The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.

This invention relates to manufacturing briquettes, pellets and shapes from recycled asphaltic limestone powder derived from waste residential roofing products. Briquettes and pellets are manufactured through a densification process at varying temperatures, creating recycled asphalt pellets, asphalt limestone pellets and bio mass and coal fines briquettes. Various shapes, including curbs and posts, are manufactured through heat and pressure in molds. Seawalls, walkways and wall panels are manufactured by blending asphaltic limestone powders with polymer resins and extruded or pultruded into shapes.

This invention relates to manufacturing briquettes, pellets and shapes from recycled asphaltic limestone powder derived from waste residential roofing products. Briquettes and pellets are manufactured through a densification process at varying temperatures, creating recycled asphalt pellets, asphalt limestone pellets and bio mass and coal fines briquettes. Various shapes, including curbs and posts, are manufactured through heat and pressure in molds. Seawalls, walkways and wall panels are manufactured by blending asphaltic limestone powders with polymer resins and extruded or pultruded into shapes.

A process comprising the following steps: a) calcination of a metal carbonate by combustion of a fuel in the presence of a mixture of oxygen, water vapour and carbon dioxide, to generate a metal oxide, water vapour, carbon dioxide and heat; b) using the heat generated to drive an oxygen generation reaction; and c) use of the oxygen generated in step b) in calcination step a). The use of the process on carbon dioxide sequestration and/or in oxygen generation.

An improved lime mud recycling system including a camera proximate the kiln outlet imaging the granular lime and providing outlet images of the granular lime exiting the kiln, a processor analyzing the outlet images of the granular lime and providing pebble size distributions for the granular lime exiting the kiln, as well as a controller communicating with the processor comparing the pebble size distribution of the granular lime exiting the kiln with predetermined prescribed operating parameters for pebble size distributions for the granular lime exiting the kiln and issuing (I) a notification and/or (II) a control signal prompting remedial action when the pebble size distributions for the granular lime exiting the kiln are outside of the predetermined prescribed operating parameters.

The invention relates to a plant for generating negative emissions of CO.sub.2. The plant 100 comprises a gasifier 110, a lime kiln 130, a separator 150, and a CO.sub.2 permanent storage 170. The gasifier is suitable for receiving as input a fuel 111 and for producing as output a high-temperature syngas flow 114. The lime kiln is suitable for receiving as input carbonate mineral 131 and the high-temperature syngas flow, the lime kiln being further suitable for producing an oxide 134 and for releasing as output a flow of syngas 133 enriched with CO.sub.2. The separator is suitable for receiving as input a gas flow containing CO.sub.2 and for treating it so as to separately provide at least CO.sub.2 151. The CO.sub.2 permanent storage is suitable for enclosing along time the CO.sub.2. The invention also relates to a method for generating negative emissions of CO.sub.2.

An improved lime mud recycling system including a camera proximate the kiln outlet imaging the granular lime and providing outlet images of the granular lime exiting the kiln, a processor analyzing the outlet images of the granular lime and providing pebble size distributions for the granular lime exiting the kiln, as well as a controller communicating with the processor comparing the pebble size distribution of the granular lime exiting the kiln with predetermined prescribed operating parameters for pebble size distributions for the granular lime exiting the kiln and issuing (I) a notification and/or (II) a control signal prompting remedial action when the pebble size distributions for the granular lime exiting the kiln are outside of the predetermined prescribed operating parameters.

An arrangement for burning lime mud into lime in a lime kiln. The lime mud flows counter-currently to flue gases from a feed end to a firing end and the fuel used is flue gas that is produced by gasifying a fuel in the presence of combustion air in a gasifier. The combustion air for gasification is preheated with heat generated in lime mud combustion. The arrangement is provided with a conduit between the lime kiln and the gasifier for leading air from the lime kiln into the gasifier as combustion air. At least a portion of the combustion air for gasification is preheated with heat generated in the lime mud combustion so that air is led into cooling of lime obtained in the combustion and further into the kiln, from or through the firing end of which air is taken into the gasification.

An arrangement for burning lime mud into lime in a lime kiln. The lime mud flows counter-currently to flue gases from a feed end to a firing end and the fuel used is flue gas that is produced by gasifying a fuel in the presence of combustion air in a gasifier. The combustion air for gasification is preheated with heat generated in lime mud combustion. The arrangement is provided with a conduit between the lime kiln and the gasifier for leading air from the lime kiln into the gasifier as combustion air. At least a portion of the combustion air for gasification is preheated with heat generated in the lime mud combustion so that air is led into cooling of lime obtained in the combustion and further into the kiln, from or through the firing end of which air is taken into the gasification.

The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.