A process can treat a gaseous material mixture obtained by catalytic conversion of synthesis gas that contains at least alkenes, possibly alcohols and possibly alkanes, and also possibly nitrogen as inert gas and unconverted components of the synthesis gas, comprising hydrogen, carbon monoxide and/or carbon dioxide. After catalytic conversion of synthesis gas, separation of the product mixture obtained in this reaction into a gas phase and a liquid phase is performed by at least partial absorption of the alkenes, possibly of the alcohols and possibly of the alkanes, in a high boiling point hydrocarbon or hydrocarbon mixture as an absorption medium, separation as the gas phase of the gases not absorbed into the absorption medium, separating an aqueous phase from the organic phase of the absorption medium, preferably by decanting, and desorption of the alkenes, possibly of the alcohols and possibly of the alkanes, from the absorption medium.

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.

Disclosed is a process for producing graphene from solid hydrocarbons including biomass and coal. The disclosed method does not require the presence of hydrogen and does not operate under a vacuum. The method begins by converting biomass to a graphene precursor while coal is used as is. Subsequently, the method grinds the graphene precursor to provide a desired particle size. The particles of graphene precursor (biocoal or coal) are converted to graphene by catalytic conversion on metallic foil under atmospheric conditions and in the absence of hydrogen.

Disclosed is a process for producing graphene from solid hydrocarbons including biomass and coal. The disclosed method does not require the presence of hydrogen and does not operate under a vacuum. The method begins by converting biomass to a graphene precursor while coal is used as is. Subsequently, the method grinds the graphene precursor to provide a desired particle size. The particles of graphene precursor (biocoal or coal) are converted to graphene by catalytic conversion on metallic foil under atmospheric conditions and in the absence of hydrogen.

Lignocellulose constitutes an alluring renewable feedstock for the production of bio-based chemicals. This contribution demonstrates for the first time a chemocatalytic biorefinery concept that produces three separate product fractions of valuable product families at high yield and purity from lignocellulosic biomass; the product families, merely comprising of stable products, are (i) a lignin oil enriched with high contents of lignin-derived (mono)phenolics, (ii) essentially humin (furanic oligomers)-free hemicellulose-derived polyols, and (iii) a cellulose pulp. This is achieved by processing biomass in a close to equivolumetric mixture of an alcohol (such as n-butanol) and water at elevated temperature, in the presence of a metal catalyst and hydrogen. During this one-pot fractionation process, the hot liquor disentangles the polymeric biomass and depolymerises lignin and hemicellulose, while the catalyst and reductive environment are essential to accumulate and target stable products at high yield (such as phenolics and polyols, respectively). The process is particularly industrially relevant because its overcomes difficult and complex separation protocols, at place in classic biorefinery technology; the process foresees simple product recuperation in one process step into the three fractions; the solid carbohydrate pulp (mainly cellulose) is retrieved upon filtration, while phase separation of n-butanol and water occurs below 125° C., offering a facile and effective strategy to isolate lignin-derived phenolics, present in the alcohol (such as n-butanol phase) from polyols, present in the aqueous phase at the same time. The three resulting product streams provide a versatile platform for down-stream conversion towards added-value bio-based chemicals.

Lignocellulose constitutes an alluring renewable feedstock for the production of bio-based chemicals. This contribution demonstrates for the first time a chemocatalytic biorefinery concept that produces three separate product fractions of valuable product families at high yield and purity from lignocellulosic biomass; the product families, merely comprising of stable products, are (i) a lignin oil enriched with high contents of lignin-derived (mono)phenolics, (ii) essentially humin (furanic oligomers)-free hemicellulose-derived polyols, and (iii) a cellulose pulp. This is achieved by processing biomass in a close to equivolumetric mixture of an alcohol (such as n-butanol) and water at elevated temperature, in the presence of a metal catalyst and hydrogen. During this one-pot fractionation process, the hot liquor disentangles the polymeric biomass and depolymerises lignin and hemicellulose, while the catalyst and reductive environment are essential to accumulate and target stable products at high yield (such as phenolics and polyols, respectively). The process is particularly industrially relevant because its overcomes difficult and complex separation protocols, at place in classic biorefinery technology; the process foresees simple product recuperation in one process step into the three fractions; the solid carbohydrate pulp (mainly cellulose) is retrieved upon filtration, while phase separation of n-butanol and water occurs below 125° C., offering a facile and effective strategy to isolate lignin-derived phenolics, present in the alcohol (such as n-butanol phase) from polyols, present in the aqueous phase at the same time. The three resulting product streams provide a versatile platform for down-stream conversion towards added-value bio-based chemicals.

Set forth herein is a Fischer-Tropsch catalytic system that allows for the efficient and selective conversion of syngas to useful hydrocarbons (nC.sub.4-nC.sub.24) as well as heavy alcohols (nC.sub.1-nC.sub.9) under ambient conditions. The instantly disclosed catalytic system is more practical and scalable than other known Fischer-Tropsch catalytic systems. Also set forth herein new catalysts which comprise supported metal-oxide-based catalysts. These catalysts are useful for the conversion of syngas into liquid hydrocarbon fuels under ambient reaction conditions. The instantly disclosed catalytic system can be made in a one-pot high mass production method, which is commercially practical and scalable. A variety of reaction products can be produced by making minor adjustments to the processes disclosed herein, e.g., by adjusting catalyst composition, reaction temperature and/or reaction pressure. The instantly disclosed process(es) produce Fischer-Tropsch products, heavy hydrocarbons (e.g., paraffin's, olefins, and their derivatives), and alcohols.

The present invention relates to a dielectric packing material for converting carbon dioxide to a valuable material using non-thermal plasma technology, and more particularly, to a dielectric packing material for converting carbon dioxide to a valuable material using non-thermal plasma technology, wherein the dielectric packing material is packed in a non-thermal plasma reactor for conversion of carbon dioxide to a valuable material and is formed to have a hollow structure with multiple edges on the surface thereof to effectively scatter non-thermal plasma at the edges and thereby to improve CO.sub.2 conversion and energy efficiency.

The present invention relates to a dielectric packing material for converting carbon dioxide to a valuable material using non-thermal plasma technology, and more particularly, to a dielectric packing material for converting carbon dioxide to a valuable material using non-thermal plasma technology, wherein the dielectric packing material is packed in a non-thermal plasma reactor for conversion of carbon dioxide to a valuable material and is formed to have a hollow structure with multiple edges on the surface thereof to effectively scatter non-thermal plasma at the edges and thereby to improve CO.sub.2 conversion and energy efficiency.

An integrated process for converting light hydrocarbon gases into products. Pre-packaged equipment such as a gas turbine and process compressors may be used to efficiently integrate the process. The gas turbine may provide a portion of the oxygen required in the process as compressed air. An additional oxygen rich stream may be provided by a separate air separation process so that the combined air and oxygen rich streams have an oxygen content of 25% to 50%. The gas turbine may also provide thermal energy to pre-heat the oxygen rich stream and feed gas stream and power to run compressors, air separation, and auxiliaries in the process.