C07C11/04

CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE AND LUBRICATING OIL VIA CRUDE AND ISOMERIZATION DEWAXING UNITS
20230048572 · 2023-02-16 · ·

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE AND LUBRICATING OIL VIA CRUDE AND ISOMERIZATION DEWAXING UNITS
20230048572 · 2023-02-16 · ·

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

Olefin production via dry reforming and olefin synthesis in a vessel

A system and method for producing olefin via dry reforming and olefin synthesis in the same vessel, including providing feed including methane and carbon dioxide to the vessel, converting methane and carbon dioxide in the vessel into syngas (that includes hydrogen and carbon monoxide) via dry reforming in the vessel, and cooling the syngas via a heat exchanger in the vessel. The method includes synthesizing olefin from the syngas in the vessel, wherein the olefin includes ethylene, propylene, or butene, or any combinations thereof.

Olefin production via dry reforming and olefin synthesis in a vessel

A system and method for producing olefin via dry reforming and olefin synthesis in the same vessel, including providing feed including methane and carbon dioxide to the vessel, converting methane and carbon dioxide in the vessel into syngas (that includes hydrogen and carbon monoxide) via dry reforming in the vessel, and cooling the syngas via a heat exchanger in the vessel. The method includes synthesizing olefin from the syngas in the vessel, wherein the olefin includes ethylene, propylene, or butene, or any combinations thereof.

Electrically heated dehydrogenation process

Systems and processes for dehydrogenating one or more alkanes using electrically heated dehydrogenation reactors. The source of electric energy or power can be a power grid, solar panel, windmill, hydropower, nuclear power, fuel cell, gas turbines, steam turbines, portable generator or the like. The systems and processes provided herein result in a simpler dehydrogenation process which is particularly beneficial at a small scale and at remote locations, including the well site.

Electrically heated dehydrogenation process

Systems and processes for dehydrogenating one or more alkanes using electrically heated dehydrogenation reactors. The source of electric energy or power can be a power grid, solar panel, windmill, hydropower, nuclear power, fuel cell, gas turbines, steam turbines, portable generator or the like. The systems and processes provided herein result in a simpler dehydrogenation process which is particularly beneficial at a small scale and at remote locations, including the well site.

A CATALYST FOR PRODUCING LIGHT OLEFINS FROM CATALYTIC CRACKING OF HYDROCARBON HAVING 4 TO 7 CARBON ATOMS AND A PROCESS FOR PRODUCING LIGHT OLEFINS BY USING A CATALYST THEREOF

The present invention relates to a catalyst for producing light olefins from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms, wherein said catalyst comprises zeolite having the ring arrangement of 8 to 10 silicon atoms and hierarchical zeolite comprising 0.1 to 2 nm of micropore, 2 to 50 nm of mesopore, and greater than 50 nm of macropore, wherein the mesopore and macropore are greater than or equal to 40% when comparing to total pore volume, and said catalyst comprises element having 2.sup.+ to 4.sup.+ oxidation state with 0.1 to 3% by weight of the catalyst.

A CATALYST FOR PRODUCING LIGHT OLEFINS FROM CATALYTIC CRACKING OF HYDROCARBON HAVING 4 TO 7 CARBON ATOMS AND A PROCESS FOR PRODUCING LIGHT OLEFINS BY USING A CATALYST THEREOF

The present invention relates to a catalyst for producing light olefins from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms, wherein said catalyst comprises zeolite having the ring arrangement of 8 to 10 silicon atoms and hierarchical zeolite comprising 0.1 to 2 nm of micropore, 2 to 50 nm of mesopore, and greater than 50 nm of macropore, wherein the mesopore and macropore are greater than or equal to 40% when comparing to total pore volume, and said catalyst comprises element having 2.sup.+ to 4.sup.+ oxidation state with 0.1 to 3% by weight of the catalyst.

METHOD AND APPARATUS FOR CONVERTING HYDROCARBON-BASED MATERIAL INTO ACETYLENE OR ETHYLENE

A method of converting a hydrocarbon-based material into acetylene or ethylene according to an embodiment of the present invention includes a supply step of supplying a gaseous or liquid hydrocarbon-based material to a plasma reactor, and a temperature control step of creating a temperature condition of a decomposition reaction of converting the hydrocarbon-based material into acetylene or ethylene in a reaction space in the plasma reactor.

METHOD AND APPARATUS FOR CONVERTING HYDROCARBON-BASED MATERIAL INTO ACETYLENE OR ETHYLENE

A method of converting a hydrocarbon-based material into acetylene or ethylene according to an embodiment of the present invention includes a supply step of supplying a gaseous or liquid hydrocarbon-based material to a plasma reactor, and a temperature control step of creating a temperature condition of a decomposition reaction of converting the hydrocarbon-based material into acetylene or ethylene in a reaction space in the plasma reactor.