Patent classifications
C07C1/22
PROCESS FOR PREPARING A MOLDING COMPRISING A ZEOLITE CATALYST AND METHOD FOR CONVERTING OXYGENATES TO OLEFINS USING THE CATALYTIC MOLDING
The present invention relates to a process for preparing a molding comprising a zeolitic material and one or more oxidic binders, the process particularly comprising preparing a mixture of a zeolitic material, such as Mg-ZSM-5, a source of an oxidic binder, and a first plasticizer; admixing an acid to said mixture; and shaping of the mixture, to obtain a precursor of a molding; wherein in said mixture a specific weight ratio of the source of the oxidic binder to the sum of the zeolitic material and the source of the oxidic binder is applied. Further, the present invention relates to a molding obtainable or obtained by the inventive process, and to a molding itself displaying in particular a comparatively improved crush strength. Yet further, the present invention relates to a method for the conversion of oxygenates to olefins and to a use of the inventive molding.
PROCESS FOR PREPARING A MOLDING COMPRISING A ZEOLITE CATALYST AND METHOD FOR CONVERTING OXYGENATES TO OLEFINS USING THE CATALYTIC MOLDING
The present invention relates to a process for preparing a molding comprising a zeolitic material and one or more oxidic binders, the process particularly comprising preparing a mixture of a zeolitic material, such as Mg-ZSM-5, a source of an oxidic binder, and a first plasticizer; admixing an acid to said mixture; and shaping of the mixture, to obtain a precursor of a molding; wherein in said mixture a specific weight ratio of the source of the oxidic binder to the sum of the zeolitic material and the source of the oxidic binder is applied. Further, the present invention relates to a molding obtainable or obtained by the inventive process, and to a molding itself displaying in particular a comparatively improved crush strength. Yet further, the present invention relates to a method for the conversion of oxygenates to olefins and to a use of the inventive molding.
PRODUCTION OF HYDROCARBON LIQUIDS
A process to efficiently convert organic feedstock material into liquid non-oxygenated hydrocarbons in the C.sub.5 to C.sub.12 carbon skeleton range is disclosed. The process can utilize gaseous, liquid or solid organic feedstocks containing carbon, hydrogen and, optionally, oxygen. The feedstock may require preparation of the organic feedstock for the process and is converted first into a synthesis gas containing carbon monoxide and hydrogen. The synthesis gas is then cleaned and conditioned and extraneous components removed, leaving substantially only the carbon monoxide and hydrogen. It is then converted via a series of chemical reactions into the desired liquid hydrocarbons. The hydrocarbons are suitable for combustion in a vehicle engine and may be regarded a replacement for petrol made from fossil fuels in the C.sub.5 to C.sub.2 carbon backbone range. The process also recycles gaseous by-products back through the various reactors of the process to maximize the liquid hydrocarbon in the C.sub.5 to C.sub.12 carbon skeleton range yield.
PRODUCTION OF HYDROCARBON LIQUIDS
A process to efficiently convert organic feedstock material into liquid non-oxygenated hydrocarbons in the C.sub.5 to C.sub.12 carbon skeleton range is disclosed. The process can utilize gaseous, liquid or solid organic feedstocks containing carbon, hydrogen and, optionally, oxygen. The feedstock may require preparation of the organic feedstock for the process and is converted first into a synthesis gas containing carbon monoxide and hydrogen. The synthesis gas is then cleaned and conditioned and extraneous components removed, leaving substantially only the carbon monoxide and hydrogen. It is then converted via a series of chemical reactions into the desired liquid hydrocarbons. The hydrocarbons are suitable for combustion in a vehicle engine and may be regarded a replacement for petrol made from fossil fuels in the C.sub.5 to C.sub.2 carbon backbone range. The process also recycles gaseous by-products back through the various reactors of the process to maximize the liquid hydrocarbon in the C.sub.5 to C.sub.12 carbon skeleton range yield.
PROCESS FOR PRODUCING COMPOUNDS, INCLUDING TRIPTANE BY AN ALCOHOL COUPLING REACTION
The present invention relates to a method for the production of molecules with seven carbons constituted by a chain of four carbons with three methyl branches, primarily triptane (2,2,3-trimethylbutane), by alcohol coupling reaction (Guerbet reaction), resulting in an alcohol with a four-carbon chain with three methyl branches, which is transformed into triptane. The importance of this method stems from the fact that triptane is the hydrocarbon with the greatest capacity to resist compression without ignition and can be used in unleaded aviation gasolines and in the formulation of high-octane automotive gasolines.
PROCESS FOR PRODUCING COMPOUNDS, INCLUDING TRIPTANE BY AN ALCOHOL COUPLING REACTION
The present invention relates to a method for the production of molecules with seven carbons constituted by a chain of four carbons with three methyl branches, primarily triptane (2,2,3-trimethylbutane), by alcohol coupling reaction (Guerbet reaction), resulting in an alcohol with a four-carbon chain with three methyl branches, which is transformed into triptane. The importance of this method stems from the fact that triptane is the hydrocarbon with the greatest capacity to resist compression without ignition and can be used in unleaded aviation gasolines and in the formulation of high-octane automotive gasolines.
FLUIDIZED BED REACTOR, DEVICE, AND USE THEREOF
A fluidized bed reactor includes a main shell and a coke control zone shell; the main shell includes an upper shell and a lower shell; the upper shell encloses a gas-solid separation zone, and the lower shell encloses a reaction zone; the reaction zone axially communicates with the gas-solid separation zone; the coke control zone shell is circumferentially arranged on an outer wall of the main shell; the coke control zone shell and the main shell enclose an annular cavity, and the annular cavity is a coke control zone; n baffles are radially arranged in the coke control zone, and the n baffles divide the coke control zone into n coke control zone subzones, where n is an integer; the coke control zone subzones are provided with a coke control raw material inlet; and a catalyst circulation hole is formed in each of n-1 of the baffles.
FLUIDIZED BED REACTOR, DEVICE, AND USE THEREOF
A fluidized bed reactor includes a main shell and a coke control zone shell; the main shell includes an upper shell and a lower shell; the upper shell encloses a gas-solid separation zone, and the lower shell encloses a reaction zone; the reaction zone axially communicates with the gas-solid separation zone; the coke control zone shell is circumferentially arranged on an outer wall of the main shell; the coke control zone shell and the main shell enclose an annular cavity, and the annular cavity is a coke control zone; n baffles are radially arranged in the coke control zone, and the n baffles divide the coke control zone into n coke control zone subzones, where n is an integer; the coke control zone subzones are provided with a coke control raw material inlet; and a catalyst circulation hole is formed in each of n-1 of the baffles.
COKE CONTROL REACTOR, AND DEVICE AND METHOD FOR PREPARING LOW-CARBON OLEFINS FROM OXYGEN-CONTAINING COMPOUND
A coke control reactor, and a device and method for preparing low-carbon olefins from an oxygen-containing compound are provided. The coke control reactor includes a coke control reactor shell, a reaction zone I, and a coke controlled catalyst settling zone; a cross-sectional area at any position of the reaction zone I is less than that of the coke controlled catalyst settling zone; n baffles are arranged in a vertical direction in the reaction zone I; the n baffles divide the reaction zone I into m reaction zone I subzones; and a catalyst circulation hole is formed in each of the baffles, such that a catalyst flows in the reaction zone I in a preset manner. A catalyst charge in the present coke control reactor can be automatically adjusted, and an average residence time of a catalyst in the coke control reactor can be controlled by changing process operating conditions.
COKE CONTROL REACTOR, AND DEVICE AND METHOD FOR PREPARING LOW-CARBON OLEFINS FROM OXYGEN-CONTAINING COMPOUND
A coke control reactor, and a device and method for preparing low-carbon olefins from an oxygen-containing compound are provided. The coke control reactor includes a coke control reactor shell, a reaction zone I, and a coke controlled catalyst settling zone; a cross-sectional area at any position of the reaction zone I is less than that of the coke controlled catalyst settling zone; n baffles are arranged in a vertical direction in the reaction zone I; the n baffles divide the reaction zone I into m reaction zone I subzones; and a catalyst circulation hole is formed in each of the baffles, such that a catalyst flows in the reaction zone I in a preset manner. A catalyst charge in the present coke control reactor can be automatically adjusted, and an average residence time of a catalyst in the coke control reactor can be controlled by changing process operating conditions.