Patent classifications
C07C2527/187
Aromatization catalyst, preparation method, regeneration method thereof, and aromatization method
The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.
Oxygen transfer agent conditioning systems and methods
Improvements in the commercial viability of oxygen transfer agents (OTAs) and/or catalysts associated with the OCM and the ODH of hydrocarbons to olefins through enhancement of one or more of the selectivity, yield, rate and lifetime of the OTA and/or catalyst is described by one or more of (i) exposing the OTA or the catalyst to a sulfur-containing compound at a site or at a time that is different from where and when the saturated hydrocarbon is converted by the OTA or the catalyst to an unsaturated hydrocarbon; (ii) increasing the particle density of the OTA or the catalyst by treating the OTA or the catalyst with a reducing agent at a site different from where the saturated hydrocarbon is converted by the OTA or by the catalyst to an unsaturated hydrocarbon; and (iii) removing non-selective redox oxygen (NSRO) present on the OTA by subjecting the OTA to a gas that is substantially free of any molecular oxygen.
AROMATIZATION CATALYST, PREPARATION METHOD, REGENERATION METHOD THEREOF, AND AROMATIZATION METHOD
The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.
Production of products from natural resources
The method disclosed herein relates to two stage catalytic processes for converting syngas to acetic acid, acrylic acid and/or propylene. More specifically, the method described and claimed herein relate to a method of producing acrylic acid and acetic acid comprising the steps of: a) providing a feedstream comprising syngas; b) contacting the feedstream with a first catalyst to produce a first product stream comprising C.sub.2-C.sub.3 olefins and/or C.sub.2-C.sub.3 paraffins; and c) contacting the first product stream with oxygen gas and a second catalyst, thereby producing a second product stream comprising acrylic acid and acetic acid, wherein there is no step for separating the components of the first product stream before the first product stream is contacted with the second catalyst.
Catalyst and process for selective production of lower hydrocarbons C1—C5 from syngas with low methane and CO2 production
A catalyst composition containing cobalt manganese oxide which is modified with silicon in the form of a hydrophilic silica, the catalyst also containing at least one of lanthanum, phosphorus, Fe, Zr, and Zn, and optionally one or more basic elements selected from the group of alkali metal, alkaline earth metal, and transition metals. Also, methods for preparing and using the catalyst composition for producing aliphatic and aromatic hydrocarbons using the catalyst composition.
PRODUCTION OF PRODUCTS FROM NATURAL RESOURCES
The method disclosed herein relates to two stage catalytic processes for converting syngas to acetic acid, acrylic acid and/or propylene. More specifically, the method described and claimed herein relate to a method of producing acrylic acid and acetic acid comprising the steps of: a) providing a feedstream comprising syngas; b) contacting the feedstream with a first catalyst to produce a first product stream comprising C.sub.2-C.sub.3 olefins and/or C.sub.2-C.sub.3 paraffins; and c) contacting the first product stream with oxygen gas and a second catalyst, thereby producing a second product stream comprising acrylic acid and acetic acid, wherein there is no step for separating the components of the first product stream before the first product stream is contacted with the second catalyst.
Production of products from natural resources
The method disclosed herein relates to two stage catalytic processes for converting syngas to acetic acid, acrylic acid and/or propylene. More specifically, the method described and claimed herein relate to a method of producing acrylic acid and acetic acid comprising the steps of: a) providing a feedstream comprising syngas; b) contacting the feedstream with a first catalyst to produce a first product stream comprising C.sub.2-C.sub.3 olefins and/or C.sub.2-C.sub.3 paraffins; and c) contacting the first product stream with oxygen gas and a second catalyst, thereby producing a second product stream comprising acrylic acid and acetic acid, wherein there is no step for separating the components of the first product stream before the first product stream is contacted with the second catalyst.
Multi-stage oxidative dehydrogenation process with inter-stage cooling
A method of oxidatively dehydrogenating a dehydrogenation reactant includes providing a first gaseous feed stream to a first adiabatic, catalytic reaction zone with less than a stoichiometric amount of oxygen and superheated steam, oxidatively dehydrogenating dehydrogenation reactant in said first adiabatic, catalytic reaction zone and subsequently cooling the effluent, adding additional oxygen and reacting the effluent stream in at least one subsequent adiabatic reaction zone. The dehydrogenation system enables higher conversion and yield per pass and in some cases greatly reduces steam usage and energy costs. In a preferred integrated process, ethylene is converted to n-butene which is then oxidatively dehydrogenated to butadiene.
CATALYST AND PROCESS FOR SELECTIVE PRODUCTION OF LOWER HYDROCARBONS C1-C5 FROM SYNGAS WITH LOW METHANE AND CO2 PRODUCTION
A catalyst composition containing cobalt manganese oxide which is modified with silicon in the form of a hydrophilic silica, the catalyst also containing at least one of lanthanum, phosphorus, Fe, Zr, and Zn, and optionally one or more basic elements selected from the group of alkali metal, alkaline earth metal, and transition metals. Also, methods for preparing and using the catalyst composition for producing aliphatic and aromatic hydrocarbons using the catalyst composition.
Catalyst and process for selective production of lower hydrocarbons C1-C5 from syngas with low methane and CO2 production
The present invention relates to a catalyst composition comprising cobalt manganese oxide which is modified with silicon in the form of a hydrophilic silica, the catalyst further comprises at least one of lanthanum, phosphorus, Fe, Zr, and Zn, and optionally one or more basic elements selected from the group consisting of alkali metal, alkaline earth metal, and transition metal. Furthermore, a method for preparing the catalyst composition and a process for producing aliphatic and aromatic hydrocarbons using the catalyst composition are provided.