A process for preparing a product including a monohydrogentrihalosilane is disclosed. The process includes the steps of: 1) initially charging a reactor with a contact mass including both fresh silicon and recycled contact mass, where the recycled contact mass is obtained from during or after a production phase of an inorganic Direct Process reaction for production of a monohydrogentrihalosilane; and thereafter 2) feeding to the reactor a hydrogen halide and additional fresh silicon, thereby forming the product.

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index Δ.sub.1MAX, and an inner cladding region having refractive index Δ.sub.2MIN surrounding the core, where Δ.sub.1MAX>Δ.sub.2MIN.

A process for producing a fluorinated quartz glass is described, including providing an SiO.sub.2 soot body; reacting the SiO.sub.2 soot body with a fluorinating agent having a boiling point of greater than or equal to −10° C. to obtain a fluorinated SiO.sub.2 soot body; and vitrifying the fluorinated SiO.sub.2 soot body.

A process for the production of a fluorinated quartz glass including the steps of generating SiO.sub.2 particles in a synthesis burner; depositing the resulting SiO.sub.2 particles into a body; and vitrifying the resulting body, wherein a fluorinating agent having a boiling point greater than or equal to −10° C. is supplied to the synthesis burner.

A burner for synthesization to synthesize glass particles that form a porous glass base material is provided, the burner for synthesization including a raw material gas injection portion to inject raw material gas toward a target, a combustion assisting gas injection portion to inject combustion assisting gas in a direction in which the combustion assisting gas is merged with the raw material gas at a first merging point, and a combustible gas injection portion to inject combustible gas in a direction in which the combustible gas is merged with the combustion assisting gas at a second merging point that is positioned closer to the combustion assisting gas injection portion than the first merging point. In the above-described burner for synthesization, the combustion assisting gas injection portion may also include a plurality of injection ports arranged along one straight line.

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index .sub.1MAX, and an inner cladding region having refractive index .sub.2MIN surrounding the core, where .sub.1MAX>.sub.2MIN.

A process for the production of a fluorinated quartz glass including the steps of generating SiO.sub.2 particles in a synthesis burner; depositing the resulting SiO.sub.2 particles into a body; and vitrifying the resulting body, wherein a fluorinating agent having a boiling point greater than or equal to ?10? C. is supplied to the synthesis burner.

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index .sub.1MAX, and a inner cladding region having refractive index .sub.2MIN surrounding the core, where .sub.1MAX>.sub.2MIN.

A burner for synthesization to synthesize glass particles that form a porous glass base material is provided, the burner for synthesization including a raw material gas injection portion to inject raw material gas toward a target, a combustion assisting gas injection portion to inject combustion assisting gas in a direction in which the combustion assisting gas is merged with the raw material gas at a first merging point, and a combustible gas injection portion to inject combustible gas in a direction in which the combustible gas is merged with the combustion assisting gas at a second merging point that is positioned closer to the combustion assisting gas injection portion than the first merging point. In the above-described burner for synthesization, the combustion assisting gas injection portion may also include a plurality of injection ports arranged along one straight line.

A process for preparing a product including a monohydrogentrihalosilane is disclosed. The process includes the steps of: 1) initially charging a reactor with a contact mass including both fresh silicon and recycled contact mass, where the recycled contact mass is obtained from during or after a production phase of an inorganic Direct Process reaction for production of a monohydrogentrihalosilane; and thereafter 2) feeding to the reactor a hydrogen halide and additional fresh silicon, thereby forming the product.