C07C2531/08

Process and apparatus for production and separation of alcohols and oligomerization of hydrocarbon feedstock

The present invention discloses an integrated process and an apparatus for production of various alcohols and Oligomerization of Olefinic feed stocks comprising butylenes and mixture thereof. In this process the combined light olefinic hydrocarbon feedstock is divided into two streams and contacted in two different reaction zones, viz. hydration and oligomerization. The mixture of alcohols and oligomer product from hydration reaction is separated and the bottom stream from separator is routed to oligomerization reaction zone in a controlled quantity as selectivity enhancer. Both the reaction zones are operated at different conditions. The product from oligomerization zone is further separated in to lighter and heavier components. Each reaction zone may comprise series of reactors filled with acidic catalysts comprising ion exchange resins.

Process for oligomerization of isobutene

A process can be used for oligomerization of isobutene by conversion of an isobutene-containing hydrocarbon stream over an acid catalyst in at least one reaction stage, where a particular ratio of recycle to feed is employed.

Process for production of mixed butanols and diisobutenes as fuel blending components

A process for simultaneously hydrating and oligomerizing a hydrocarbon feed comprising mixed olefins incudes the steps of: (a) introducing the hydrocarbon feed in the presence of water into a fixed bed; (b) contacting the hydrocarbon feed with a catalyst within said fixed bed reactor, where the catalyst is of the type that hydrates the mixed olefins to form mixed alcohols and oligomerizes at least a portion of the mixed olefins into oligomers to produce a first product stream that includes an organic phase and an aqueous phase; (c) introducing the first product stream into a first separator which separates the organic phase from the aqueous phase; (d) introducing the separated organic phase into a second separator which separates unreacted olefins from mixed alcohols and one or more oligomers which comprise a final product stream; and (e) introducing the separated aqueous phase into a third separator which separates an alcohol-water azeotrope component from water.

Acyclic monoterpenes as biofuels based on linalool and method for making the same

Acyclic monterpene alcohols, like linalool, to be converted through a series of highly efficient catalytic reactions a biogasoline blending component, and a drop-in biodiesel fuel.

OLEFIN TRIMERIZATION
20220144723 · 2022-05-12 · ·

The present disclosure relates to a process and a production unit that are used to catalytically manufacture olefin trimers from olefin monomers, and wherein olefin dimers are recycled after dimerization reaction, and reacted with olefin monomers in an addition reaction.

Olefin trimerization
11535577 · 2022-12-27 · ·

The present disclosure relates to a process and a production unit that are used to catalytically manufacture olefin trimers from olefin monomers, and wherein olefin dimers are recycled after dimerization reaction, and reacted with olefin monomers in an addition reaction.

USE OF DIVIDED WALL TECHNOLOGY TO PRODUCE HIGH PURITY METHANOL
20220064078 · 2022-03-03 · ·

Methods and systems for producing high purity methanol and isobutene from crude MTBE feed using multiple divided wall columns are provided. The methods can include purifying the MTBE, dissociating the MTBE to produce isobutene and methanol, purifying the isobutene and recovering/purifying methanol.

Process for oligomerization of isobutene

A process can be used for oligomerization of isobutene by conversion of an isobutene-containing hydrocarbon stream over an acid catalyst in at least one reaction stage, where a particular ratio of recycle to feed is employed.

PROCESS AND APPARATUS FOR PRODUCTION AND SEPARATION OF ALCOHOLS AND OLIGOMERIZATION OF HYDROCARBON FEEDSTOCK

The present invention discloses an integrated process and an apparatus for production of various alcohols and Oligomerization of Olefinic feed stocks comprising butylenes and mixture thereof. In this process the combined light olefinic hydrocarbon feedstock is divided into two streams and contacted in two different reaction zones, viz. hydration and oligomerization. The mixture of alcohols and oligomer product from hydration reaction is separated and the bottom stream from separator is routed to oligomerization reaction zone in a controlled quantity as selectivity enhancer. Both the reaction zones are operated at different conditions. The product from oligomerization zone is further separated in to lighter and heavier components. Each reaction zone may comprise series of reactors filled with acidic catalysts comprising ion exchange resins.

Process for production of mixed butanol and diisobutenes as fuel blending components

Provided is a process for hydrating and oligomerizing a hydrocarbon feed comprising mixed olefins, by contacting the feed with water and a catalyst in a fixed bed reactor, wherein the catalyst hydrates mixed olefins to mixed alcohols and oligomerizes mixed olefins into oligomers; introducing the resulting stream into a first separator that separates an organic phase from an aqueous phase; introducing the organic phase into a second separator that separates unreacted olefins from mixed alcohols/oligomers; introducing the aqueous phase into a third separator that separates an alcohol-water azeotrope from water; introducing the second stream into a fourth separator that separates sec-butyl alcohol to produce a third stream comprising mixed butanols and oligomers and an SBA stream; f) mixing the third stream and a first portion of the SBA stream to produce a final product stream; and g) recycling a second portion of the SBA stream to the second separator.