C07C27/12

PLANT LEAVES-DERIVED CARBON MATERIAL DOPED WITH TWO METALS AND PREPARATION AND USE THEREOF
20230069145 · 2023-03-02 ·

A plant leaves-derived carbon material doped with two metals and preparation and use thereof are provided, the carbon material prepared by carbonizing, in an inert atmosphere, plant leaves which have absorbed ions of two metals M1 and M2. The metal M1 is Co, Mn, or Fe. The metal M2 is Ni, Cu, or Zn. The carbon material can be used as an efficient, green, and safe catalyst for the selective oxidation of cycloalkanes to produce cycloalkanols and cycloalkanones, and enable an increased selectivity of the target products (thus less by-products), a low yield of cycloalkyl peroxides, reduced reaction temperature, low environmental impact, and safe production.

PLANT LEAVES-DERIVED CARBON MATERIAL DOPED WITH TWO METALS AND PREPARATION AND USE THEREOF
20230069145 · 2023-03-02 ·

A plant leaves-derived carbon material doped with two metals and preparation and use thereof are provided, the carbon material prepared by carbonizing, in an inert atmosphere, plant leaves which have absorbed ions of two metals M1 and M2. The metal M1 is Co, Mn, or Fe. The metal M2 is Ni, Cu, or Zn. The carbon material can be used as an efficient, green, and safe catalyst for the selective oxidation of cycloalkanes to produce cycloalkanols and cycloalkanones, and enable an increased selectivity of the target products (thus less by-products), a low yield of cycloalkyl peroxides, reduced reaction temperature, low environmental impact, and safe production.

Method for preparing polyaromatic oxide and polyaromatic oxide prepared thereby

Disclosed are a method of preparing polyaromatic oxide and polyaromatic oxide prepared thereby, wherein the method includes (a) placing a plurality of kinds of polyaromatic hydrocarbons and water in a reactor and then stirring them; (b) increasing the temperature inside the reactor to 150 to 300° C. and then feeding a gas containing 10 wt % or more of oxygen into the reactor to increase the partial pressure of oxygen inside the reactor to 2 to 30 bar; and (c) reacting the plurality of kinds of polyaromatic hydrocarbons with oxygen to oxidize the plurality of kinds of polyaromatic hydrocarbons.

Method for preparing polyaromatic oxide and polyaromatic oxide prepared thereby

Disclosed are a method of preparing polyaromatic oxide and polyaromatic oxide prepared thereby, wherein the method includes (a) placing a plurality of kinds of polyaromatic hydrocarbons and water in a reactor and then stirring them; (b) increasing the temperature inside the reactor to 150 to 300° C. and then feeding a gas containing 10 wt % or more of oxygen into the reactor to increase the partial pressure of oxygen inside the reactor to 2 to 30 bar; and (c) reacting the plurality of kinds of polyaromatic hydrocarbons with oxygen to oxidize the plurality of kinds of polyaromatic hydrocarbons.

Oxidative dehydrogenation coproduction

A system and method for coproduction in the production of ethylene, including contacting ethane with an oxidative dehydrogenation (ODH) catalyst in presence of oxygen in a first reactor to dehydrogenate ethane to ethylene, and contacting a first-reactor effluent with an ODH catalyst in a second reactor to form ethanol and acetaldehyde.

Oxidative dehydrogenation coproduction

A system and method for coproduction in the production of ethylene, including contacting ethane with an oxidative dehydrogenation (ODH) catalyst in presence of oxygen in a first reactor to dehydrogenate ethane to ethylene, and contacting a first-reactor effluent with an ODH catalyst in a second reactor to form ethanol and acetaldehyde.

CHROMIUM-CATALYZED REACTIONS OF CARBON MONOXIDE WITH HYDROCARBONS IN THE PRESENCE OF UV LIGHT

A hydrocarbon compound and carbon monoxide are reacted in the presence of either a supported chromium (VI) catalyst or a supported chromium (II) catalyst, optionally with UV-visible light irradiation and/or exposure to an oxidizing atmosphere, followed by removing a reaction product containing an alcohol compound and/or a carbonyl compound from the respective chromium catalyst. Often, the reaction product contains one or more ketone and/or aldehyde compounds.

OXIDATIVE DEHYDROGENATION COPRODUCTION
20220251004 · 2022-08-11 ·

A system and method for coproduction in the production of ethylene, including contacting ethane with an oxidative dehydrogenation (ODH) catalyst in presence of oxygen in a first reactor to dehydrogenate ethane to ethylene, and contacting a first-reactor effluent with an ODH catalyst in a second reactor to form ethanol and acetaldehyde.

OXIDATIVE DEHYDROGENATION COPRODUCTION
20220251004 · 2022-08-11 ·

A system and method for coproduction in the production of ethylene, including contacting ethane with an oxidative dehydrogenation (ODH) catalyst in presence of oxygen in a first reactor to dehydrogenate ethane to ethylene, and contacting a first-reactor effluent with an ODH catalyst in a second reactor to form ethanol and acetaldehyde.

Ozone-facilitated selective oxidation of alkanes in liquid carbon dioxide

A process for the ozonolysis of an alkane may comprise combining an alkane and ozone in a liquid phase medium comprising CO.sub.2 under conditions sufficient to oxidize the alkane to produce one or more non-combustion products. The liquid phase medium may be free of a super acid.