Provided are self-binding suspensions and coated substrates prepared using self-binding suspensions. Also provided are methods of preparing self-binding suspensions. Methods may include preparing a binder solution; preparing a titanium dioxide-zinc oxide suspension using ultrasonication; mixing the binder solution with the titanium dioxide-zinc oxide suspension and a surfactant to form a self-binding suspension composition; and coating a glass substrate with the self-binding suspension composition to form a coated glass substrate.

To provide a coating material capable of forming a solar cell module excellent in the weather resistance, the power generation efficiency and the design, a cover glass, a solar cell module comprising the cover glass, and an outer wall material for building. The cover glass of the present invention is a cover glass comprising a glass plate and a layer containing a fluorinated polymer having units based on a fluoroolefin, on at least one surface of the glass plate, which has an average visible reflectance of from 10 to 100%, and an average near infrared transmittance of from 20 to 100%.

The disclosure pertains to thermochromic materials, coatings, to coated articles and to preparation methods. In addition, the disclosure relates to thermochromic particulate material comprising vanadium (IV) oxide. A described preparation method involves curing of the coating using two curing stages performed with different oxygen levels.

A display that includes an image producing system and a light filtering layer in the blue range, the light filtering layer having a limited impact on the gamut of the display. The image producing system has a gamut G.sub.0 defined in a color space The light filtering layer includes semi-conductive nanoparticles, and the absorbance through the light filtering layer is greater than 0.25 for each light wavelength ranging from 350 nm to λ.sub.cut, λ.sub.cut being in the range from 420 nm to 450 nm. The gamut G.sub.1 of the image producing system with the filtering layer has an area greater than 90% of the area of gamut G.sub.0 in the color space.

Urea and amine comprising sol-gel hybrid coatings have been developed for numerous applications, including capillary microextraction-high performance liquid chromatographic analysis from aqueous samples. A fused silica capillary may be coated from the inside with surface bonded coating material and may be created by in-situ sol-gel reaction(s). Urea-functionalized coatings can be immobilized on the inner surface of a capillary by condensing silanol groups of capillary and sol-solution. Urea functionalized, sol-gel coated capillaries may be installed, e.g., in HPLC manual injection ports, and optionally pre-concentrated analytes including phenols, ketones, aldehydes, and/or polyaromatic hydrocarbons, from highly polar to non-polar, maybe analyzed by online extraction and high-performance liquid chromatographic. Such coatings may achieve sensitivities with lower detection limits (S/N=3) of 0.10 ng/mL to 14.29 ng/mL, with reproducibilities of <12.0% RSD (n=3), or <10.0% RSD (n=3) by exchanging the capillary of the same size.

A process for obtaining a material including a textured glass substrate coated, on at least one of its textured faces, with an antireflective coating of sol-gel type based on porous silica, includes a stage of application, to the at least one textured face of the substrate, of a solution containing at least one silica precursor and at least one pore-forming agent, then a heat treatment stage targeted at consolidating the antireflective coating. Before the application stage, the glass substrate is subjected to a preheating stage, so that the at least one textured face intended to be coated with the antireflective coating has a temperature within a range extending from 30° C. to 100° C. immediately before the application stage.

A method for preparing an optically transparent, superomniphobic coating on a substrate, such as an optical substrate, is disclosed. The method includes providing a glass layer disposed on a substrate, the glass layer having a first side adjacent the substrate and an opposed second side, the glass layer comprising 45-85 wt. % silicon oxide in a first glass phase and 10-40 wt. % boron oxide in a second glass phase, such that a glass layer has a composition in a spinodal decomposition region. The method further includes heating the second side of the glass layer to form a phase-separated portion of the layer, the phase-separated portion comprising an interpenetrating network of silicon oxide domains and boron oxide domains, and removing at least a portion of the boron oxide domains from the phase-separated portion to provide a graded layer disposed on the substrate. The graded layer has a first side disposed adjacent the substrate, the first side comprising 45-85 wt. % silicon oxide and 10-40 wt. % boron oxide, and opposite the first side, a porous second side comprising at least 45 wt. % silicon oxide and no more than 5 wt. % boron oxide.

A greenhouse according to the present invention includes: a ceiling portion; and in at least a portion of the ceiling portion, a glass sheet with a coating film. The glass sheet with a coating film has a total light transmittance of 90% to 98%, a haze ratio of 20% to 80%, and a hemispherical transmittance of 80% to 90%. When a test is performed according to JIS R 1703-1: 2007 by applying oleic acid to a surface of a coating film and subsequently irradiating the surface with ultraviolet light at an intensity of 1.0 mW/cm.sup.2, a time period from start of irradiation with the ultraviolet light to a point at which a water contact angle on the surface reaches 5° is 24 hours or less.

A glass substrate with a silica film according to the present invention includes a glass substrate and a silica film formed using a silica film-forming composition, in which the composition includes at least one kind selected from the group consisting of a hydrolyzable compound, a hydrolyzate thereof, and a hydrolysis condensation compound thereof, and at least one kind selected from the group consisting of a silica particle and a zirconia particle, the hydrolyzable compound consisting of a tetraalkoxysilane, a compound (compound I) represented by formula I: (R.sub.3-p(L).sub.pSi-Q-Si(L).sub.pR.sub.3-p), optionally a fluoroalkylsilane having a hydrolysable group, and optionally a zirconium compound having a hydrolyzable group, and the contents of the tetraalkoxysilane, the compound I, and the at least one kind selected from the group consisting of a silica particle and a zirconia particle in terms of SiO.sub.2/ZrO.sub.2 fall within specified ranges, respectively.

Provided are methods of forming stacks comprising a substrate and one or more sol-gel layers disposed on the substrate. Also provided are stacks formed by these methods. The sol-gel layers in these stacks, especially outer layers, may have a porosity of less than 1% or even less than 0.5%. In some embodiments, these layers may have a surface roughness (R.sub.a) of less than 1 nanometers. The sol-gel layers may be formed using radiative curing and/or thermal curing at temperatures of between 400° C. and 700° C. or higher. These temperatures allow application of sol-gel layers on new types of substrates. A sol-gel solution, used to form these layers, may have colloidal nanoparticles with a size of less than 20 Angstroms on average. This small size and narrow size distribution is believed to control the porosity of the resulting sol-gel layers.