Heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is produced by polymerizing a polymerizable component containing (A) a nitrile monomer including acrylonitrile and methacrylonitrile, (B) a carboxyl-group-containing monomer, and (C) a monomer copolymerizable with the nitrile monomer (A) and the carboxyl-group-containing monomer (B). Further, the amount of the acrylonitrile in the nitrile monomer (A) ranges from 0.1 to 9 wt % based on the nitrile monomer (A). Also disclosed are hollow particles manufactured by heating and expanding the heat-expandable microspheres; a composition containing a base compound and at least one particulate material selected from the heat-expandable microspheres and the hollow particles; and a formed product manufactured by molding or applying a coat of the composition.

A process of fabricating a static structure including an interior volume that includes the steps of mixing coal combustible residual (CCR) with structural reinforcing materials to form a construction material and utilizing the construction material to fabricate exterior enclosure-forming components of the static structure. The enclosure-forming components are sufficiently reinforced, enhanced and/or thick to provide protection against exterior forces directed against the structure.

A method of expanding expandable polymeric microspheres including contacting an aqueous slurry including unexpanded, expandable polymeric microspheres with heat in-situ during manufacture of a cementitious composition or article, wherein the aqueous slurry optionally further includes an admixture therefor. A method of manufacturing a cementitious composition or article includes: (i) contacting an aqueous slurry of unexpanded, expandable polymeric microspheres with heat proximate to and/or during said manufacturing of the cementitious composition to create expanded polymeric microspheres; (ii) pre-wetting the expanded polymeric microspheres; and (iii) mixing the pre-wetted, expanded polymeric microspheres with cement and water to form the cementitious composition, wherein the aqueous slurry optionally further comprises an admixture therefor.

A method of expanding expandable polymeric microspheres including contacting an aqueous slurry including unexpanded, expandable polymeric microspheres with heat in-situ during manufacture of a cementitious composition or article, wherein the aqueous slurry optionally further includes an admixture therefor. A method of manufacturing a cementitious composition or article includes: (i) contacting an aqueous slurry of unexpanded, expandable polymeric microspheres with heat proximate to and/or during said manufacturing of the cementitious composition to create expanded polymeric microspheres; (ii) pre-wetting the expanded polymeric microspheres; and (iii) mixing the pre-wetted, expanded polymeric microspheres with cement and water to form the cementitious composition, wherein the aqueous slurry optionally further comprises an admixture therefor.

A method of expanding expandable polymeric microspheres including contacting an aqueous slurry including unexpanded, expandable polymeric microspheres with heat in-situ during manufacture of cement. A method of manufacturing cement includes: (i) contacting an aqueous slurry of unexpanded, expandable polymeric microspheres with heat proximate to and/or during said manufacturing of cement to create expanded polymeric microspheres; (ii) optionally pre-wetting the expanded polymeric microspheres; and (iii) mixing the expanded polymeric microspheres with cement.

A method of expanding expandable polymeric microspheres including contacting an aqueous slurry including unexpanded, expandable polymeric microspheres with heat in-situ during manufacture of cement. A method of manufacturing cement includes: (i) contacting an aqueous slurry of unexpanded, expandable polymeric microspheres with heat proximate to and/or during said manufacturing of cement to create expanded polymeric microspheres; (ii) optionally pre-wetting the expanded polymeric microspheres; and (iii) mixing the expanded polymeric microspheres with cement.

A method of expanding expandable polymeric microspheres including contacting an aqueous slurry including unexpanded, expandable polymeric microspheres with heat in-situ during manufacture of a construction material. A method of manufacturing a construction material includes: (i) contacting an aqueous slurry of unexpanded, expandable polymeric microspheres with heat proximate to and/or during said manufacturing of the construction material to create expanded polymeric microspheres; (ii) optionally pre-wetting the expanded polymeric microspheres; and (iii) mixing the expanded polymeric microspheres with the construction material.

A method of expanding expandable polymeric microspheres including contacting an aqueous slurry including unexpanded, expandable polymeric microspheres with heat in-situ during manufacture of a construction material. A method of manufacturing a construction material includes: (i) contacting an aqueous slurry of unexpanded, expandable polymeric microspheres with heat proximate to and/or during said manufacturing of the construction material to create expanded polymeric microspheres; (ii) optionally pre-wetting the expanded polymeric microspheres; and (iii) mixing the expanded polymeric microspheres with the construction material.

An oil well cement composite permeation enhancement agent suitable for a hydrate layer and a preparation method thereof are disclosed. In parts by weight, the composition of raw materials of the composite permeation enhancement agent is 4.6 parts-5.0 parts of kerosene, 0.23 parts-0.25 parts of emulsifier, 0.8 parts-1.1 parts of modified polypropylene fiber, 10.0 parts-12.0 parts of porous and permeable microspheres, 1.0 part-1.2 parts of paraffin, and 57.5 parts-62.5 parts of water. The composite permeation enhancement agent can effectively improve the permeability of the cement stone which reshapes the formation framework and increase the mining rate of hydrate. The oil well cement composite permeation enhancement agent has the advantages of long-term performance, low cost, and green environmental protection. The composite permeation enhancement agent of the present invention does not need secondary treatment to increase permeation, the operation is convenient and fast, and the working time of holding pressure is reduced.

An oil well cement composite permeation enhancement agent suitable for a hydrate layer and a preparation method thereof are disclosed. In parts by weight, the composition of raw materials of the composite permeation enhancement agent is 4.6 parts-5.0 parts of kerosene, 0.23 parts-0.25 parts of emulsifier, 0.8 parts-1.1 parts of modified polypropylene fiber, 10.0 parts-12.0 parts of porous and permeable microspheres, 1.0 part-1.2 parts of paraffin, and 57.5 parts-62.5 parts of water. The composite permeation enhancement agent can effectively improve the permeability of the cement stone which reshapes the formation framework and increase the mining rate of hydrate. The oil well cement composite permeation enhancement agent has the advantages of long-term performance, low cost, and green environmental protection. The composite permeation enhancement agent of the present invention does not need secondary treatment to increase permeation, the operation is convenient and fast, and the working time of holding pressure is reduced.