The present invention relates to the field of foam formation and stabilization, particularly foamed construction materials, such as cement. Disclosed are additives suitable to obtain mineral foams when added to the corresponding starting materials. The invention provides a ready-to-use product in the form of a solid particulate composition comprising hydrophobized particles (1) and catalytically active particles (2) as defined in claim 1. The invention further provides for manufacturing methods of such ready-to-use product.

The present invention relates to the field of foam formation and stabilization, particularly foamed construction materials, such as cement. Disclosed are additives suitable to obtain mineral foams when added to the corresponding starting materials. The invention provides a ready-to-use product in the form of a solid particulate composition comprising hydrophobized particles (1) and catalytically active particles (2) as defined in claim 1. The invention further provides for manufacturing methods of such ready-to-use product.

The present invention is a method for producing a powder dispersant composition for hydraulic compositions including, drying a mixture containing a copolymer having constituent unit (1) represented by the following formula (1) and constituent unit (2) represented by the following formula (2) and water to produce a powder containing the copolymer, wherein: when the copolymer is a copolymer whose n in constituent unit (2) is less than 40, the mixture is dried by a thin film drying method or a spray drying method with a pH of 11 or more and 14 or less; when the copolymer is a copolymer whose n in constituent unit (2) is 40 or more and less than 80, the mixture is dried by a thin film drying method or a spray drying method with a pH of 9 or more and 14 or less; and when the copolymer is a copolymer whose n in constituent unit (2) is 80 or more, the mixture is dried by a thin film drying method or a spray drying method with a pH of 7 or more and 14 or less,

##STR00001## wherein R.sup.1 and R.sup.3 are the same or different and individually represent a hydrogen atom or a methyl group; R.sup.2 and R.sup.4 are the same or different and individually represent a hydrogen atom or an alkyl group with 1 or more and 3 or less carbons; M represents a hydrogen atom, an alkali metal, an alkaline-earth metal, ammonium or an organic ammonium; p represents a number of 0 or more and 2 or less; q represents a number of 0 or 1; and n represents an average number of added moles and a number of 5 or more and 150 or less.

The present invention is a method for producing a powder dispersant composition for hydraulic compositions including, drying a mixture containing a copolymer having constituent unit (1) represented by the following formula (1) and constituent unit (2) represented by the following formula (2) and water to produce a powder containing the copolymer, wherein: when the copolymer is a copolymer whose n in constituent unit (2) is less than 40, the mixture is dried by a thin film drying method or a spray drying method with a pH of 11 or more and 14 or less; when the copolymer is a copolymer whose n in constituent unit (2) is 40 or more and less than 80, the mixture is dried by a thin film drying method or a spray drying method with a pH of 9 or more and 14 or less; and when the copolymer is a copolymer whose n in constituent unit (2) is 80 or more, the mixture is dried by a thin film drying method or a spray drying method with a pH of 7 or more and 14 or less,

##STR00001## wherein R.sup.1 and R.sup.3 are the same or different and individually represent a hydrogen atom or a methyl group; R.sup.2 and R.sup.4 are the same or different and individually represent a hydrogen atom or an alkyl group with 1 or more and 3 or less carbons; M represents a hydrogen atom, an alkali metal, an alkaline-earth metal, ammonium or an organic ammonium; p represents a number of 0 or more and 2 or less; q represents a number of 0 or 1; and n represents an average number of added moles and a number of 5 or more and 150 or less.

A refractory composition including refractory aggregate, one or more matrix components, and silicate-coated set accelerator particles. The silicate-coated set accelerator particles can include one more of silicate-coated calcium hydroxide, magnesium hydroxide, calcium chloride, calcium carbonate, magnesium carbonate and calcium sulfate. Suitable silicate coatings include sodium silicate, potassium silicate, lithium silicate and mixtures thereof. A method of recovering an aged refractory composition, a settable composition and a method of manufacturing silicate-coated calcium hydroxide particles are also provided.

A highly thixotropic 3D printing concrete and a manufacturing method therefor are provided. The weight percentage of each component calculated per cube of concrete is: 35-40% of cement, 0.1-0.4% of polycarboxylate superplasticizer, 0.1-0.4% of polypropylene fiber, 1.0-3.0% of special thixotropic agent for 3D printing concrete, and 12.5-14.5% of water, and the remainder is sand.

A highly thixotropic 3D printing concrete and a manufacturing method therefor are provided. The weight percentage of each component calculated per cube of concrete is: 35-40% of cement, 0.1-0.4% of polycarboxylate superplasticizer, 0.1-0.4% of polypropylene fiber, 1.0-3.0% of special thixotropic agent for 3D printing concrete, and 12.5-14.5% of water, and the remainder is sand.

The present invention discloses a method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing, such as white paste, natural stones or clinker, including TiO.sub.2 as bio-additive, and product obtained by the micronized sandstone thereof. The ceramics and industrial wastes of ceramic are grinded in several steps and the resultant powders are collected by means of individual filters and further combined in a nanopowder micronizer for posterior treatment, where TiO.sub.2 hydrolyzed can be optionally added. This micronized sandstone comprising the bio-additive TiO.sub.2 is used in the production of plasters, mortars, grouts and/or as additive for paints and/or epoxy enriched with TiO.sub.2. The micronized sandstone bio-additive with TiO.sub.2 can be additionally subjected to two optional embodiments of the invention: treatment with or without the use of a pigment. In order to obtain the final product that can be used in the production of blocks, floors and other products of various sizes, an agglomerating agent combined with TiO.sub.2 is added to the micronized sandstone comprising the bio-additive TiO.sub.2, either in an aqueous solution or as a dry product, optionally including colored oxides.

The present invention discloses a method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing, such as white paste, natural stones or clinker, including TiO.sub.2 as bio-additive, and product obtained by the micronized sandstone thereof. The ceramics and industrial wastes of ceramic are grinded in several steps and the resultant powders are collected by means of individual filters and further combined in a nanopowder micronizer for posterior treatment, where TiO.sub.2 hydrolyzed can be optionally added. This micronized sandstone comprising the bio-additive TiO.sub.2 is used in the production of plasters, mortars, grouts and/or as additive for paints and/or epoxy enriched with TiO.sub.2. The micronized sandstone bio-additive with TiO.sub.2 can be additionally subjected to two optional embodiments of the invention: treatment with or without the use of a pigment. In order to obtain the final product that can be used in the production of blocks, floors and other products of various sizes, an agglomerating agent combined with TiO.sub.2 is added to the micronized sandstone comprising the bio-additive TiO.sub.2, either in an aqueous solution or as a dry product, optionally including colored oxides.

A process for preparing powdered dispersants comprising at least 90% by weight of at least one copolymer CP of the polycarboxylate ether type. The powdered dispersants can be easily dispersed in water. The invention also relates to the use of such powdered dispersants in mineral binder compositions, in particular dry mortars, concrete or gypsum formulations.