The invention discloses a composite with an adsorption-visible light catalytic degradation synergistic effect and a preparation method and application thereof. The preparation method includes the specific steps that firstly, a bismuth oxyiodide/bismuth oxychloride composite nano-particle loaded activated carbon fiber composite ACF@BiOI.sub.xCl.sub.1-x is synthesized; then, the fiber surface is grafted with polyethyleneimine, and the end composite PEI-g-ACF@BiOI.sub.xCl.sub.1-x is obtained. The composite can rapidly adsorb pollutants in water, and meanwhile the pollutants are efficiently degraded with a photocatalyst loaded on the surface of the composite; besides, the purpose of recycling and reusing the photocatalyst is achieved, the comprehensive treatment capability of the composite is improved, the service life of the composite is prolonged, and the use cost is lowered.

An efficient photocatalyst nanocomposite comprising reduced graphene oxide, noble metal, and a metal oxide prepared by a one-step method that utilizes date seed extract as a reducing and nanoparticle determining size agent. The photocatalyst of the invention is a more effective sunlight photocatalyst than that prepared by traditional method in the photo decomposition of organic compounds in contaminated water.

Cross-linked polyvinyl polymers comprising charged groups and methods of making are disclosed. The polymers are effective and durable adsorbent of dyes from aqueous solutions. Also, a method of removal of dyes from contaminated water is disclosed.

The invention relates to a water insoluble solid crosslinked dextrin-based matrix, wherein the crosslinking agent is sodium trimetaphosphate (STMP), its use and method of preparation.

A composite nanomaterial of ZnO impregnated by, e.g., a green copper phthalocyanine compound (CuPc) can be an efficient solar light photocatalyst for water remediation. The composite may include hollow shell microspheres and hollow nanospheres of CuPc-ZnO. CuPc may function as a templating and/or structure modifying agent, e.g., for forming hollow microspheres and/or nanospheres of ZnO particles. The composite can photocatalyze the degradation of organic pollutants such as crystal violet (CV) and 2,4-dichlorophenoxyacetic acid as well as microbes in water under solar light irradiation. The ZnO-CuPc composite can be stable and recyclable under solar irradiation.

Disclosed is a multifunctional continuous hydrothermal oxidation experiment system, comprising a reactor (12), wherein an inlet of the reactor (12) is connected in parallel with an oxidant pipeline and a material pipeline; the oxidant pipeline comprises a gas oxidant delivery pipe and a liquid oxidant delivery pipe connected in parallel, and the gas oxidant pipe comprises an air oxidant delivery pipe and an oxygen delivery pipe connected in parallel; and a heat exchanger and a preheater are sequentially connected in series on the oxidant pipeline and the material pipeline, the oxidant pipeline and the material pipeline are in communication with an inner pipe of the heat exchanger; and the outlet of the reactor (12) is sequentially in communication, by means of piping, with a corrosion experiment device (14), an outer pipe of the heat exchanger, a cooler (16) and a gas-liquid separator (17).

A photocatalytically active particulate material includes a particle core of ZnS, particles of a nanoscale metal selected from Au, Ag, Pt, Pd, Cu or an alloy thereof loaded on the particle core, and a layer of Al2O3, SiO2, TiO2 or mixtures thereof on the loaded particle core.

To provide a sterilizing liquid and a method of producing the same that have no restrictions on application methods and usage and can be widely used for sterilization, a sterilizing liquid including water containing reactive oxygen species and a nanoparticle catalyst in a stationary state is produced by causing cavitation in water having a conductivity of 2000 μS/cm or less and COD of 2000 ppm or less while causing the water to flow by a stirrer 2, and causing generation of plasma by a plasma generation mechanism 3 in which a pulse voltage is applied across electrodes 31 in the water including air bubbles mainly containing water vapor generated by the cavitation.

A porous activated asphaltene material is described with a method of making and a method of using for the adsorption of a contaminant from a solution. The porous activated asphaltene material may be made by functionalizing solid asphaltene with nitric acid, and then treating the product with a metal hydroxide. The resulting porous activated asphaltene material exhibits a high porosity, and may be cleaned and reused for adsorbing contaminants.

Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H.sub.2O.sub.2 and .Math.OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe.sup.3+ and 5 to 15% wt. Cu.sup.2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .Math.OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H.sub.2O.sub.2 to .Math.OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.