Patent classifications
C03C25/326
RESIN COMPOSITION, OPTICAL FIBER, AND METHOD FOR PRODUCING OPTICAL FIBER
A resin composition for secondary coating of an optical fiber is a resin composition comprising: a photopolymerizable compound comprising a urethane (meth)acrylate having a number average molecular weight of 10000 or more and 40000 or less; and a photopolymerization initiator, the content of the urethane (meth)acrylate is 0.05 parts by mass or more and 15 parts by mass or less based on the total amount of the resin composition of 100 parts by mass, and the urethane (meth)acrylate is a reaction product of a polyol having a number average molecular weight of 1800 or more and 4500 or less, a diisocyanate, and a hydroxyl group-containing (meth)acrylate.
RESIN COMPOSITION, OPTICAL FIBER, AND METHOD FOR PRODUCING OPTICAL FIBER
A resin composition for secondary coating of an optical fiber is a resin composition comprising: a photopolymerizable compound comprising a urethane (meth)acrylate having a number average molecular weight of 10000 or more and 40000 or less; and a photopolymerization initiator, the content of the urethane (meth)acrylate is 0.05 parts by mass or more and 15 parts by mass or less based on the total amount of the resin composition of 100 parts by mass, and the urethane (meth)acrylate is a reaction product of a polyol having a number average molecular weight of 1800 or more and 4500 or less, a diisocyanate, and a hydroxyl group-containing (meth)acrylate.
Fiber coating compositions with high cure speed
The present disclosure provides coating compositions and cured products formed from the coating compositions. The cured products can be formed at high cure speeds from the coating compositions and feature low Young's modulus, high tear strength, and/or high tensile toughness. The cured products can be used as primary coatings for optical fibers. The primary coatings provide good microbending performance and are resistant to defect formation during fiber coating processing and handling operations. The coating compositions include an oligomer, an alkoxylated monofunctional acrylate monomer, and preferably, an N-vinyl amide compound.
Fiber coating compositions with high cure speed
The present disclosure provides coating compositions and cured products formed from the coating compositions. The cured products can be formed at high cure speeds from the coating compositions and feature low Young's modulus, high tear strength, and/or high tensile toughness. The cured products can be used as primary coatings for optical fibers. The primary coatings provide good microbending performance and are resistant to defect formation during fiber coating processing and handling operations. The coating compositions include an oligomer, an alkoxylated monofunctional acrylate monomer, and preferably, an N-vinyl amide compound.
Coated panel and method for manufacturing a coated panel
The present invention relates to a method for the manufacturing of a coated panel, in particular a wall, ceiling or flooring panel for applications in outdoor areas, as well as such a panel. The method comprises the following steps: providing a carrier plate of mineral wool and/or glass wool, comprising a front side and a rear side, applying a primer onto the front side of the carrier plate, thereafter applying a liquid first oligomer in an amount of 30 to 150 g/m.sup.2 onto the front side of the carrier plate; thereafter applying a liquid second oligomer, which differs from the first oligomer, in an amount of 30 to 180 g/m.sup.2 onto the wet surface of the before applied layer of the first oligomer.
Coated panel and method for manufacturing a coated panel
The present invention relates to a method for the manufacturing of a coated panel, in particular a wall, ceiling or flooring panel for applications in outdoor areas, as well as such a panel. The method comprises the following steps: providing a carrier plate of mineral wool and/or glass wool, comprising a front side and a rear side, applying a primer onto the front side of the carrier plate, thereafter applying a liquid first oligomer in an amount of 30 to 150 g/m.sup.2 onto the front side of the carrier plate; thereafter applying a liquid second oligomer, which differs from the first oligomer, in an amount of 30 to 180 g/m.sup.2 onto the wet surface of the before applied layer of the first oligomer.
Radiation polymerizable composition, cured layer of same, optical fiber containing cured layer and method for producing same
[Problem] To provide a radiation curable resin composition which is suitable as a primary material for optical fibers, while having a high curing rate by means of irradiation of radiation [Solution] A radiation polymerizable composition for forming an optical fiber primary coating layer, said composition containing: (A) a urethane oligomer containing a structure represented by formula (I) (in formula (I), R represents a vinyl group; and * represents a bonding hand); (B) one or more compounds selected from among (i) maleic acid anhydride, (ii) a compound represented by formula (II) (in formula (II), R.sup.I represents a single bond or an alkanediyl group having from 1 to 6 carbon atoms; and R.sup.2 represents a hydrogen atom, a hydroxy group or a specific group represented by formula (II-1) or formula (II-2)), and (iii) a compound represented by formula (III) (in formula (III), R.sup.5 represents an alkanediyl group having from 1 to 6 carbon atoms); and (C) a radiation polymerization initiator.
Radiation polymerizable composition, cured layer of same, optical fiber containing cured layer and method for producing same
[Problem] To provide a radiation curable resin composition which is suitable as a primary material for optical fibers, while having a high curing rate by means of irradiation of radiation [Solution] A radiation polymerizable composition for forming an optical fiber primary coating layer, said composition containing: (A) a urethane oligomer containing a structure represented by formula (I) (in formula (I), R represents a vinyl group; and * represents a bonding hand); (B) one or more compounds selected from among (i) maleic acid anhydride, (ii) a compound represented by formula (II) (in formula (II), R.sup.I represents a single bond or an alkanediyl group having from 1 to 6 carbon atoms; and R.sup.2 represents a hydrogen atom, a hydroxy group or a specific group represented by formula (II-1) or formula (II-2)), and (iii) a compound represented by formula (III) (in formula (III), R.sup.5 represents an alkanediyl group having from 1 to 6 carbon atoms); and (C) a radiation polymerization initiator.
METHOD OF MANUFACTURING OPTICAL FIBER AND OPTICAL-FIBER-MANUFACTURING APPARATUS
A method of manufacturing an optical fiber includes applying a curable resin composition containing a photopolymerization initiator so that an outer circumference of a glass fiber including a core and a cladding is coated, and forming a coating layer by radiating an ultraviolet ray to the curable resin composition and curing the curable resin composition. Forming the coating layer includes providing two or more non-radiation periods and intermittently radiating the ultraviolet ray three or more times so that a total time of the non-radiation periods is 0.010 seconds or more.