the industrial field can be realized, thereby achieving a large-scale high-salt wastewater treatment process with low cost, high recovery rate.

A preparation method and application of a zero-valent aluminum/iron-bearing clay composite for catalyzing a persulfate to oxidize organics are provided, which belongs to the field of water environmental treatment. A novel catalyst is prepared by an iron-bearing clay and a zero-valent aluminum through a simple ball milling method, for achieving the effect of activating a persulfate to efficiently oxidize and degrade refractory organics in water. The preparation method and operation process thereof are simple. Compared with a chemical synthesis method, the method of the present disclosure brings about less secondary pollution, and has a shorter synthesis time, higher yield and lower cost. The modified material is the natural iron-bearing clay, which is widely available, non-toxic and stable as a heterogeneous catalyst.

The presently disclosed subject matter is generally directed to a system and method of reducing, reacting, and/or removing an oxidant or unwanted chemical species from a chemical stream. Particularly, the system and method include the use of one or more reductants that react with the undesired chemical species. The reductant and the chemical stream are added to a reactor and allowed to react for a desired amount of time. The reductant will reduce, react with, and/or remove the chemical species from the stream. The excess reductant and reaction products are then removed from the reactor, as described in more detail herein below.