The present disclosure provides optical fiber preforms formed from core canes having large core-clad ratio, intermediate core-cladding assemblies, and methods for making the preforms and core cladding assemblies. The preforms are made with capped core canes. The capping material has a coefficient of thermal expansion less than the coefficient of thermal expansion of the core cane and more closely matched to or lower than the coefficient of thermal expansion of the surrounding cladding monolith in a cane-in-soot process. Presence of the cap reduces stresses that arise from differential thermal expansion of the core cane and cladding materials and leads to preforms having low defect concentration and low probability of failure during subsequent thermal processing steps.

Provided is a hydrogen isotope adsorbent with differential binding properties and including mesoporous silica doped with fluorine.

A glass body manufacturing apparatus includes: a first heating furnace including a furnace core tube accommodating the soot and a first heater, to supply a dehydration gas into the furnace core tube and heat the soot at a first treatment temperature lower than a softening point of the porous portion by the first heater; a second heating furnace including a structural body accommodating the soot and a second heater, to heat the soot at a second treatment temperature equal to or higher than the softening point by the second heater; and a conveyance container, connectable to each of the first and second heating furnaces while keeping airtightness with respect to the atmosphere, to accommodate and hold the soot, and convey the soot between the first and second heating furnaces.

According to some embodiments method for making an optical fiber preform comprises the steps of: (i) placing a plurality of rods with an outer surface having a coefficient of friction 0.02≦COF≦0.3 into an inner cavity of an apparatus; (ii) placing particulate glass material in the inner cavity between the rods and an inner wall of the mold cavity; and (iii) applying pressure against the particulate glass material to press the particulate glass material against the plurality of rods.

In known methods for producing a glass component, a void-containing intermediate product containing doped or non-doped SiO.sub.2 is inserted into a sheath tube composed of glass, which has a longitudinal axis and an inner bore, and is thermally treated therein. In order to subject the intermediate product to a thermal and/or reactive treatment that is reproducible and uniform in its effect from this starting point, it is proposed in one embodiment that into the sheath tube's inner bore a first gas-permeable gas diffuser is inserted which is displaceable along the sheath tube's longitudinal axis and is pressed against the intermediate product during the thermal treatment.

A continuous sol-gel process for producing silicate-containing glasses and glass ceramics is proposed, comprising the following steps: (a) continuously feeding a silicon tetraalkoxide, a silicon alkoxide with at least one non-alcoholic functional group and an alcohol into a first reactor (R1), and at least partially hydrolyzing by the addition of a mineral acid to obtain a first product stream (A); (b) continuously providing a second product stream (B) in a second reactor (R2) by feeding a metal alkoxide component or continuously mixing an alcohol and a metal alkoxide component; (c) continuously mixing product streams (A) and (B) in a third reactor (R3) for producing a presol to obtain a third product stream (C); (d) continuously adding water or a diluted acid to the product stream (C) to obtain a sol (gelation); (e) continuously filling the emerging sol into molds to obtain an aquagel; (f) drying the aquagels to obtain xerogels; (g) sintering the xerogels to obtain silicate-containing glasses and glass ceramics.

Provided is a hydrogen isotope adsorbent with differential binding properties and including mesoporous silica doped with fluorine.

A continuous sol-gel process for producing silicate-containing glasses and glass ceramics is proposed, comprising the following steps: (a) continuously feeding a silicon tetraalkoxide, a silicon alkoxide with at least one non-alcoholic functional group and an alcohol into a first reactor (R1), and at least partially hydrolyzing by the addition of a mineral acid to obtain a first product stream (A); (b) continuously providing a second product stream (B) in a second reactor (R2) by feeding a metal alkoxide component or continuously mixing an alcohol and a metal alkoxide component; (c) continuously mixing product streams (A) and (B) in a third reactor (R3) for producing a presol to obtain a third product stream (C); (d) continuously adding water or a diluted acid to the product stream (C) to obtain a sol (gelation); (e) continuously filling the emerging sol into molds to obtain an aquagel; (f) drying the aquagels to obtain xerogels; (g) sintering the xerogels to obtain silicate-containing glasses and glass ceramics.

An optical fiber includes a core region of silica glass doped with an alkali metal oxide. A depressed-index cladding region surrounds the core region and comprises silica glass doped with a first concentration of fluorine. The depressed-index cladding region has a minimum relative refractive index Δ.sub.3min in a range from −0.80% to −0.30%. An outer cladding region comprises silica glass doped with a second, lesser concentration. The outer cladding region has a relative refractive index Δ.sub.4, where Δ.sub.4−Δ.sub.3min>0.05%. The optical fiber has a time-to-peak hydrogen aging value at 23° C. of less than 100 hours upon exposure to an atmosphere having a total pressure of 1 atm and containing a partial pressure of 0.01 atm H.sub.2 and a partial pressure of 0.99 atm N.sub.2. The optical fiber exhibits an attenuation <0.16 dB/km.

A method of manufacturing a transparent glass article is provided. The manufacturing method includes the following steps (a) to (f): in step (a), a nanocomposite is provided; in step (b), the nanocomposite is subjected to an external stimulus in order to render it remoldable; in step (c), the nanocomposite is remolded into a predetermined shape in order to obtain a primary structure; in step (d), the primary structure is debound in order to obtain a secondary structure having cavities formed therein; in step (e) which is optional, the cavities of the secondary structure are filled with at least one additive; and in step (f), the secondary structure is sintered to obtain the transparent glass article.