A new integrated method to capture polluted CO.sub.2 using CaO produced from phosphogypsum calcination using sulfur as non-CO.sub.2 fuel where (1) both pollutants of phosphogypsum and CO.sub.2 are transformed into environmentally neutral or useful products such as limestone or clinker and sulfuric acid; (2) low-CO.sub.2 CaO produced from calcination of phosphogypsum with sulfur as fuel can be used to produce low-CO.sub.2 clinker that replaces the use of high-CO.sub.2 limestone as raw material; (3) the use of sulfur as fuel to calcine phosphogypsum allows the production of low-cost sulfuric acid.

A new integrated method to capture polluted CO.sub.2 using CaO produced from phosphogypsum calcination using sulfur as non-CO.sub.2 fuel where (1) both pollutants of phosphogypsum and CO.sub.2 are transformed into environmentally neutral or useful products such as limestone or clinker and sulfuric acid; (2) low-CO.sub.2 CaO produced from calcination of phosphogypsum with sulfur as fuel can be used to produce low-CO.sub.2 clinker that replaces the use of high-CO.sub.2 limestone as raw material; (3) the use of sulfur as fuel to calcine phosphogypsum allows the production of low-cost sulfuric acid.

An apparatus for calcination of gypsum includes a gypsum calciner having an interior wall surface with a circular or annular configuration as seen in its plan view, and a tubular combustor positioned at a center part of a body of the calciner. Raw gypsum is calcined or dehydrated by a high temperature gas spouting flow (Hg) ejected from a lower portion of the combustor. The calciner has a stationary-vane-type or movable-vane-type auxiliary device, which circumferentially energizes the raw gypsum in the vicinity of the interior wall surface toward a circumferential direction of the calciner. The auxiliary device has a plurality of stationary vanes circumferentially arranged in an outer peripheral zone of a lower portion of the combustor and spaced apart from each other at an angular interval, or an agitator extending through a conical or inner circumferential surface defined by the interior wall surface.

An apparatus for calcination of gypsum includes a gypsum calciner having an interior wall surface with a circular or annular configuration as seen in its plan view, and a tubular combustor positioned at a center part of a body of the calciner. Raw gypsum is calcined or dehydrated by a high temperature gas spouting flow (Hg) ejected from a lower portion of the combustor. The calciner has a stationary-vane-type or movable-vane-type auxiliary device, which circumferentially energizes the raw gypsum in the vicinity of the interior wall surface toward a circumferential direction of the calciner. The auxiliary device has a plurality of stationary vanes circumferentially arranged in an outer peripheral zone of a lower portion of the combustor and spaced apart from each other at an angular interval, or an agitator extending through a conical or inner circumferential surface defined by the interior wall surface.

Multi-burner apparatus for calcining gypsum. In accordance with an implementation, an apparatus for calcining gypsum includes a housing and pair of burner assemblies positioned within the housing. Each burner assembly includes a burner, a fluidization plenum, an agitation frame positioned over the fluidization plenum, and a serpentine burner conduit extending through the housing between the burner and the fluidization plenum. The fluidization plenums of the burner assemblies are spaced from one another.