Disclosed are gas generating compositions and methods of making and used them.

This disclosure is directed to an airbag gas generant formulation optimized for hybrid airbag inflators, and an airbag inflator, an airbag, an airbag module comprising same, and a method of inflating an airbag using the airbag gas generant.

This disclosure is directed to an airbag gas generant formulation optimized for hybrid airbag inflators, and an airbag inflator, an airbag, an airbag module comprising same, and a method of inflating an airbag using the airbag gas generant.

The invention relates to gas generating compositions for use in safety devices for vehicles. In particular, the invention relates to said compositions based on guanidine nitrate used in pedestrian protection devices. The composition substantially comprises 75 to 98% by weight of guanidine nitrate as fuel and 2 to 25% by weight of a burn accelerator selected from the group of the transition metal compounds, the metal nitrates, metal chlorates, metal perchlorates, ammonium perchlorate and mixtures thereof, wherein the transition metal compounds are selected from the compounds of the transition metals Ti, Cr, Mn, Fe, Cu, Zn, Zr and Mo and wherein the gas generating composition exhibits a burn rate of from 3 to 17 mm/s at 20 MPa.

The invention relates to gas generating compositions for use in safety devices for vehicles. In particular, the invention relates to said compositions based on guanidine nitrate used in pedestrian protection devices. The composition substantially comprises 75 to 98% by weight of guanidine nitrate as fuel and 2 to 25% by weight of a burn accelerator selected from the group of the transition metal compounds, the metal nitrates, metal chlorates, metal perchlorates, ammonium perchlorate and mixtures thereof, wherein the transition metal compounds are selected from the compounds of the transition metals Ti, Cr, Mn, Fe, Cu, Zn, Zr and Mo and wherein the gas generating composition exhibits a burn rate of from 3 to 17 mm/s at 20 MPa.

A priming mix composition includes between about 30% and about 60% of at least one of KDNBF, dinol, and tetrazene as a primary explosive; between about 10% and about 35% of a metallocene as a propagation aid; between about 5% and about 40% of at least one nitrate, peroxide, or oxide, as an oxidizer; between about 5% and about 25% of at least one of nitrocellulose or PETN as a reactive fuel; and a fuel. The metallocene is preferable ferrocene.

A priming mix composition includes between about 30% and about 60% of at least one of KDNBF, dinol, and tetrazene as a primary explosive; between about 10% and about 35% of a metallocene as a propagation aid; between about 5% and about 40% of at least one nitrate, peroxide, or oxide, as an oxidizer; between about 5% and about 25% of at least one of nitrocellulose or PETN as a reactive fuel; and a fuel. The metallocene is preferable ferrocene.