Polyamine additives are disclosed that are useful to provide early water resistant to drying anionically colloidally stabilized polymer dispersions in aqueous media. The polyamines are polymerization products from ethylenically unsaturated monomers with pendant tertiary amine groups with ethylenically unsaturated monomers with pendant poly(alkylene oxide) chains of 88 to 1200 g/mole molecular weight.

Polyamine additives are disclosed that are useful to provide early water resistant to drying anionically colloidally stabilized polymer dispersions in aqueous media. The polyamines are polymerization products from ethylenically unsaturated monomers with pendant tertiary amine groups with ethylenically unsaturated monomers with pendant poly(alkylene oxide) chains of 88 to 1200 g/mole molecular weight.

A coating composition includes: an aqueous dispersion of self-crosslinkable core-shell particles, where the corm-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups, where the polymeric core is covalently bonded to at least a portion of the polymeric shell, and a hydrophobic additive including a wax and/or a silicon-containing compound, where the hydrophobic additive is non-reactive with the polymeric core and the polymeric shell. A substrate coated with a coating formed from the coating composition and a method for improving stain resistance of a substrate are also disclosed.

A coating composition includes: an aqueous dispersion of self-crosslinkable core-shell particles, where the core-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups, where the polymeric core is covalently bonded to at least a portion of the polymeric shell, and a hydrophobic additive including a wax and/or a silicon-containing compound, where the hydrophobic additive is non-reactive with the polymeric core and the polymeric shell. A substrate coated with a coating formed from the coating composition and a method for improving stain resistance of a substrate are also disclosed.

A coating composition includes: an aqueous dispersion of self-crosslinkable core-shell particles, where the core-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups, where the polymeric core is covalently bonded to at least a portion of the polymeric shell, and a hydrophobic additive including a wax and/or a silicon-containing compound, where the hydrophobic additive is non-reactive with the polymeric core and the polymeric shell. A substrate coated with a coating formed from the coating composition and a method for improving stain resistance of a substrate are also disclosed.

Disclosed is a composite gypsum board comprising a board core and a concentrated layer, as well as related methods of preparing board and slurries. The board core and the concentrated layer both are formed from water and stucco. The concentrated layer is designed to have higher density and/or nail pull than the core. The concentrated layer is further formed from one or more of starch thickener, cellulose, and/or copolymer containing polyacrylamide and acrylic acid. In some embodiments, the concentrated layer is formed from an enhancing additive to enhance strength therein, while the core is formed without using enhancing additive or less enhancing additive than used in forming the board core.

Disclosed is a composite gypsum board comprising a board core and a concentrated layer, as well as related methods of preparing board and slurries. The board core and the concentrated layer both are formed from water and stucco. The concentrated layer is designed to have higher density and/or nail pull than the core. The concentrated layer is further formed from one or more of starch thickener, cellulose, and/or copolymer containing polyacrylamide and acrylic acid. In some embodiments, the concentrated layer is formed from an enhancing additive to enhance strength therein, while the core is formed without using enhancing additive or less enhancing additive than used in forming the board core.

A coating composition includes: an aqueous dispersion of self-crosslinkable core-shell particles, where the corm-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups, where the polymeric core is covalently bonded to at least a portion of the polymeric shell, and a hydrophobic additive including a wax and/or a silicon-containing compound, where the hydrophobic additive is non-reactive with the polymeric core and the polymeric shell. A substrate coated with a coating formed from the coating composition and a method for improving stain resistance of a substrate are also disclosed.

A method of coating a cementitious and/or masonry substrate includes applying an aqueous coating composition to the cementitious and/or masonry substrate. The aqueous coating composition includes at least one pigment, optionally at least one filler, at least one emulsified polymeric binder, at least one water-soluble silicate, and optionally at least one additive. The emulsified polymeric binder includes at least one of: a)(meth)acrylamide or derivative thereof as a polymerized monomer; or b) 1 weight % or more of at least one surfactant based on the total dry weight of the total monomer in the emulsified polymeric binder. The aqueous coating composition has a weight ratio of emulsified polymeric binder to the water-soluble silicate from 65:35 to 95:5 on a dry weight basis. The aqueous coating composition also has a pigment volume concentration (PVC) from 5% to 85.

An aqueous composition for coating cementitious or masonry substrates is provided. When dried, the coating composition has high gloss and low dirt pick-up. The composition includes at least one emulsified polymeric binder; at least one water-soluble silicate; at least one alkyl siliconate; at least one pigment, optionally at least one filler; optionally at least one paint additive; and water. The pigment volume concentration (PVC) of the aqueous composition is 40 weight % or less.