Patent classifications
C07C11/20
Hydrocarbon production method and production apparatus
A hydrocarbon production method for producing hydrocarbons from a hydrocarbon mixture includes: a first extractive distillation step of performing extractive distillation of an extractive distillation target to obtain a fraction (A) in which isoprene and piperylene are enriched and a fraction (B) in which a linear hydrocarbon and a branched hydrocarbon are enriched; a first distillation step of obtaining a fraction (C) in which isoprene is enriched and a fraction (D) in which piperylene is enriched from the fraction (A); a dehydrogenation step of performing dehydrogenation or oxidative dehydrogenation of either or both of the linear hydrocarbon and the branched hydrocarbon contained in the fraction (B) to obtain a dehydrogenated product; and a recovery step of supplying the dehydrogenated product to an extractive distillation column or a distillation column and obtaining isoprene and/or piperylene from the dehydrogenated product.
Hydrocarbon production method and production apparatus
A hydrocarbon production method for producing hydrocarbons from a hydrocarbon mixture includes: a first extractive distillation step of performing extractive distillation of an extractive distillation target to obtain a fraction (A) in which isoprene and piperylene are enriched and a fraction (B) in which a linear hydrocarbon and a branched hydrocarbon are enriched; a first distillation step of obtaining a fraction (C) in which isoprene is enriched and a fraction (D) in which piperylene is enriched from the fraction (A); a dehydrogenation step of performing dehydrogenation or oxidative dehydrogenation of either or both of the linear hydrocarbon and the branched hydrocarbon contained in the fraction (B) to obtain a dehydrogenated product; and a recovery step of supplying the dehydrogenated product to an extractive distillation column or a distillation column and obtaining isoprene and/or piperylene from the dehydrogenated product.
METHOD OF PRODUCING PIPERYLENE
Provided is a method of producing piperylene from a hydrocarbon mixture derived from a petroleum fraction having a carbon number of 5. The hydrocarbon mixture has a piperylene proportional content of not less than 60 mass % and not more than 80 mass % and has a cyclic hydrocarbon proportional content of not less than 20 mass % and not more than 40 mass %. The method of producing piperylene includes a membrane separation step of performing membrane separation of the hydrocarbon mixture using a zeolite membrane to obtain a separated product in which piperylene is enriched.
METHOD OF PRODUCING PIPERYLENE
Provided is a method of producing piperylene from a hydrocarbon mixture derived from a petroleum fraction having a carbon number of 5. The hydrocarbon mixture has a piperylene proportional content of not less than 60 mass % and not more than 80 mass % and has a cyclic hydrocarbon proportional content of not less than 20 mass % and not more than 40 mass %. The method of producing piperylene includes a membrane separation step of performing membrane separation of the hydrocarbon mixture using a zeolite membrane to obtain a separated product in which piperylene is enriched.
PROCESSES FOR CONVERTING NAPHTHA TO DISTILLATE PRODUCTS
The present disclosure provides processes to convert heavy hydrocarbons to light distillates. The present disclosure further provides compositions including light distillates. In an embodiment, a process for upgrading a hydrocarbon feed includes dehydrogenating a C.sub.3-C.sub.50 cyclic alkane and an C.sub.2-C.sub.50 acyclic alkane in the presence of a dehydrogenation catalyst to form a C.sub.3-C.sub.50 cyclic olefin and a C.sub.2-C.sub.50 acyclic olefin. The process includes reacting the C.sub.3-C.sub.50 cyclic olefin and the C.sub.2-C.sub.50 acyclic olefin in the presence of a group 6 or group 8 transition metal catalysts to form a C.sub.5-C.sub.200 olefin. The process further includes hydrogenating the C.sub.5-C.sub.200 olefin in the presence of a hydrogenation catalyst to form a C.sub.5-C.sub.200 hydrogenated product. Processes of the present disclosure may further include hydroisomerizing the C.sub.5-C.sub.200 hydrogenated product in the presence of a hydroisomerization catalyst to form a C.sub.5-C.sub.200 hydroisomerized product.
PROCESSES FOR CONVERTING NAPHTHA TO DISTILLATE PRODUCTS
The present disclosure provides processes to convert heavy hydrocarbons to light distillates. The present disclosure further provides compositions including light distillates. In an embodiment, a process for upgrading a hydrocarbon feed includes dehydrogenating a C.sub.3-C.sub.50 cyclic alkane and an C.sub.2-C.sub.50 acyclic alkane in the presence of a dehydrogenation catalyst to form a C.sub.3-C.sub.50 cyclic olefin and a C.sub.2-C.sub.50 acyclic olefin. The process includes reacting the C.sub.3-C.sub.50 cyclic olefin and the C.sub.2-C.sub.50 acyclic olefin in the presence of a group 6 or group 8 transition metal catalysts to form a C.sub.5-C.sub.200 olefin. The process further includes hydrogenating the C.sub.5-C.sub.200 olefin in the presence of a hydrogenation catalyst to form a C.sub.5-C.sub.200 hydrogenated product. Processes of the present disclosure may further include hydroisomerizing the C.sub.5-C.sub.200 hydrogenated product in the presence of a hydroisomerization catalyst to form a C.sub.5-C.sub.200 hydroisomerized product.
Method of producing piperylene
Provided is a method of producing piperylene from a hydrocarbon mixture derived from a petroleum fraction having a carbon number of 5. The hydrocarbon mixture has a piperylene proportional content of not less than 60 mass % and not more than 80 mass % and has a cyclic hydrocarbon proportional content of not less than 20 mass % and not more than 40 mass %. The method of producing piperylene includes a membrane separation step of performing membrane separation of the hydrocarbon mixture using a zeolite membrane to obtain a separated product in which piperylene is enriched.
Method of producing piperylene
Provided is a method of producing piperylene from a hydrocarbon mixture derived from a petroleum fraction having a carbon number of 5. The hydrocarbon mixture has a piperylene proportional content of not less than 60 mass % and not more than 80 mass % and has a cyclic hydrocarbon proportional content of not less than 20 mass % and not more than 40 mass %. The method of producing piperylene includes a membrane separation step of performing membrane separation of the hydrocarbon mixture using a zeolite membrane to obtain a separated product in which piperylene is enriched.
HYDROCARBON PRODUCTION METHOD AND PRODUCTION APPARATUS
A hydrocarbon production method for producing hydrocarbons from a hydrocarbon mixture includes: a first extractive distillation step of performing extractive distillation of an extractive distillation target to obtain a fraction (A) in which isoprene and piperylene are enriched and a fraction (B) in which a linear hydrocarbon and a branched hydrocarbon are enriched; a first distillation step of obtaining a fraction (C) in which isoprene is enriched and a fraction (D) in which piperylene is enriched from the fraction (A); a dehydrogenation step of performing dehydrogenation or oxidative dehydrogenation of either or both of the linear hydrocarbon and the branched hydrocarbon contained in the fraction (B) to obtain a dehydrogenated product; and a recovery step of supplying the dehydrogenated product to an extractive distillation column or a distillation column and obtaining isoprene and/or piperylene from the dehydrogenated product.
HYDROCARBON PRODUCTION METHOD AND PRODUCTION APPARATUS
A hydrocarbon production method for producing hydrocarbons from a hydrocarbon mixture includes: a first extractive distillation step of performing extractive distillation of an extractive distillation target to obtain a fraction (A) in which isoprene and piperylene are enriched and a fraction (B) in which a linear hydrocarbon and a branched hydrocarbon are enriched; a first distillation step of obtaining a fraction (C) in which isoprene is enriched and a fraction (D) in which piperylene is enriched from the fraction (A); a dehydrogenation step of performing dehydrogenation or oxidative dehydrogenation of either or both of the linear hydrocarbon and the branched hydrocarbon contained in the fraction (B) to obtain a dehydrogenated product; and a recovery step of supplying the dehydrogenated product to an extractive distillation column or a distillation column and obtaining isoprene and/or piperylene from the dehydrogenated product.