A glass container includes a glass body comprising an external surface, an internal surface opposite the external surface, a thickness T extending between the external surface and the internal surface, and an external surface layer extending from the external surface into the thickness of the glass body, wherein the external surface layer has a porosity greater than a porosity of a remainder of the glass body extending from the external surface layer to the internal surface.

A vacuum insulated structure for use in an appliance includes an inner liner and an outer wrapper coupled to the inner liner. A vacuum insulated cavity is defined therebetween. An insulation material is disposed in the vacuum insulated cavity. The insulation material includes porous glass flakes.

A method for producing a high silicate glass substrate, includes: (1) obtaining a glass precursor containing, as represented by mol % based on oxides, 60% to 75% of SiO.sub.2, 0% to 15% of Al.sub.2O.sub.3, 15% to 30% of B.sub.2O.sub.3, 0% to 3% of P.sub.2O.sub.5, and 1% to 10% in total of at least one selected from R.sub.2O and R′O; (2) applying first heat treatment to the glass precursor to cause phase separation so as to obtain a phase-separated glass; (3) applying acid treatment to the phase-separated glass to make the phase-separated glass porous so as to obtain a porous glass; (4) drying the porous glass so that a rate of change in mass reaches 10% to 50%; and (5) applying second heat treatment to the porous glass to sinter the porous glass so as to obtain a high silicate glass substrate.

A glass microsphere, comprising: a main body, wherein the main body is solid while including a network of inter-connected pores produced from a phase separation process and thermal and chemical leaching operations, with porosity extending throughout a cross-section of the solid glass microsphere.

A method for preparing an optically transparent, superomniphobic coating on a substrate, such as an optical substrate, is disclosed. The method includes providing a glass layer disposed on a substrate, the glass layer having a first side adjacent the substrate and an opposed second side, the glass layer comprising 45-85 wt. % silicon oxide in a first glass phase and 10-40 wt. % boron oxide in a second glass phase, such that a glass layer has a composition in a spinodal decomposition region. The method further includes heating the second side of the glass layer to form a phase-separated portion of the layer, the phase-separated portion comprising an interpenetrating network of silicon oxide domains and boron oxide domains, and removing at least a portion of the boron oxide domains from the phase-separated portion to provide a graded layer disposed on the substrate. The graded layer has a first side disposed adjacent the substrate, the first side comprising 45-85 wt. % silicon oxide and 10-40 wt. % boron oxide, and opposite the first side, a porous second side comprising at least 45 wt. % silicon oxide and no more than 5 wt. % boron oxide.

Provided is a method for producing a porous glass member whereby excellent productivity can be achieved because of a high etching rate during acidic treatment and a porous glass member having excellent alkali resistance can be obtained. A method for producing a porous glass member includes the steps of: subjecting a glass base material containing, in terms of % by mole, 40 to 80% SiO.sub.2, over 0 to 40% B.sub.2O.sub.3, 0 to 20% Li.sub.2O, 0 to 20% Na.sub.aO, 0 to 20% K.sub.2O, over 0 to 10% TiO.sub.2, over 0 to 20% ZrO.sub.2, 0 to 10% Al.sub.2O.sub.3, and 0 to 20% RO (where R represents at least one selected from among Mg, Ca, Sr, and Ba) and having a molar ratio of Li.sub.2O/Na.sub.2O of 0 to 0.16 to thermal treatment to separate the glass base material into two phases; and removing one of the two phases with an acid.

Provided is a method for producing a porous glass member whereby cracking during production is less likely to occur and a porous glass member having excellent alkali resistance can be produced. A method for producing a porous glass member includes the steps of: subjecting a glass base material containing, in terms of % by mole, 40 to 80% SiO.sub.2, over 0 to 40% B.sub.2O.sub.3, 0 to 20% Li.sub.2O, 0 to 20% Na.sub.2O, 0 to 20% K.sub.2O, over 0 to 2% P.sub.2O.sub.5, over 0 to 20% ZrO.sub.2, 0 to 10% Al.sub.2O.sub.3, and 0 to 20% RO (where R represents at least one selected from among Mg, Ca, Sr, and Ba) to thermal treatment to separate the glass base material into two phases; and removing one of the two phases with an acid.

A high-strength geopolymer hollow microsphere, a preparation method thereof and a phase change energy storage microsphere are provided, including: dissolving sodium hydroxide, sodium silicate and spheroidizing aid in water to form a solution A, and adding active powder to the solution A, stirring and uniformly mixing to form a slurry B, adding the slurry B to an oil phase, stirring and dispersing into balls, filtering to obtain geopolymer microspheres I, washing the geopolymer microspheres I, and then carrying out a high-temperature calcination to obtain the high-strength geopolymer hollow microspheres II; using the high-strength geopolymer hollow microsphere as a carrier, absorbing a phase change material into the carrier, and mixing a microsphere carrying the phase change material with an epoxy resin, adding a powder dispersant and stirring to disperse the microsphere, after the epoxy resin is solidified, screening the superfluous powder dispersant to obtain the phase energy storage microsphere.

There is provided a glass substrate for observing minute substance, made of porous glass and capable of separating and capturing a minute substance with a 10 to 500 nm average particle diameter contained in a solution or a suspension, comprising a porous glass substrate having a plurality of pores, wherein the plurality of pores has an average pore diameter ranging from 30 to 110% of the average particle diameter of the minute substance, each of the plurality of pores has a surface pore diameter on an uppermost surface of the glass substrate, a standard deviation of the surface pore diameter is 60% or less of the average particle diameter of the minute substance, and a pore with a pore diameter ranging from 60 to 140% of a pore diameter at peak top in a pore diameter distribution of the plurality of pores occupies 90% or more of total pore volume.

A nanocomposite solid material includes nanoparticles of a metal coordination polymer with CN ligands comprising M.sup.n+ cations, in which M is a transition metal and n is 2 or 3; and anions [M′(CN).sub.m].sup.x− in which M′ is a transition metal, x is 3 or 4, and m is 6 or 8. The M.sup.n+ cations of the coordination polymer are bound through an organometallic bond to an organic group of an organic graft chemically attached inside the pores of a support made of porous glass. The material can be used in a method for fixing (binding) a mineral pollutant, such as radioactive cesium, contained in a solution by bringing the solution in contact with the nanocomposite solid material.