The invention discloses a method of making waterproof magnesium oxychloride refractory brick using fly ash from municipal solid waste incineration (MSWFA). The solidification and stabilization of heavy metals in MSWFA is achieved by the chemical action of a sulfur-containing compound and a physical wrapping of a geopolymer. The large amount of chloride ions in MSWFA is also reused in the manufacture of magnesium oxychloride refractory brick, which requires a high chlorine environment. This method, with the inclusion of the geopolymer, also produces refractory brick exhibiting improved water resistance relative to traditional magnesium oxychloride refractory brick, thereby allowing the improved magnesium oxychloride refractory brick to be used in a wider range of applications.

A ceramic membrane is provided, which may include glass, incinerator fly ash, kaolin and palygorskite. The weight percent of the glass may be 3060 wt %. The weight percent of the incinerator fly ash may be 530 wt %. The weight percent of the kaolin may be 050 wt %. The weight percent of the palygorskite is 030 wt %.

The invention discloses a method of making waterproof magnesium oxychloride refractory brick by fly ash from municipal solid waste incineration. The method comprises the following steps: (1) sulfur-containing compound and water are mixed into the fly ash and stirred evenly to make stabilized slurry, the heavy metals are stabilized and CaO is turned to Ca(OH).sub.2 during this process. (2) The aqueous solution of MgO and MgCl.sub.2 is added into the stabilized slurry to make magnesium oxychloride slurry by being stirred evenly. (3) The magnesium oxychloride slurry is cured to make magnesium oxychloride gel, (4) and the magnesium oxychloride aggregate is prepared by crushing the magnesium oxychloride gel. (5) The blended slurry is prepared by mixing metastable material, alkali metal hydroxide, Na.sub.2SiO.sub.3, magnesium oxychloride aggregate and water, (6) after being stirred, molded and cured, the waterproof magnesium oxychloride refractory brick is obtained. The waterproof magnesium oxychloride refractory brick made by this invention combines two materials, the geopolymer gel and the magnesium oxychloride gel, which possess different properties of fire resistance and water resistance. It is confirmed that the coexistence of geopolymer gel and magnesium oxychloride gel achieves the multi-stage solidification and stabilization of heavy metals and improving the water resistance of magnesium oxychloride refractory brick.

According to one aspect of the invention, a method to create a ceramic waste form from used nuclear fuel. An active metal salt waste, a rare earth metal waste, and raw materials are received. The active metal salt waste is combined with the rare earth metal waste, forming a waste salt. The waste salt is then heated to approximately 500 C. The raw materials are also heated to approximately 500 C. The waste salt and raw materials are then blended to form a homogenous waste mixture. The homogenous waste mixture is heated to a first predetermined temperature for a predetermined amount of time, creating a ceramic waste form. The ceramic waste form is cooled to a second predetermined temperature.

According to one aspect of the invention, a method to create a ceramic waste form from used nuclear fuel. An active metal salt waste, a rare earth metal waste, and raw materials are received. The active metal salt waste is combined with the rare earth metal waste, forming a waste salt. The waste salt is then heated to approximately 500 C. The raw materials are also heated to approximately 500 C. The waste salt and raw materials are then blended to form a homogenous waste mixture. The homogenous waste mixture is heated to a first predetermined temperature for a predetermined amount of time, creating a ceramic waste form. The ceramic waste form is cooled to a second predetermined temperature.

Drill cuttings, initially cleaned to remove a majority of drilling fluids therefrom, but which have residual organic species, including hydrocarbons, therein are used in clean technologies to make a wide variety of ceramic and concrete products, such as tiles, slabs, blocks, bricks, pavers, decorative edgings, planters, modular barriers, embankments, medians, dividers, precast products and the like for a variety of commercial sectors. In the case of the concrete products, the organic species in the drill cuttings, including hydrocarbons, are first minimized or degraded in the drill cuttings using an oxidative process, such as photocatalytic oxidation, use of an oxidant or combinations thereof, prior to mixing the drill cuttings with cement and water, to form various concrete products. The products produced have acceptable compressive strengths and minimize or eliminate any leaching of the drill cutting contaminants therefrom. In the case of the ceramic and advanced ceramic products, the hydrocarbons and other contaminants are melted during the process of firing the ceramic products in the kiln. The kiln temperature is carefully controlled to minimize safety issues, which would otherwise be associated with the presence of at least the hydrocarbons in the products.

A biochar is produced by co-pyrolysing an aquatic plant enriched with heavy metals with a clay mineral, and the aquatic plants themselves have high enrichment and adsorb heavy metals in contaminated water; heavy metals are in situ adsorbed, and are coated or enriched in the biochar, therefore extending the migration time of heavy metals, which are also very stable; attapulgite and montmorillonite as clay minerals are loaded in the biochar during the preparing process; heavy metals contained in the biochar play a catalytic role, and synergy with activated attapulgite, therefore increasing the reliability of the biochar, and effectively reducing the ecological effectiveness and potential risk of heavy metals in the biochar.