The invention relates to bis(aniline) compounds containing multiple arylethynyl, alkylethynyl, ethynyl groups or their combinations, processes of making such compounds and materials comprising such compounds. Such, bis(aniline) compounds preferably comprise multiple phenylethynyl (PE) groups, i.e. 2-4 PE moieties. Such compounds are useful monomers for the preparation of polyimides, polyamides and poly(amide-imides) whose post-fabrication crosslinking chemistry (i.e. reaction temperature) can be controlled by the number of PE per repeat unit as well as finding utility in thermosetting matrix resins, 3D printable resins, and as high-carbon-content precursors to carbon-carbon composites.

The invention relates to bis(aniline) compounds containing multiple arylethynyl, alkylethynyl, ethynyl groups or their combinations, processes of making such compounds and materials comprising such compounds. Such, bis(aniline) compounds preferably comprise multiple phenylethynyl (PE) groups, i.e. 2-4 PE moieties. Such compounds are useful monomers for the preparation of polyimides, polyamides and poly(amide-imides) whose post-fabrication crosslinking chemistry (i.e. reaction temperature) can be controlled by the number of PE per repeat unit as well as finding utility in thermosetting matrix resins, 3D printable resins, and as high-carbon-content precursors to carbon-carbon composites.

Provided is a polymer flocculant which is capable of controlling the structure of a polymer that is a copolymerization product of a monomer (a) having a structure derived from formula (I) in each molecule and a water-soluble unsaturated monomer (b) having a polymerizable unsaturated bond in each molecule, and which has a branched or cross-linking structure, and is excellent in water-solubility and water dispersibility, ##STR00001## In formula (I), R.sub.1 and R.sub.2 are respectively a linear or branched functional group configured of atoms selected from the group consisting of carbon not having a carbon-carbon unsaturated bond, oxygen, nitrogen, and hydrogen; W is a non-metal element of the group 15; X and Y are each a linear or branched functional group configured of atoms selected from the group consisting of carbon, oxygen, nitrogen, and hydrogen, and each have at least one carbon-carbon unsaturated bond, provided that X and Y have different structures; and Z is a chlorine ion, a bromine ion, or an iodine ion.

Provided is a polymer flocculant which is capable of controlling the structure of a polymer that is a copolymerization product of a monomer (a) having a structure derived from formula (I) in each molecule and a water-soluble unsaturated monomer (b) having a polymerizable unsaturated bond in each molecule, and which has a branched or cross-linking structure, and is excellent in water-solubility and water dispersibility, ##STR00001## In formula (I), R.sub.1 and R.sub.2 are respectively a linear or branched functional group configured of atoms selected from the group consisting of carbon not having a carbon-carbon unsaturated bond, oxygen, nitrogen, and hydrogen; W is a non-metal element of the group 15; X and Y are each a linear or branched functional group configured of atoms selected from the group consisting of carbon, oxygen, nitrogen, and hydrogen, and each have at least one carbon-carbon unsaturated bond, provided that X and Y have different structures; and Z is a chlorine ion, a bromine ion, or an iodine ion.

The present disclosure provides for alkyl-aryl amine-rich small molecules that are prepared by nucleophilic substitution from tri- and hexa-bromine-substituted aromatic cores with various aliphatic diamines. The resulting products can be subsequently subjected by solution impregnation into solid mesoporous supports. Various types of alkyl-aryl amine-rich small molecules can fill the support's pores up to ˜90% and displayed good thermal stability

The present disclosure provides for alkyl-aryl amine-rich small molecules that are prepared by nucleophilic substitution from tri- and hexa-bromine-substituted aromatic cores with various aliphatic diamines. The resulting products can be subsequently subjected by solution impregnation into solid mesoporous supports. Various types of alkyl-aryl amine-rich small molecules can fill the support's pores up to ˜90% and displayed good thermal stability

A compound is represented by general formula (1). In general formula (1), R.sup.1 and R.sup.2 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R.sup.1 and the number of carbon atoms of the chemical group represented by R.sup.2 is 2. R.sup.3 and R.sup.4 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R.sup.3 and the number of carbon atoms of the chemical group represented by R.sup.1 is 2. A photosensitive layer of an electrophotographic photosensitive member contains at least a charge generating material, a hole transport material, and a binder resin. The hole transport material includes a compound represented by general formula (1) ##STR00001##

A compound is represented by general formula (1). In general formula (1), R.sup.1 and R.sup.2 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R.sup.1 and the number of carbon atoms of the chemical group represented by R.sup.2 is 2. R.sup.3 and R.sup.4 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R.sup.3 and the number of carbon atoms of the chemical group represented by R.sup.1 is 2. A photosensitive layer of an electrophotographic photosensitive member contains at least a charge generating material, a hole transport material, and a binder resin. The hole transport material includes a compound represented by general formula (1) ##STR00001##

Compositions of oligoanilines with higher purity, methods of making and using thereof, are provided. The compositions are produced in large scale with larger yield using simple purification techniques such as washing. Methods have been developed that allow large scale synthesis of oligoaniline compounds with the following benefits: (i) higher purity; (ii) larger yield of oligoaniline compounds; (iii) simple purification that does not require complicated techniques such as liquid chromatograph; (iv) lower cost; and (v) full characterization. The highly pure oligoaniline compositions can be used as reducing or oxidizing agent in a redox reaction. The oligoaniline compositions have colors and can be used as dyes, i.e. redox active dyes in a redox reaction, as intermediates for the development of conductive elastomers, or as catalysts.

Compositions of oligoanilines with higher purity, methods of making and using thereof, are provided. The compositions are produced in large scale with larger yield using simple purification techniques such as washing. Methods have been developed that allow large scale synthesis of oligoaniline compounds with the following benefits: (i) higher purity; (ii) larger yield of oligoaniline compounds; (iii) simple purification that does not require complicated techniques such as liquid chromatograph; (iv) lower cost; and (v) full characterization. The highly pure oligoaniline compositions can be used as reducing or oxidizing agent in a redox reaction. The oligoaniline compositions have colors and can be used as dyes, i.e. redox active dyes in a redox reaction, as intermediates for the development of conductive elastomers, or as catalysts.