A method of producing bi-modal particles includes the steps of igniting a first precursor gas using a primary burner thereby producing a first plurality of particles of a first size, fluidly transporting the first plurality of particles down a particle tube, igniting a second precursor gas using a secondary burner thereby producing a second plurality of particles of a second size, flowing the second plurality of particles into the first plurality of particles, and capturing the first and second plurality of particles.

A method of producing a glass preform including: forming a porous glass soot configured by an inner deposition soot deposited on a start material and an outer deposition soot deposited outside the inner deposition soot; and sintering, after the forming, the porous glass soot while doping with fluorine to form a glass body including an inner glass portion and an outer glass layer. An amount of the fluorine, with which the inner deposition soot is doped at the sintering, is equal to or more than 0 g/cm.sup.3 and less than an amount of the fluorine with which the outer deposition soot is doped.

In a device for producing a large-sized porous base material by a VAD process, the cracking and variation of the outer diameter of the base material are suppressed by forming a smooth tapered part, without changing the length of a non-effective part. In producing the porous base material by a VAD process, the time for a gas to reach a flow amount of the gas in a steady state from starting of the deposition is extended more in a burner that deposits glass microparticles on a layer closer to the outside of the base material.

A method of producing bi-modal particles includes the steps of igniting a first precursor gas using a primary burner thereby producing a first plurality of particles of a first size, fluidly transporting the first plurality of particles down a particle tube, igniting a second precursor gas using a secondary burner thereby producing a second plurality of particles of a second size, flowing the second plurality of particles into the first plurality of particles, and capturing the first and second plurality of particles.

According to a fabrication method for fabricating a porous glass base material for optical fiber, the orientation of a clad forming burner used to form the outermost layer of a clad-corresponding portion is changed further upward while glass fine particles are deposited during the period between a first timing and a second timing. At the first timing, the outer diameter of the porous glass base material for optical fiber has not reached a target outer diameter. The second timing is later than the first timing, and either a timing at which the outer diameter of the porous glass base material for optical fiber reaches the target outer diameter for the first time, or a timing prior to this timing.

A manufacturing apparatus of porous glass base material includes deposition apparatuses that manufacture a porous glass base material by generating raw material particles from vaporized raw material compounds in an oxyhydrogen flame, and then depositing the generated raw material particles on a rotating starting material. The manufacturing apparatus includes a storage container that stores liquid raw material compounds for each compound, a vapor generation mechanism that vaporizes the raw material compounds, and a gas channel that supplies the vaporized raw material compounds to the deposition apparatuses. The gas channel includes a common gas channel shared to supply vaporized raw material compounds to the plurality of deposition apparatuses, and individual gas channels branched off from the common gas channel to supply vaporized raw material compounds to each of the deposition apparatuses individually. Each of the individual gas channels has a flow controller, a steam valve, and a valve.

This raw material supply device supplies a raw material for producing glass fine particle deposits, to a burner and includes a raw material tank; a liquid raw material pipe having one end thereof connected to the raw material tank; a liquid raw material pressure feed pump that pumps siloxane, being a liquid raw material, from the raw material tank via the liquid raw material pipe; a pressure adjustment valve provided on a secondary side of the liquid raw material pressure feed pump in the liquid raw material pipe; an MFC for liquid, connected to the other end of the liquid raw material pipe; and an aeration device that is connected to the secondary side of the MFC for liquid and aerates the liquid raw material. The pipe on the secondary side of the pressure adjustment valve is connected to a location having lower pressure than the primary side pressure.

An apparatus for manufacturing a porous glass soot body to be formed into an optical fiber preform includes: a reaction chamber; a burner to form the porous glass soot body by depositing glass particles onto a seed rod hung inside the reaction chamber; and a heat-blocking element filling a gap between the burner and an opening for inserting the burner into the reaction chamber. A purpose is to prevent damage to the burner in the apparatus for manufacturing a porous glass soot body. In the manufacturing apparatus, the heat-blocking element may include a fibriform material. Also, in the manufacturing apparatus, the heat-blocking element may include a quartz wool material. Further, in the manufacturing apparatus, the content of iron in the quartz wool material may be 1 ppm or less.

The present invention provides an optical fiber with improved optical properties such as zero dispersion wavelength by suppressing the volatilization of dopant materials such as germanium dioxide and optimizing the refractive index distribution by adjusting the setting position of the core portion burner for deposition in a larger optical fiber preform. An optical fiber preform includes a core portion with a relatively high refractive index and a clad portion with a relatively low refractive index, wherein a position having a value of 45% of a refractive index difference between a center of the core portion and the clad portion is a boundary rcore (mm) between the core portion and the clad portion; and when a radius position r at which a refractive index difference with the clad portion being a maximum value is rside (mm), r.sub.side/rcore is 0.745 to 1.

A method for manufacturing an optical fiber preform includes a core part deposition process and a clad part deposition process. The number of burners used in the core part deposition process is less than the number of burners used in the clad part deposition process. A distance between turning back points in a first reciprocating motion for the core deposition process is equal to or greater than a length of an effective portion of the optical fiber preform. At least three burners are used in the clad part deposition process. A distance between turning back points in a second reciprocating motion for the clad part deposition process is shorter than a distance between turning back points in the first reciprocating motion. The turning back points in the second reciprocating motion vary during the clad part deposition process.