An appliance cabinet includes a structural envelope having an exterior surface and an interior surface that defines an insulating cavity, wherein the insulating cavity defines an at least partial vacuum. A plurality of silica-based agglomerates are disposed within the insulating cavity, wherein each agglomerate of the plurality of silica-based agglomerates includes silica-based powder insulation material that is water-densified and is at least substantially free of a material binder. A secondary insulation material is disposed within interstitial spaces defined between the plurality of silica-based agglomerates, wherein the plurality of silica-based agglomerates defines an interior structure that resists inward compressive forces exerted as a result of the at least partial vacuum defined within the insulating cavity.

An appliance cabinet includes a structural envelope having an exterior surface and an interior surface that defines an insulating cavity, wherein the insulating cavity defines an at least partial vacuum. A plurality of silica-based agglomerates are disposed within the insulating cavity, wherein each agglomerate of the plurality of silica-based agglomerates includes silica-based powder insulation material that is water-densified and is at least substantially free of a material binder. A secondary insulation material is disposed within interstitial spaces defined between the plurality of silica-based agglomerates, wherein the plurality of silica-based agglomerates defines an interior structure that resists inward compressive forces exerted as a result of the at least partial vacuum defined within the insulating cavity.

A low-density, high-strength concrete composition that is lightweight and self-compacting or non-self-compacting, with a low weight-fraction of aggregate to total dry raw materials, and a highly-homogenous distribution of a non-absorptive and closed-cell lightweight aggregate such as glass microspheres or copolymer polymer beads or a combination thereof, and the steps of providing the composition or components. Lightweight concretes formed therefrom have low density, high strength-to-weight ratios, and high R-value. The concrete has strength similar to that ordinarily found in structural lightweight concrete but at a lower density, such as an oven-dried density as low as 40 lbs./cu.ft. Such strength-to-density ratios range approximately from above 30 cu.ft/sq.in. to above 110 cu.ft/sq.in., with a 28-day compressive strength ranging from about 3400 to 8000 psi.

A concrete composition having an optimized formulation and suitable for 3-D printing is provided. The composition may include a hydraulic cement composition, aggregate, cement and/or aggregate by-product dust, one or more rheology modifiers, a plasticizer, fibers, and a sufficient amount of water to effect setting of the composition. Optionally the concrete composition may include a setting agent. A method for 3D printing multiple layers of the concrete composition is also provided.

The use of polyol having a functionality of 4 or less and an OH group density of at least 0.033 mol OH per g polyol as a composition for reducing shrinking of construction chemicals on the basis of a hydraulic binder comprising a) alumina cement and/or calcium sulfoaluminate cement, b) calcium sulfate, and c) optionally Portland cement.