Methods of passively sampling PFAS in the environment, PFAS sorbents, apparatus and systems (apparatus plus conditions) for sampling groundwater, porewater, and surface water are described.

There is disclosed a method of improving water quality, the method comprising adding a pool of isolated Daphnia to a body of water such that the pool of isolated Daphnia is exposed to one or more contaminants which may be in the water. The pool of isolated Daphnia comprise Daphnia which have been resurrected from dormant Daphnia. The pool of isolated Daphnia are allowed to filter from the body of water at least a portion of said one or more contaminants to reduce the level of the one or more contaminants in the body of water. After a period of time, at least a portion of the Daphnia containing said one or more contaminants are removed from the body of water, thereby improving the water quality of the body of water.

Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H.sub.2O.sub.2 and .Math.OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe.sup.3+ and 5 to 15% wt. Cu.sup.2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .Math.OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H.sub.2O.sub.2 to .Math.OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.

A filter medium of the present invention includes a porous carbon material having a value of a specific surface area by a nitrogen BET method of 1×10.sup.2 m.sup.2/g or more, a volume of fine pores by a BJH method of 0.3 cm.sup.3/g or more, and a particle size of 75 μm or more, alternatively, a porous carbon material having a value of a specific surface area by a nitrogen BET method of 1×10.sup.2 m.sup.2/g or more, a total of volumes of fine pores having a diameter of from 1×10.sup.−9 m to 5×10.sup.−7 m, obtained by a non-localized density functional theory method, of 1.0 cm.sup.3/g or more, and a particle size of 75 μm or more.

A magnet band for production of magnetized water according to an embodiment of the present disclosure is easy to carry and convenient to use so that a user can easily magnetically activate and drink a beverage, and has a structure with reduced production cost so that many people can inexpensively and widely use the magnet band.

Use of Keplerate type polyoxomolybdates of the general structure Mo.sub.72M.sub.30, wherein M is selected from the group consisting of Fe, Cr, V or Mo.sub.2, for decontaminating aqueous media (water) from inorganic and organic pollutants.

The present invention refers to an industrial process and system that is efficient and advantageous for inactivation of liquid wastes contaminated by mutagenic, genotoxic and/or teratogenic substances arising from high potency APIs production using inactivation chemical agents and excluding ozone, heat or UV light source.

Recombinant MlrA and MlrB proteins having enzymatic activity against microcystin (MC) degrade and reduce the toxicity of MC. Compositions of the proteins can be used in the remediation of MC toxin generated from harmful cyanobacterial and algal blooms. Recombinant proteins, nucleic acids, host cells, and methods of producing the MlrA and MlrB are disclosed.

A nucleophilic substitution reaction to crosslink cyclodextrin (CD) polymer with rigid aromatic groups, providing a high surface area, mesoporous CD-containing polymers (P-CDPs). The P-CDPs can be used for removing organic contaminants from water. By encapsulating pollutants to form well-defined host-guest complexes with complementary selectivities to activated carbon (AC) sorbents. The P-CDPs can rapidly sequester pharmaceuticals, pesticides, and other organic micropollutants, achieving equilibrium binding capacity in seconds with adsorption rate constants 15-200 times greater than ACs and nonporous CD sorbents. The CD polymer can be regenerated several times, through a room temperature washing procedure, with no loss in performance.

Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H.sub.2O.sub.2 and .OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe.sup.3+ and 5 to 15% wt. Cu.sup.2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H.sub.2O.sub.2 to .OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.