A method may include comprising: defining engineering parameters of a proposed cement slurry, the engineering parameters comprising at least a compressive strength requirement, a density requirement, a storage time requirement, and a thickening time requirement; selecting, based at least in part on a model of compressive strength, a model of storage time, and the density requirement, at least a cement and mass fraction thereof, at least one supplementary cementitious material and mass fraction thereof, and a water and mass fraction thereof, such that a set cement formed from the cement, the at least one supplementary cementitious material, and the water meets or exceeds the compressive strength requirement and the density requirement; selecting, based at least in part on a model of thickening time, an accelerator and mass fraction thereof; and preparing a cement slurry comprising the cement and mass fraction thereof, the at least one supplementary cementitious material and mass fraction thereof, the water and mass fraction thereof, and the cement retarder and mass fraction thereof.

A method may include comprising: defining engineering parameters of a proposed cement slurry, the engineering parameters comprising at least a compressive strength requirement, a density requirement, a storage time requirement, and a thickening time requirement; selecting, based at least in part on a model of compressive strength, a model of storage time, and the density requirement, at least a cement and mass fraction thereof, at least one supplementary cementitious material and mass fraction thereof, and a water and mass fraction thereof, such that a set cement formed from the cement, the at least one supplementary cementitious material, and the water meets or exceeds the compressive strength requirement and the density requirement; selecting, based at least in part on a model of thickening time, an accelerator and mass fraction thereof; and preparing a cement slurry comprising the cement and mass fraction thereof, the at least one supplementary cementitious material and mass fraction thereof, the water and mass fraction thereof, and the cement retarder and mass fraction thereof.

A synchronous single-liquid grouting slurry, its technology and application for large diameter shield engineering under water-rich, high-pressure and weak soil strata conditions, comprising raw materials: 1050-1200 parts of gold tailing, 420-480 parts of silicate cement clinker, 220-240 parts of fly ash, 45-120 parts of waste clay brick, 65-95 parts of slag, 25-45 parts of limestone tailing, 70-80 parts of steel slag, 30-45 parts of silica fume, 15-22 parts of desulfurized gypsum, and 9-15 parts of quick-setting and early-strength composite additive. The invention controls the d.sub.50, d.sub.85 and d.sub.95 of the material particles as 35-40, 42-48 and 50-55 μm, respectively. Gold tailing with the particle size of 120-600 μm being used as the fine aggregate, their volume fractions are 40-60%. The slurry production technique, comprising crushing-sieving-superfine ball milling-homogenization-particle size classification-variable speed mixing being developed. The shield tail eight-point grouting technique is being developed for filling.

A method of designing a cement slurry may include: (a) selecting at least a cement and concentration thereof, a water and concentration thereof, and one or more chemical additives and a concentration thereof such that a cement slurry formed from the cement, water, and the one or more chemical additives meet a density requirement; (b) calculating a thickening time of the cement slurry using a thickening time model; (c) comparing the thickening time of the cement slurry to a thickening time requirement, wherein steps (a)-(c) are repeated if the thickening time of the cement slurry does not meet or exceed the thickening time requirement, wherein the step of selecting comprises selecting concentrations and/or different chemical identities for the one or more chemical additives, cement, or water, or step (d) is performed if the thickening time of the cement slurry meets or exceeds the thickening time requirement; and (d) preparing the cement slurry.

A method of designing a cement slurry may include: (a) selecting at least a cement and concentration thereof, a water and concentration thereof, and one or more chemical additives and a concentration thereof such that a cement slurry formed from the cement, water, and the one or more chemical additives meet a density requirement; (b) calculating a thickening time of the cement slurry using a thickening time model; (c) comparing the thickening time of the cement slurry to a thickening time requirement, wherein steps (a)-(c) are repeated if the thickening time of the cement slurry does not meet or exceed the thickening time requirement, wherein the step of selecting comprises selecting concentrations and/or different chemical identities for the one or more chemical additives, cement, or water, or step (d) is performed if the thickening time of the cement slurry meets or exceeds the thickening time requirement; and (d) preparing the cement slurry.

Disclosed herein are methods and compositions for cementing. An example method may comprise providing a cement composition. The cement composition may comprise a composite cementitious material comprising a micronized particulate solid and a monophase amorphous hydraulic binder. The micronized particulate solid may have a mean particle size of about 500 microns or less. The cement composition may further comprise water. The method may further comprise introducing the cement composition into a subterranean formation; and allowing the cement composition to set.

Disclosed herein are methods and compositions for cementing. An example method may comprise providing a cement composition. The cement composition may comprise a composite cementitious material comprising a micronized particulate solid and a monophase amorphous hydraulic binder. The micronized particulate solid may have a mean particle size of about 500 microns or less. The cement composition may further comprise water. The method may further comprise introducing the cement composition into a subterranean formation; and allowing the cement composition to set.

A method of producing a cement composition with reduced carbon emissions may include: defining cement constraints comprising at least one cement property; calculating a set of cement compositions which satisfy the cement constraints, using cement property models corresponding to the cement constraints; calculating a carbon emission associated with each of the cement compositions in the set of cement compositions using a carbon footprint model; selecting a cement composition from the set of cement compositions; and preparing the cement composition.

A method of producing a cement composition with reduced carbon emissions may include: defining cement constraints comprising at least one cement property; calculating a set of cement compositions which satisfy the cement constraints, using cement property models corresponding to the cement constraints; calculating a carbon emission associated with each of the cement compositions in the set of cement compositions using a carbon footprint model; selecting a cement composition from the set of cement compositions; and preparing the cement composition.

Methods, compositions, and tools for use in creating rapidly forming plugs in situ in subterranean formations. In one instance, the disclosure provides a method that includes: placing a first pill comprising a calcium-aluminate-based cement composition at a plug location within the wellbore with the tubing; and placing a second pill comprising an alkaline fluid composition into the wellbore adjacent to the first pill with the tubing. In some cases there is a spacer fluid or spacer device between the first pill and the second pill. In some cases tubing having a mixing device is located at the bottom of the tubing in the wellbore to aid I mixing the first pill and the second pill to facilitate a chemical in situ reaction of the first pill and the second pill. The reaction between the first pill and the second pill forms a set plug at the plug location.