Methods of making permeable aerogels (100) can include providing a sol mixture (110) comprising an organic scaffold, an inorganic aerogel precursor, and a first solvent. The organic scaffold can be insoluble in the first solvent. The sol mixture can react to form a gel (120) such that an interconnected channel network is formed which is at least partially defined by the organic scaffold. The first solvent in the gel can be exchanged (130) with a second solvent. The second solvent can dissolve the organic scaffold to expose the interconnected channel network. The gel can be dried (140) to form the permeable aerogel.

Methods of making permeable aerogels (100) can include providing a sol mixture (110) comprising an organic scaffold, an inorganic aerogel precursor, and a first solvent. The organic scaffold can be insoluble in the first solvent. The sol mixture can react to form a gel (120) such that an interconnected channel network is formed which is at least partially defined by the organic scaffold. The first solvent in the gel can be exchanged (130) with a second solvent. The second solvent can dissolve the organic scaffold to expose the interconnected channel network. The gel can be dried (140) to form the permeable aerogel.

The present invention relates to a foam material comprising:—a structural matrix (1),—at least one guest phase (2), and—a fluid, the material being characterised in that the structural matrix (1) comprises a plurality of interconnected pores (3), the one or more guest phases (2) are accommodated inside at least one pore (3) of the structural matrix (1) and the fluid is accommodated inside the pores (3). The present invention further relates to the process for preparing the foam material according to the present invention and to the various uses of the foam material according to the present invention.

The present invention relates to a foam material comprising:—a structural matrix (1),—at least one guest phase (2), and—a fluid, the material being characterised in that the structural matrix (1) comprises a plurality of interconnected pores (3), the one or more guest phases (2) are accommodated inside at least one pore (3) of the structural matrix (1) and the fluid is accommodated inside the pores (3). The present invention further relates to the process for preparing the foam material according to the present invention and to the various uses of the foam material according to the present invention.

The present invention concerns a process for the preparation of a porous carbon structure comprising the steps: a) providing a template comprising voids, b) filling of at least part of the voids with a precursor for the formation of the porous carbon structure, c) carbonizing the precursor for the formation of the porous carbon structure and d) removing at least part of the template. In preferred embodiments the precursor for the formation of the porous carbon structure is a formaldehyde-phenol resin, especially a cross-linked resorcinol-formaldehyde resin. The template further preferably comprises a block copolymer and an amphiphilic molecule, wherein the block copolymer comprises polymeric units of at least one lipophilic monomer and polymeric units of at least one hydrophilic monomer. Further preferred is a process wherein the template comprises a bimodal mixture of particles of silicon dioxide.

The present invention concerns a process for the preparation of a porous carbon structure comprising the steps: a) providing a template comprising voids, b) filling of at least part of the voids with a precursor for the formation of the porous carbon structure, c) carbonizing the precursor for the formation of the porous carbon structure and d) removing at least part of the template. In preferred embodiments the precursor for the formation of the porous carbon structure is a formaldehyde-phenol resin, especially a cross-linked resorcinol-formaldehyde resin. The template further preferably comprises a block copolymer and an amphiphilic molecule, wherein the block copolymer comprises polymeric units of at least one lipophilic monomer and polymeric units of at least one hydrophilic monomer. Further preferred is a process wherein the template comprises a bimodal mixture of particles of silicon dioxide.

A mesoporous metal oxide materials with a chiral organization; and a method for producing it, in the method a polymerizable metal oxide precursor is condensed inside the pores of chiral nematic mesoporous silica by the so-called “hard templating” method. As a specific example, mesoporous titanium dioxide is formed inside of a chiral nematic silica film templated by nanocrystalline cellulose (NCC). After removing the silica template such as by dissolving the silica in concentrated aqueous base, the resulting product is a mesoporous titania with a high surface area. These mesoporous metal oxide materials with high surface area and chiral nematic structures that lead to photonic properties may be useful for photonic applications as well as enantioselective catalysis, photocatalysis, photovoltaics, UV filters, batteries, and sensors.

A mesoporous metal oxide materials with a chiral organization; and a method for producing it, in the method a polymerizable metal oxide precursor is condensed inside the pores of chiral nematic mesoporous silica by the so-called “hard templating” method. As a specific example, mesoporous titanium dioxide is formed inside of a chiral nematic silica film templated by nanocrystalline cellulose (NCC). After removing the silica template such as by dissolving the silica in concentrated aqueous base, the resulting product is a mesoporous titania with a high surface area. These mesoporous metal oxide materials with high surface area and chiral nematic structures that lead to photonic properties may be useful for photonic applications as well as enantioselective catalysis, photocatalysis, photovoltaics, UV filters, batteries, and sensors.

Methods of making permeable aerogels (100) can include providing a sol mixture (110) comprising an organic scaffold, an inorganic aerogel precursor, and a first solvent. The organic scaffold can be insoluble in the first solvent. The sol mixture can react to form a gel (120) such that an interconnected channel network is formed which is at least partially defined by the organic scaffold. The first solvent in the gel can be exchanged (130) with a second solvent. The second solvent can dissolve the organic scaffold to expose the interconnected channel network. The gel can be dried (140) to form the permeable aerogel.

Methods of making permeable aerogels (100) can include providing a sol mixture (110) comprising an organic scaffold, an inorganic aerogel precursor, and a first solvent. The organic scaffold can be insoluble in the first solvent. The sol mixture can react to form a gel (120) such that an interconnected channel network is formed which is at least partially defined by the organic scaffold. The first solvent in the gel can be exchanged (130) with a second solvent. The second solvent can dissolve the organic scaffold to expose the interconnected channel network. The gel can be dried (140) to form the permeable aerogel.