Patent classifications
C07C17/2635
1-haloalkadiene and a process for preparing the same and a process for preparing (9e, 11z)-9,11-hexadecadienyl acetate
A process to prepare (9E,11Z)-9,11-hexadecadienyl acetate with a good yield and high purity of the general formula (1): CH.sub.3(CH.sub.2).sub.3CHCHCHCH(CH.sub.2).sub.aX.=The process includes a step of conducting a Wittig reaction between a haloalkenal of the general formula (2): OHCCHCH(CH.sub.2).sub.aX, and a triarylphosphonium pentylide of the general formula (3): CH.sub.3(CH.sub.2).sub.3CH.sup.P.sup.+Ar.sub.3, to obtain the 1-haloalkadiene, and the use of a (7E,9Z)-1-halo-7,9-tetradecadiene obtained by the process for a process of preparing (9E, 11Z)-9,11-hexadecadienyl acetate.
1-haloalkadiene and a process for preparing the same and a process for preparing (9e, 11z)-9,11-hexadecadienyl acetate
A process to prepare (9E,11Z)-9,11-hexadecadienyl acetate with a good yield and high purity of the general formula (1): CH.sub.3(CH.sub.2).sub.3CHCHCHCH(CH.sub.2).sub.aX.=The process includes a step of conducting a Wittig reaction between a haloalkenal of the general formula (2): OHCCHCH(CH.sub.2).sub.aX, and a triarylphosphonium pentylide of the general formula (3): CH.sub.3(CH.sub.2).sub.3CH.sup.P.sup.+Ar.sub.3, to obtain the 1-haloalkadiene, and the use of a (7E,9Z)-1-halo-7,9-tetradecadiene obtained by the process for a process of preparing (9E, 11Z)-9,11-hexadecadienyl acetate.
Oxy-cope rearrangement for the manufacture of insecticidal cyclopentene compounds
Compounds of formula I ##STR00001##
a process for preparation of compounds of formula I; precursor compounds of formula II ##STR00002##
a process for preparation of precursor compounds of formula II; compounds of formula III ##STR00003##
a process for the preparation of compounds of formula IV from compounds of formula III ##STR00004##
and the use of compounds of formula I for the preparation of compounds of formula IV.
Oxy-cope rearrangement for the manufacture of insecticidal cyclopentene compounds
Compounds of formula I ##STR00001##
a process for preparation of compounds of formula I; precursor compounds of formula II ##STR00002##
a process for preparation of precursor compounds of formula II; compounds of formula III ##STR00003##
a process for the preparation of compounds of formula IV from compounds of formula III ##STR00004##
and the use of compounds of formula I for the preparation of compounds of formula IV.
CARBON NANOBELT AND PRODUCTION METHOD THEREFOR
A carbon nanobelt represented by formula (1) was synthesized by chemical synthesis:
wherein each Ar is identical or different and represents an aromatic hydrocarbon ring; each R.sup.1 is identical or different and represents hydrogen, alkyl, aryl, or alkoxy; and n represents an integer of 0 or more.
CARBON NANOBELT AND PRODUCTION METHOD THEREFOR
A carbon nanobelt represented by formula (1) was synthesized by chemical synthesis:
wherein each Ar is identical or different and represents an aromatic hydrocarbon ring; each R.sup.1 is identical or different and represents hydrogen, alkyl, aryl, or alkoxy; and n represents an integer of 0 or more.
1-HALOALKADIENE AND A PROCESS FOR PREPARING THE SAME AND A PROCESS FOR PREPARING (9e, 11z)-9,11-HEXADECADIENYL ACETATE
A process to prepare (9E,11Z)-9,11-hexadecadienyl acetate with a good yield and high purity of the general formula (1): CH.sub.3(CH.sub.2).sub.3CHCHCHCH(CH.sub.2).sub.aX.=The process includes a step of conducting a Wittig reaction between a haloalkenal of the general formula (2): OHCCHCH(CH.sub.2).sub.aX, and a triarylphosphonium pentylide of the general formula (3): CH.sub.3(CH.sub.2).sub.3CH.sup.P.sup.+Ar.sub.3, to obtain the 1-haloalkadiene, and the use of a (7E,9Z)-1-halo-7,9-tetradecadiene obtained by the process for a process of preparing (9E, 11Z)-9,11-hexadecadienyl acetate.
1-HALOALKADIENE AND A PROCESS FOR PREPARING THE SAME AND A PROCESS FOR PREPARING (9e, 11z)-9,11-HEXADECADIENYL ACETATE
A process to prepare (9E,11Z)-9,11-hexadecadienyl acetate with a good yield and high purity of the general formula (1): CH.sub.3(CH.sub.2).sub.3CHCHCHCH(CH.sub.2).sub.aX.=The process includes a step of conducting a Wittig reaction between a haloalkenal of the general formula (2): OHCCHCH(CH.sub.2).sub.aX, and a triarylphosphonium pentylide of the general formula (3): CH.sub.3(CH.sub.2).sub.3CH.sup.P.sup.+Ar.sub.3, to obtain the 1-haloalkadiene, and the use of a (7E,9Z)-1-halo-7,9-tetradecadiene obtained by the process for a process of preparing (9E, 11Z)-9,11-hexadecadienyl acetate.
OXY-COPE REARRANGEMENT FOR THE MANUFACTURE OF INSECTICIDAL CYCLOPENTENE COMPOUNDS
Compounds of formula I
##STR00001##
a process for preparation of compounds of formula I; precursor compounds of formula II
##STR00002##
a process for preparation of precursor compounds of formula II; compounds of formula III
##STR00003##
a process for the preparation of compounds of formula IV from compounds of formula III
##STR00004##
and the use of compounds of formula I for the preparation of compounds of formula IV.
OXY-COPE REARRANGEMENT FOR THE MANUFACTURE OF INSECTICIDAL CYCLOPENTENE COMPOUNDS
Compounds of formula I
##STR00001##
a process for preparation of compounds of formula I; precursor compounds of formula II
##STR00002##
a process for preparation of precursor compounds of formula II; compounds of formula III
##STR00003##
a process for the preparation of compounds of formula IV from compounds of formula III
##STR00004##
and the use of compounds of formula I for the preparation of compounds of formula IV.