Examples of new polymer-modified cement formulations with self-healing capability at ambient temperature are described. These polymer-modified cements can be readily mixed with typical fine and coarse aggregates to build new concrete structures. One example of such a formulation includes a concrete comprising a MBA-BDA polymer having bond forming chemical functionality configured to form a bonding matrix between the polymer and at least one component of the concrete at a temperature less than 50 degrees C. wherein the matrix obtains at least 70% recovery of compressive strength after a damage event.

Examples of new polymer-modified cement formulations with self-healing capability at ambient temperature are described. These polymer-modified cements can be readily mixed with typical fine and coarse aggregates to build new concrete structures. One example of such a formulation includes a concrete comprising a MBA-BDA polymer having bond forming chemical functionality configured to form a bonding matrix between the polymer and at least one component of the concrete at a temperature less than 50 degrees C. wherein the matrix obtains at least 70% recovery of compressive strength after a damage event.

A variety of methods and compositions are disclosed, including, in one embodiment a method a cementing in a subterranean formation comprising: providing a set-delayed cement composition comprising water, pumice, hydrated lime, and a set retarder; foaming the set-delayed cement composition; activating the set-delayed cement composition; introducing the set-delayed cement composition into a subterranean formation; and allowing the set-delayed cement composition to set in the subterranean formation. Additional methods, foamed set-delayed cement composition, and systems for cementing are also provided.

A variety of methods and compositions are disclosed, including, in one embodiment a method a cementing in a subterranean formation comprising: providing a set-delayed cement composition comprising water, pumice, hydrated lime, and a set retarder; foaming the set-delayed cement composition; activating the set-delayed cement composition; introducing the set-delayed cement composition into a subterranean formation; and allowing the set-delayed cement composition to set in the subterranean formation. Additional methods, foamed set-delayed cement composition, and systems for cementing are also provided.

A chemical additive for calcium sulphoaluminate-modified Portland cement comprises the following substances: (a) at least one alkanolamine borate; (b) at least one organic alcohol; and (c) at least one saccharide or a derivative thereof; and the substances and water are sequentially mixed and stirred to obtain the chemical additive for calcium sulphoaluminate-modified Portland cement. The chemical additive for calcium sulphoaluminate-modified Portland cement provided by the invention has better effects of regulating the setting time of the calcium sulphoaluminate-modified Portland cement and improving the 3d/28d strength increase rate, and also has a grinding aid effect when being added during grinding.

A chemical additive for calcium sulphoaluminate-modified Portland cement comprises the following substances: (a) at least one alkanolamine borate; (b) at least one organic alcohol; and (c) at least one saccharide or a derivative thereof; and the substances and water are sequentially mixed and stirred to obtain the chemical additive for calcium sulphoaluminate-modified Portland cement. The chemical additive for calcium sulphoaluminate-modified Portland cement provided by the invention has better effects of regulating the setting time of the calcium sulphoaluminate-modified Portland cement and improving the 3d/28d strength increase rate, and also has a grinding aid effect when being added during grinding.

A set control composition for cementitious systems comprises (a) an amine-glyoxylic acid condensate, and (b) at least one of (i) a borate source and (ii) a carbonate source. The carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 gL.sup.−1 or more, and organic carbonates. The set control composition improves workability of cementitious systems for prolonged periods of time without compromising early compressive strength. Due to the retarding action of the set control composition, the dosage of dispersant(s) necessary to obtain a desired flowability of the cementitious system can be reduced.

A set control composition for cementitious systems comprises (a) an amine-glyoxylic acid condensate, and (b) at least one of (i) a borate source and (ii) a carbonate source. The carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 gL.sup.−1 or more, and organic carbonates. The set control composition improves workability of cementitious systems for prolonged periods of time without compromising early compressive strength. Due to the retarding action of the set control composition, the dosage of dispersant(s) necessary to obtain a desired flowability of the cementitious system can be reduced.

A set control composition for cementitious systems comprises (a) an amine-glyoxylic acid condensate, and (b) at least one of (i) a borate source and (ii) a carbonate source. The carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 gL.sup.−1 or more, and organic carbonates. The set control composition improves workability of cementitious systems for prolonged periods of time without compromising early compressive strength. Due to the retarding action of the set control composition, the dosage of dispersant(s) necessary to obtain a desired flowability of the cementitious system can be reduced.

A set control composition for cementitious systems comprises (a) an amine-glyoxylic acid condensate, and (b) at least one of (i) a borate source and (ii) a carbonate source. The carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 gL.sup.−1 or more, and organic carbonates. The set control composition improves workability of cementitious systems for prolonged periods of time without compromising early compressive strength. Due to the retarding action of the set control composition, the dosage of dispersant(s) necessary to obtain a desired flowability of the cementitious system can be reduced.