Described are a composition comprising furfuryl silicates and furfuryl alcohol, especially for use as acid-curable binder, and processes for producing such a composition.

A method for producing a sand mold includes mixing artificial sand with a furan resin composition including a furan resin precursor, preparing molding sand having the artificial sand and a surface-modified layer containing a resin cured product covering the artificial sand and including a curing agent attached to the surface-modified layer by mixing the curing agent including xylene sulfonic acid with the artificial sand with which the furan resin composition is mixed, and curing the furan resin composition, after mixing the artificial sand with the furan resin composition, and curing an added portion of the binder in the molding sand by adding the binder to the molding sand. In the step of curing the added portion of the binder, the curing agent for curing the furan resin composition is used also as a curing agent for curing the binder.

A method for producing a sand mold includes mixing artificial sand with a furan resin composition including a furan resin precursor, preparing molding sand having the artificial sand and a surface-modified layer containing a resin cured product covering the artificial sand and including a curing agent attached to the surface-modified layer by mixing the curing agent including xylene sulfonic acid with the artificial sand with which the furan resin composition is mixed, and curing the furan resin composition, after mixing the artificial sand with the furan resin composition, and curing an added portion of the binder in the molding sand by adding the binder to the molding sand. In the step of curing the added portion of the binder, the curing agent for curing the furan resin composition is used also as a curing agent for curing the binder.

Methods for treating and restoring zonal isolation in a subterranean well involve the use of a well treatment tool that may drill one or more holes in casing and inject a treatment fluid that may seal cracks or fissures in the cement sheath behind the casing. Microannuli may also be sealed. The treatment fluids may be solids free or in the form of suspensions containing solids having a particle size between 1 nm and 100 nm.

A refractory, coarse ceramic product including at least one granular refractory material, has an open porosity of between 22 and 45 vol.-%, in particular of between 23 and 29 vol.-%, and a grain structure of the refractory material, wherein the medium grain size fraction with grain sizes of between 0.1 and 0.5 mm is 10 to 55 wt.-%, in particular 35 to 50 wt.-%, and wherein the remainder of the grain structure is a finest grain fraction with grain sizes of up to 0.1 mm and/or coarse-grain fraction with grain sizes of more than 0.5 mm.

A refractory, coarse ceramic product including at least one granular refractory material, has an open porosity of between 22 and 45 vol.-%, in particular of between 23 and 29 vol.-%, and a grain structure of the refractory material, wherein the medium grain size fraction with grain sizes of between 0.1 and 0.5 mm is 10 to 55 wt.-%, in particular 35 to 50 wt.-%, and wherein the remainder of the grain structure is a finest grain fraction with grain sizes of up to 0.1 mm and/or coarse-grain fraction with grain sizes of more than 0.5 mm.

A method for producing a sand mold includes mixing artificial sand with a furan resin composition including a furan resin precursor, preparing molding sand having the artificial sand and a surface-modified layer containing a resin cured product covering the artificial sand and including a curing agent attached to the surface-modified layer by mixing the curing agent including xylene sulfonic acid with the artificial sand with which the furan resin composition is mixed, and curing the furan resin composition, after mixing the artificial sand with the furan resin composition, and curing an added portion of the binder in the molding sand by adding the binder to the molding sand. In the step of curing the added portion of the binder, the curing agent for curing the furan resin composition is used also as a curing agent for curing the binder.

A method for producing a sand mold includes mixing artificial sand with a furan resin composition including a furan resin precursor, preparing molding sand having the artificial sand and a surface-modified layer containing a resin cured product covering the artificial sand and including a curing agent attached to the surface-modified layer by mixing the curing agent including xylene sulfonic acid with the artificial sand with which the furan resin composition is mixed, and curing the furan resin composition, after mixing the artificial sand with the furan resin composition, and curing an added portion of the binder in the molding sand by adding the binder to the molding sand. In the step of curing the added portion of the binder, the curing agent for curing the furan resin composition is used also as a curing agent for curing the binder.

Described are a composition comprising furfuryl silicates and furfuryl alcohol, especially for use as acid-curable binder, and processes for producing such a composition.

A method for producing molding sand includes mixing an artificial sand with a furan resin composition including a furan resin precursor, and mixing a curing agent with the artificial sand with which the furan resin composition is mixed, wherein the curing agent includes xylene sulfonic acid.