Claimed herein is a method of applying amorphous Co—SiOx to activate PMS and produce SO.sub.4..sup.− due to the formation of Co(II)-O.sub.v, pairs via the substitution of Si by Co. The inherent Co significantly change the electronic structure of O and Si atoms in the Co—SiOx via final state effects and increase the conductivity in terms of more effective electron transfers. The claimed method using Co—SiOx functions as a more effective oxidative catalyst for the faster degradation of pollutants. The simplicity of the synthetic procedures indicates that the conductive Co—SiOx could be used for the activation of PMS and other electrochemical applications on a wider scale.

The present disclosure discloses a method for removing TBBPA in water, a microbial strain and a microbial agent, wherein the microbial strain is a domesticated Burkholderia cepacia strain, which is named Y17 with a conservation number GDMCC No. 62153. The microbial agent and the method for removing TBBPA in water with the microbial agent are that Y17 strains are colonized on the surface and pore channels of biochar, TBBPA in water is used as a carbon source, air and dissolved oxygen are used as oxygen sources, biochar provides the strains a growth microenvironment for degrading TBBPA in water, the strains are subjected to aerobic growth in water, and bio-enhanced degradation of TBBPA in water is performed by continuously degradation reaction. The removal method and the microbial strain as well as the microbial agent are high in degradation efficiency, environmental-friendly and low in cost, and can meet requirements on large-range promotion and application.

The present invention discloses a solvent assisted cavitation process for the removal of pollutants from waste water comprising treating waste water in a batch or continuous process in a cavitation device fed with 1-10% of an immiscible solvent resulting in a reduction in concentration of ammoniacal nitrogen and/or COD in the waste water.

Processes for producing olefins may include electrolyzing an aqueous solution comprising metal chloride, where electrolyzing the aqueous solution causes at least a portion of the metal chloride to undergo chemical reaction to produce a treatment composition comprising hypochlorite. The processes may further include contacting at least a portion of the treatment composition with the sour water at a pH from 8 to 12, where the sour water comprises sulfides and the contacting causes reaction of the sulfides in the sour water with the hypochlorite to produce a treated aqueous mixture comprising at least metal sulfates and metal chlorides, where the metal sulfates are present in the treated aqueous mixture as precipitated solids. The processes may further include separating the precipitated solids from the treated aqueous mixture to produce a treated effluent comprising at least the metal chloride.

A medium material for removing phenol contamination from groundwater, a method of producing the same, and use of the same id disclosed. In at least some embodiments, the medium material is a granular material which has an average particle diameter of 0.5-1.5 cm and is formed from a bacteria-entrapping solution, a manganese sand filter material, modified bentonite, and biochar at a mass ratio of 1:0.2-0.4:0.2-0.4:0.1-0.2 by a series of processes including strain culturing, catalysis, mixing, solidification, and the like. The medium material can remove phenol from groundwater, is a safe and environment-friendly material, has a long service life, and/or achieves waste treatment with waste.

A preparation method and application of a zero-valent aluminum/iron-bearing clay composite for catalyzing a persulfate to oxidize organics are provided, which belongs to the field of water environmental treatment. A novel catalyst is prepared by an iron-bearing clay and a zero-valent aluminum through a simple ball milling method, for achieving the effect of activating a persulfate to efficiently oxidize and degrade refractory organics in water. The preparation method and operation process thereof are simple. Compared with a chemical synthesis method, the method of the present disclosure brings about less secondary pollution, and has a shorter synthesis time, higher yield and lower cost. The modified material is the natural iron-bearing clay, which is widely available, non-toxic and stable as a heterogeneous catalyst.

A process for preparing a granular composite adsorbent, that includes combining poly (diallyl dimethyl ammonium halide) and a clay mineral in water, maintaining the mixture under stirring, recovering a wet mass, forming the wet mass into granules and drying the granules to obtain the granular adsorbent having surface layer with positive zeta potential. The granular material and methods using the granular material in water treatment are also disclosed.

The present invention relates to an aqueous composition comprising cells of at least one strain of a halophilic microorganism, and alkali sulfate in a concentration of at least 30 g/l based on the total volume of the aqueous composition. The present invention further relates to a method for treating a waste water, comprising obtaining or providing a waste water, contacting said waste water with cells of at least one strain of a halophilic microorganism, and thereby generating an aqueous composition comprising alkali sulfate in a concentration of at least 30 g/l, and incubating said aqueous composition under conditions which allow for the treatment of the waste water.

The disclosure is a method for recovering groundwater contaminated with organic phenols. The method includes the step of injecting a remediation agent into the groundwater extracted from the stratum to be rehabilitated or ex-situ extracted, followed by the step of injecting manganese-based oxidant. By adding a suitable proportion of soluble silicon to the water to be treated as a remediation agent, the efficiency of manganese-based oxidant in the treatment of phenolic pollutants is enhanced based on interface properties and stability of various manganese oxides in the regulating and recovering process. The method for recovering groundwater contaminated with organic phenols provided by the disclosure has a simple process and is convenient to operate, the adopted chemicals are inexpensive and easy to obtain, cause little corrosion to the injection equipment, and has a wide range of applications in practice. The adopted oxidant will not produce halogenated toxic by-products during the treatment process.

A method of forming an activated carbon sorbent from a seagrass. The method involves treating a seagrass with a base solution to form an intermediate solid, drying the intermediate solid to form a precursor, and pyrolyzing the precursor at 600 to 1000° C. to form the activated carbon sorbent. Preferably the seagrass is Halodule uninervis. The activated carbon sorbent is used in a method of removing an organic pollutant from a contaminated water. Preferred organic pollutants removed are phenols, specifically 2,4-dimethylphenol and 2,4-dichlorophenol.