A system that includes one or more quartz-sleeveless reactors to purify contaminated liquid in series or parallel. Each quartz-sleeveless reactor includes a continuous and independent reactor chamber. The system includes at least one continuous-batch flow, interior chamber reactor housed in the reactor chamber. Each interior chamber reactor of the at least one interior chamber reactor includes an ultraviolet (UV) lamp to emit UV radiation and fluid transport chamber. Each interior chamber reactor passes a stream of a mixture in the fluid transport chamber and around the UV lamp. The mixture includes an advanced oxidative process (AOP) additive and contaminated liquid. Each interior chamber reactor radiates the mixture while in the chamber with the emitted UV radiation from the UV lamp, simultaneously cools the UV lamp with the mixture, and autonomously passes a radiated resultant mixture into the reactor chamber.

An environmental remediation system includes a contaminate treatment mat assembly to extract contaminates in pore water and sediment. The mat assembly includes a flexible liner and pore water and sediment-penetrating chambers individually anchored to the flexible liner. The anchored chambers include lids that are positioned above the liner and containers below the liner. The system includes a plate subsystem including plate holes. The plate subsystem is configured to have the mat assembly removable attached thereunder, absorb impact forces from a delivery system, translate the impact forces into a driving force applied simultaneously to tops of the lids of all the pore water and sediment-penetrating chambers under the plate subsystem to cause penetration of the containers into underlying pore water and sediment, and simultaneously displace fluid through liner holes of the liner and the plate holes. A method for environmental remediating using the system is also provided.

Reactive treatment cells (RTCs) are described in combination with sediment capping systems as a means for environmental remediation. RTCs include an impermeable housing defining an interior, a permeable ceiling and floor typically including filtration materials such as geotextiles, and at least one interior compartment for treatment reagents. One RTC includes a gabion-like cage structure retaining a geomembrane-supported geosynthetic clay liner (GM-GCL) housing, while a second embodiment includes a hard, cylindrical shell as a replaceable reagent cartridge. RTCs may be employed in initial capping system installations or retrofitted into existing capping systems. RTCs may include optional baffles, flow restrictors, floating discs, sensor probes, and two or more serial reagent zones or compartments.

A composition for remediation of soil and groundwater containing halogenated compounds. The remediation composition includes an elemental iron-based composition, which may include activated carbon capable of absorbing the halogenated compounds with numerous pores impregnated with elemental iron. The remediation composition further includes a first bioremediation material including a blend of one-to-many organisms capable of degrading the halogenated compounds. The remediation composition includes an organic compound or polymeric substance and a second bioremediation material including a blend of one-to-many organisms capable of degrading the organic compound or polymeric substance over time (e.g., 20 to 365 or more days to provide a time release substrate-creating material or platform) into smaller molecules or compounds used by the organisms in the first bioremediation material while degrading the halogenated compounds. The organic compound may be a complex carbohydrate such as food grade starch, chitin, or other complex carbohydrate such as one with low water solubility.

Methods for electrochemically oxidizing organic compounds in aqueous solution. The methods include contacting an aqueous solution comprising organic compounds with a first anode and electrochemically oxidizing at least a portion of the organic compounds to provide a first aqueous solution comprising oxidation products; and contacting the first aqueous solution comprising oxidation products with a first cathode and electrochemically reducing at least a portion of the oxidation products to provide a first aqueous solution comprising reduced products and residual oxidizable organic compounds. The first aqueous solution can be further treated to electrochemically oxidize at least a portion of the residual oxidizable organic compounds to provide a second aqueous solution comprising oxidation products, and the second aqueous solution can be further treated to electrochemically reduce at least a portion of the oxidation products to provide a third aqueous solution comprising reduced products and residual oxidizable organic compounds. Systems for electrochemically oxidizing organic compounds and effectively carrying out the methods are also provided.

A composition for remediation of soil and groundwater containing halogenated compounds. The remediation composition includes an elemental iron-based composition, which may include activated carbon capable of absorbing the halogenated compounds with numerous pores impregnated with elemental iron. The remediation composition further includes a first bioremediation material including a blend of one-to-many organisms capable of degrading the halogenated compounds. The remediation composition includes an organic compound or polymeric substance and a second bioremediation material including a blend of one-to-many organisms capable of degrading the organic compound or polymeric substance over time (e.g., 20 to 365 or more days to provide a time release substrate-creating material or platform) into smaller molecules or compounds used by the organisms in the first bioremediation material while degrading the halogenated compounds. The organic compound may be a complex carbohydrate such as food grade starch, chitin, or other complex carbohydrate such as one with low water solubility.

A device for selectively removing a perfluorinated compound may include an adsorption electrooxidation tank including a reaction unit having a plurality of electrodes and granular activated carbon configured to oxidize and decompose a perfluorinated compound in raw water through adsorption and electrooxidation, a power supply device configured to supply power to the adsorption electrooxidation tank, and a head adjustment pipe unit configured to maintain a water level within the reaction unit at a height greater than or equal to a reaction height of the electrode.

A biochar-derived adsorbent preferably from Sargassum boveanum, macroalgae can be used for removing phenolic compounds, such as 2,4,6-trichlorophenol and 2,4-dimethylphenol, from aqueous solutions. The carbonization can improve the removal capability of the macroalgae adsorbent for such phenolic compounds with removal efficiencies of 60% or more from high salinity seawater and 100% from distilled water. The adsorption may occur through a mixed mechanism dominated by physisorption following pseudo second-order kinetics. The adsorption of the phenolic molecules may be spontaneous, endothermic and thermodynamically favorable.

Formulations and methods for destroying dense non-aqueous phase liquids (DNAPLs) using in situ chemical oxidation (ISCO) are provided. In particular, the invention provides slow release formulations comprising oxidants such as percarbonate and persulfate that efficiently destroy DNAPLs e.g. at sites requiring clean-up due to the presence of toxic DNAPL contaminants.

A supercritical water oxidation (SCWO) system with a well-mixed SCWO reactor, a feedstock supplied to the well-mixed SCWO reactor by a feedstock supply line, a recirculation loop flow regulator in fluid communication with the well-mixed SCWO reactor; and a recirculation loop which includes the well-mixed SCWO reactor and the recirculation loop flow regulator, such that the recirculation loop flow regulator receives an oxidant from an oxidant supply line and a first portion of a reactor effluent from the well-mixed SCWO reactor and supplies the oxidant and the first portion of the reactor effluent to the well-mixed SCWO reactor. The SCWO system also includes a heat transfer unit operationally associated with the well-mixed SCWO reactor which performs at least one of: heating the well-mixed SCWO reactor and cooling the well-mixed SCWO reactor.