Disclosed are compositions and methods of making a liquid fertilizer additive solution of polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors comprising a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols. Fertilizer compositions are disclosed comprising of a) one or more polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors adducts from the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols b) a non-aqueous organo solvent delivery system (NOSDS), and c) one or more nitrogen sources.

Disclosed are compositions and methods of making a liquid fertilizer additive solution of polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors comprising a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols. Fertilizer compositions are disclosed comprising of a) one or more polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors adducts from the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols b) a non-aqueous organo solvent delivery system (NOSDS), and c) one or more nitrogen sources.

Disclosed herein are methods of increasing nitrogen fixation in a non-leguminous plant. The methods can comprise exposing the plant to a plurality of bacteria. Each member of the plurality comprises one or more genetic variations introduced into one or more genes or non-coding polynucleotides of the bacteria's nitrogen fixation or assimilation genetic regulatory network, such that the bacteria are capable of fixing atmospheric nitrogen in the presence of exogenous nitrogen. The bacteria are not intergeneric microorganisms. Additionally, the bacteria, in planta, produce 1% or more of the fixed nitrogen in the plant.

Disclosed herein are methods of increasing nitrogen fixation in a non-leguminous plant. The methods can comprise exposing the plant to a plurality of bacteria. Each member of the plurality comprises one or more genetic variations introduced into one or more genes or non-coding polynucleotides of the bacteria's nitrogen fixation or assimilation genetic regulatory network, such that the bacteria are capable of fixing atmospheric nitrogen in the presence of exogenous nitrogen. The bacteria are not intergeneric microorganisms. Additionally, the bacteria, in planta, produce 1% or more of the fixed nitrogen in the plant.

A stabilized ammonium humate mixture including an amount of humic acid between about 7.0% to about 10% of the mixture and an amount of ammonia between about 1.0% to about 14% of the mixture, where the remainder of the mixture is water.

A method of producing a fertiliser composition, the method comprising: •(a) providing partially decomposed organic matter; •(b) contacting the organic matter with: •(i) an anaerobic digestate; •(ii) a source of nitrate ion; •(iii) a source of ammonia; and •(c) contacting the mixture obtained in step (b) with a source of carbon dioxide. •Also claimed is a fertiliser composition comprising partially decomposed organic matter admixed with an anaerobic digestate, a source of nitrate ion, a source of ammonia and carbon dioxide.

According to some embodiments, there is provided herein a fertilizer granule comprising Polyhalite and Ammonium Sulphate, wherein said granule comprises a concentration of 40-60% w/w Polyhalite and 60-40% w/w of Ammonium Sulphate.

According to some embodiments, there is provided herein a fertilizer granule comprising Polyhalite and Ammonium Sulphate, wherein said granule comprises a concentration of 40-60% w/w Polyhalite and 60-40% w/w of Ammonium Sulphate.

The invention is directed to organic fertilizers having commercial levels of nitrogen reacted with organic substances. The scalable process comprises adding an organic processing center to a fertilizer granulation plant specifically for the treatment of organics with an acid that acidifies, heats and liquifies a mix resulting in the hydrolysis of most or all organic material and polymers. For ammonium sulfate-based fertilizer this mix is only reacted with concentrated sulfuric acid. For ammonium phosphate fertilizers, this mix is reacted with both concentrated sulfuric acid and a concentrated phosphoric acid. The acidified organic mixes are piped to an existing or new granulation plant where it is injected with anhydrous ammonia in a tee mixer/reactor that results in a partially neutralized melt. Subsequently a sterilized and liquefied organic melt is sprayed over recycled bed material for production of granules before drying. Fertilizers made as disclosed provide a “green”, dual nitrogen-release profile when applied to crops releasing a bolus of nitrogen over one to two weeks following application followed by a slow or enhanced efficiency release of nitrogen over weeks of the growing season.

Disclosed are compositions and methods of making a liquid fertilizer additive solution of polymeric and /or oligomeric heterocyclic nitrogen containing nitrification inhibitors comprising a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols. Fertilizer compositions are disclosed comprising of a) one or more polymeric and /or oligomeric heterocyclic nitrogen containing nitrification inhibitors adducts from the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols b) a non-aqueous organo solvent delivery system (NOSDS), and c) one or more nitrogen sources.